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Development and Demonstration of a Low Emissions Four-Stroke Outboard Marine Engine Utilizing Catalyst Technology

2012-06-18
A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.
Collection

Advances in Catalyst Substrates, 2017

2017-03-28
Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.
Collection

Advances in Catalyst Substrates, 2018

2018-04-03
Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.
Journal Article

Treatment of Vehicle Emissions from the Combustion of E85 and Gasoline with Catalyzed Hydrocarbon Traps

2009-04-20
2009-01-1080
Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.
Journal Article

Advanced Control System of Variable Compression Ratio (VCR) Engine with Dual Piston Mechanism

2009-04-20
2009-01-1063
A dual piston Variable Compression Ratio (VCR) engine has been newly developed. This compact VCR system uses the inertia force and hydraulic pressure accompanying the reciprocating motion of the piston to raise and lower the outer piston and switches the compression ratio in two stages. For the torque characteristic enhancement and the knocking prevention when the compression ratio is being switched, it is necessary to carry out engine controls based on accurate compression ratio judgment. In order to accurately judge compression ratio switching timing, a control system employing the Hidden Markov Model (HMM) was used to analyze vibration generated during the compression ratio switching. Also, in order to realize smooth torque characteristics, an ignition timing control system that separately controls each cylinder and simultaneously performs knocking control was constructed.
Journal Article

Estimation of deviations in NO and soot emissions between steady-state and EUDC transient operation of a common-rail diesel engine

2009-09-13
2009-24-0147
The study measured Mass Air Flow, (MAF), Manifold Absolute Pressure, (MAP), and emissions of NO and soot during fourteen transients of speed and load, representative of the Extra Urban Drive Cycle (EUDC). The tests were conducted on a typical passenger car/light-duty truck powertrain (a turbocharged common-rail diesel engine, of in-line 4-cylinder configuration). The objective was to compare NO and soot with corresponding steady-state emission results and propose an engine measurement methodology that will potentially quantify deviation (i.e. deterioration with respect to steady state optimum) in emissions of NO and soot during transients. Comparison between steady state, quasi-steady-states (defined later in the paper) and transients indicated that discrete quasi-steady-state engine operation, can be used for accurate prediction of transient emissions of NO and soot.
Journal Article

Characteristics of Isopentanol as a Fuel for HCCI Engines

2010-10-25
2010-01-2164
Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.
Journal Article

Controlling Lubricant-Derived Phosphorous Deactivation of the Three-Way Catalysts Part 2: Positive Environmental Impact of Novel ZDP Technology

2010-10-25
2010-01-2257
Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).
Journal Article

Efficiency and Emissions-Optimized Operating Strategy of a High-pressure Direct Injection Hydrogen Engine for Heavy-duty Trucks

2009-11-02
2009-01-2683
Hydrogen engines are required to provide high thermal efficiency and low nitrogen oxide (NOx) emissions. There are many possible combinations of injection pressure, injection timing, ignition timing, lambda and EGR rate that can be used in a direct-injection system for achieving such performance. In this study, several different combinations of injection and ignition timings were classified as possible combustion regimes, and experiments were conducted to make clear the differences in combustion conditions attributable to these timings. Lambda and the EGR rate were also evaluated for achieving the desired performance, and indicated thermal efficiency of over 45% was obtained at IMEP of 0.95 MPa. It was found that a hydrogen engine with a high-pressure direct-injection system has a high potential for improving thermal efficiency and reducing NOx emissions.
Journal Article

Simultaneous Measurements of Aromatic Hydrocarbons in Exhaust using a Laser Ionization Method

2009-11-02
2009-01-2742
A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.
Journal Article

Very Lean and Diluted SI Combustion Using a Novel Ignition System with Repetitive Pulse Discharges

2009-11-03
2009-32-0119
A newly developed small-sized IES (inductive energy storage) circuit with semiconductor switch at turn-off action is successfully applied to an ignition system of a small gasoline internal combustion engine. This IES circuit can generate repetitive nanosecond pulse discharges. An ignition system using repetitive nanosecond pulse discharges is investigated as an alternative to a conventional spark ignition system. The present study focuses on the extension of the operational limits for lean and diluted combustion using the repetitive nanosecond pulse discharges. First, in order to investigate the flame kernel formation process when the repetitive nanosecond pulse discharges are used, the initial flame kernel is observed using Schlieren photography with a high speed camera. As a result, the flame kernel generated by repetitive pulse discharges is larger than by a conventional ignition system.
Journal Article

High Efficiency, Low Feedgas NOx, and Improved Cold Start Enabled by Low-Temperature Ethanol Reforming

2010-04-12
2010-01-0621
Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.
Journal Article

Effect of Fuel and Thermal Stratifications on the Operational Range of an HCCI Gasoline Engine Using the Blow-Down Super Charge System

