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Analysis of non-legislated engine-emission components, with different exhaust-gas after-treatment techniques, is an important air quality objective. This paper reports the results for various nitrogen oxides, ammonia and differentiated hydrocarbons emitted at part load from a small 4-S SI engine. It was operated with gasoline, with CNG and with two different three-way catalytic converters. CNG produces less HC and less aromatics. But the HC conversion rate is insufficient. This is due to the lower exhaust gas temperatures, at part load with CNG, and due to the higher stability of light HCs. CNG affects the λ-regulation window, of the investigated system, such that the NOx conversion rate is lowered. In the rich domain of the λ-regulation window, the NO & NOx emissions after catalyst were lowest, while the NH₃ formation was most intense, and vice versa.

During the VERT *) testing of different DPF systems it was remarked, that the oxidation catalyst converts sometimes a big part of NO to NO2, producing on the one hand a more toxic composition of the exhaust gases and causing on the other hand measuring artefacts, which tend to underestimate of NO2 and NOx by the cold NOx - measurement. The present work summarizes the experiences in this matter elaborated at the Laboratories for IC-Engines & Exhaust Emissions Control (AFHB) of the University of Applied Sciences Biel-Bienne, Switzerland, during several VERT activities and didactic projects on engine and chassis dynamometers in the years 2000-2006.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

An active oxidation catalyst is an efficient measure to reduce not only gaseous components (CO, HC), but also particle emissions (mostly oil condensates) of a small 2-stroke engine with lost oil lubrication. Since the 2- and 3-wheelers with 2-stroke propulsion are still a very serious source of air pollution worldwide in many urban areas, it is important to have a look on some consequences of an improperly working catalyst. The present paper shows some results of user-oriented aging of catalyst on the vehicle and results of limited emissions and unlimited (nano)particles during the catalysts screening tests. The works are a part of an international scooter network project, which was performed (2004 to 2007) in the Laboratories for IC-Engines & Exhaust Emission Control of the University of Applied Sciences, Biel, Switzerland with main support of the Swiss Federal Office of Environment (BAFU), Swiss Petrol Union (EV) and Swiss Lubes (VSS).

Different Diesel Particle Filters (DPF)*) were tested on a 2-Stroke Detroit-Diesel bus engine 6V 92 TA. The investigations focused on soot burden and regeneration of the DPF with special filter materials. Also examined was promoting the regeneration by: throttling, additive (FBC), oxidation catalytic converter upstream of DPF and the catalytic coating of the filter material. The metrics were the particulate matter emission, its composition and the nanoparticles. The most important results are: The average SOF content in the engine exhaust particulate matter is 77.6 % and the majority of it is emitted as bigger droplets The wire-mesh filter catalyst (WFC) - a novel emission reduction technology -substantially curtails the SOF and PM. WFC traps and oxidizes the oil droplets and produces a “dry” soot. This can be very advantageous for the DPF downstream of WFC. (WFC can be also very interesting for 2-S gasoline engines).

1 The topic of investigation of this work was the influence of different gas qualities on the engine parameters and particularly on the air excess factor λ. For this research the normalized gases with extreme compositions were used. At stationary operation there are no differences of the leaning capability of the different gases. The gas with the highest content of inert components causes the lowest full load power, the highest fuel consumption and the highest cyclic irregularity. With the same air flow and the same injection duration for different gases result different air excess factors λ according to the density and to the necessary stoichiometric air quantity of each gas. This fact influences the λ at transient operation conditions as: cold starting, gas quality jump, or load increase, if there is no λ-control. With an active λ-control, which is today fast enough, especially with an adaptive system there are no problems with λ- differences.

In this study, the combustion of butanol, neat and mixed with gasoline, was investigated on a 0.6 liter two-cylinder spark ignition engine with fully adjustable fuel injection and spark timing, coupled with an eddy current dynamometer. Two isomers of butanol, n-butanol and iso-butanol, were examined. This basic parameter study gives information about potential requirements of engine control systems for butanol FFV. Compared to the traditionally used ethanol, butanol does not exhibit hygroscopic behaviour, is chemically less aggressive and has higher energy density. On other hand, different laminar burning velocity and higher boiling temperature of butanol, compared to gasoline, requires some countermeasures to keep the engine operation reliable and efficient.