2010-04-12
2010-01-0845
In order to extend the HCCI high load operational limit, the effects of the distributions of temperature and fuel concentration on pressure rise rate (dP/dθ) were investigated through theoretical and experimental methods. The Blow-Down Super Charge (BDSC) and the EGR guide parts are employed simultaneously to enhance thermal stratification inside the cylinder. And also, to control the distribution of fuel concentration, direct fuel injection system was used. As a first step, the effect of spatial temperature distribution on maximum pressure rise rate (dP/dθmax) was investigated. The influence of the EGR guide parts on the temperature distribution was investigated using 3-D numerical simulation. Simulation results showed that the temperature difference between high temperature zone and low temperature zone increased by using EGR guide parts together with the BDSC system.
Journal Article

Effect of Manifold Orientation on Non-Reacting In-Cylinder Tumble Flows in an IC Engine with Pentroof Piston - An Investigation Using PIV

2010-04-12
2010-01-0956
This paper deals with experimental study of in-cylinder tumble flows in a single-cylinder, four-stroke, two-valve internal combustion engine using a pentroof-offset-bowl piston under non-reacting conditions with four intake manifold orientations at an engine speed of 1000 rev/min., during suction and compression strokes using particle image velocimetry. Two-dimensional in-cylinder tumble flow measurements and analysis are carried out in combustion space on a vertical plane passing through cylinder axis. Ensemble average velocity vectors are used to analyze the tumble flows. Tumble ratio (TR) and average turbulent kinetic energy (TKE) are evaluated and used to characterize the tumble flows. From analysis of results, it is found that at end of compression stroke, 90° intake manifold orientation shows an improvement in TR and TKE compared other intake manifold orientations considered.
Journal Article

Quantitative Study of Concentration and Temperature of a Diesel Spray by Using Planar Laser Induced Exciplex Fluorescence Technique

2010-04-12
2010-01-0878
The Lambert-Beer's coefficient K was measured in a wide range of temperatures (400-1200K) and pressures (2-8.2 MPa) in this paper. Based on the measured MAP of K and principle of energy conservation in the sprays mass and transfer, a quantitative presentation of equivalence ratio and temperature in vapor phase sprays at diesel engine like conditions was put forward. The experimental range of temperatures was 800-1100K and 20-100 kg/m₃ for density. It was found that the maximum equivalence ratio of vapor phase spray remained fairly constant at about 3.0 and the maximum equivalence ratio appearance earlier as the ambient density increased, while the ambient temperature in the constant volume vessel was set at 800K. The maximum equivalence ratio of vapor phase spray increased from about 3.0 to about 3.7 as ambient temperature increased from 800 to 1100K.
Journal Article

Development of the Combustion System for a Flexible Fuel Turbocharged Direct Injection Engine

2010-04-12
2010-01-0585
Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.
Journal Article

Applying Detailed Kinetics to Realistic Engine Simulation: the Surrogate Blend Optimizer and Mechanism Reduction Strategies

2010-04-12
2010-01-0541
Designing advanced, clean and fuel-efficient engines requires detailed understanding of fuel chemistry. While knowledge of fuel combustion chemistry has grown rapidly in recent years, the representation of conventional fossil fuels in full detail is still intractable. A popular approach is to use a model-fuel or surrogate blend that can mimic various characteristics of a conventional fuel. Despite the use of surrogate blends, there remains a gap between detailed chemistry and its utilization in computational fluid dynamics (CFD), due to the prohibitive computational cost of using thousands of chemical species in large numbers of computational cells. This work presents a set of software tools that help to enable the use of detailed chemistry in representing conventional fuels in CFD simulation. The software tools include the Surrogate Blend Optimizer and a suite of automated mechanism reduction strategies.
Journal Article

The Role of EGR in PM Emissions from Gasoline Engines

2010-04-12
2010-01-0353
A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.
Journal Article

Controlling Lubricant Derived Phosphorous Deactivation of the Three Way Catalysts Part 1: Assessments of Various Testing Methodologies

2010-05-05
2010-01-1544
Prior work by various OEMs has identified the ability of phosphorus-containing compounds to interfere with the efficiency of modern emissions control systems utilized by gasoline-powered vehicles. Considering the growing societal concerns about ecological effects of exhaust emissions, greenhouse gas emissions and related global climatic changes, it becomes desirable to examine the effect of reduced phosphorous (P) deposits in various vehicle makes, models and types of service, over the lifetime of a vehicle's operation. This paper assesses advantages and disadvantages of various methods to examine the path of P transfer throughout exhaust catalytic systems. Test types discussed include examples of bench testing focusing on catalyst compatibility, dyno mileage accumulation and field trial examinations.
Journal Article

Development of a Control Method to Reduce Acceleration Shock in Motorcycles

2010-09-28
2010-32-0106
The purpose of this paper is to propose a control method to reduce acceleration shock in motorcycles. Reducing the acceleration shock is very important in improving driveability of motorcycles. Motorcycles equipped with manual transmission have some backlashes in the transmission, with large backlash especially in dog clutch portions. We have figured out that one of the main causes of the acceleration shock is the collision of the dogs at high relative angular velocity during acceleration. Also, our data analysis has revealed that there is a correlation between a peak value of the longitudinal body acceleration and the relative angular velocity at the moment of the dog collision. A simulation was undertaken to verify this phenomenon, and its results have made it clear that we need to decrease the relative angular velocity at the moment of the dog collision so as to reduce the acceleration shock.
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