Exhaust emissions measurements of a small 2-S Scooter Peugeot TSDI*), 50cc with different particle filters have been performed in this present work according to the measuring procedures, which were established in the previous research in the Swiss Scooter Network, [1, 2, 3, 4, 5, 6, 7, 8, 9]. The investigated particle filtration materials were supplied from different manufacturers as samples without specifications and they were applied by the research laboratory in a special muffler able to be taken apart. The investigated scooter represented a modern (2002) 2-stroke technology with direct injection, with oxidation catalyst and with injection of the lube oil to the intake air. Since there is a special concern about the particle emissions of the small engines, the particle mass and nanoparticle measurements were systematically carried out. The nanoparticulate emissions were measured by means of SMPS (CPC) and NanoMet*).

Nanoparticle emissions of two 2-stroke scooters were investigated along the exhaust and the CVS (Constant Volume Sampling) systems. Two configurations were tested: regular full-flow dilution configuration (denoted as “closed”) and also a modified sampling configuration (denoted as “open”). The scooters represent two distinct modern technologies. One scooter had direct injection TSDI*) (Two-Stroke Direct Injection). The other had a carburettor. Depending on the technology, the scooters produce different kind of aerosols (state-of-oxidation and SOF content). Moreover, the scooters were operated with and without oxidation catalyst. The tests were performed at two constant vehicular speeds (20 km/h and 40 km/h). The measuring procedures are those established during the previous research of the Swiss Scooter Network. The nanoparticulate emissions were measured using SMPS (Scanning Mobility Particle Sizer) and DC (Diffusion Charging) sensors.

Limited and nonlimited emissions of scooters were analysed during several annual research programs of the Swiss Agency of Environment Forests and Landscape (SAEFL, BUWAL)*). Small scooters, which are very much used in the congested centers of several cities are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburetor were performed. The nanoparticulate emissions with different lube oils and fuels were measured by means of SMPS, (CPC) and NanoMet *). Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for PAH & SOF/INSOF, as well as for VOC were carried out in an international project network.

NO₂ is much more toxic than NO. The average proportion of NO₂ in exhaust gases of vehicles increases significantly due to the use of oxidation catalysts and catalytic coatings in the exhaust gas systems during the last decades combined with generalization of using low sulfur fuels. Diesel oxidation catalysts (DOC) and Pt-containing DPF coatings are widely used to support the regeneration of particle filters, being a source of strongly increased production of NO₂. The present work shows some examples and summarizes the experiences in this matter performed at the Laboratories for IC-Engines & Exhaust Emissions Control (AFHB) of the University of Applied Sciences Biel-Bienne, Switzerland, during some research activities on engine dynamometers in the years 2010-2012.

The progressing exhaust gas legislation for on- and off-road vehicles includes gradually the nanoparticle count limits. The invisible nanoparticles from different emission sources penetrate like a gas into the living organisms and may cause several health hazards. The present paper shows some results of a modern chain saw with & without oxidation catalyst, with Alkylate fuel and with different lube oils. The measurements focused specially on particulate emissions. Particulates were analysed by means of gravimetry (PM) and granulometry SMPS (PN). In this way the reduction potentials with application of the best materials (fuel, lube oil, ox-cat.) were indicated. It has been shown that the particle mass (PM) and the particle numbers (PN), which both consisting almost exclusively of unburned lube-oil, can attain quite high values, but can be influenced by the lube oil quality and can be considerably reduced with an oxidation catalyst.

The invisible nanoparticles (NP)*) from combustion processes penetrate easily into the human body through the respiratory and olfactory pathways and carry numerous harmful health effects potentials. NP count concentrations are limited in EU for Diesel passenger cars since 2013 and for gasoline cars with direct injection (GDI) since 2014. The limit for GDI was temporary extended to 6 × 1012 #/km, (regulation No. 459/2012/EU). Nuclei of metals as well as organics are suspected to significantly contribute especially to the ultrafine particle size fractions, and thus to the particle number concentration. In the project GasOMeP (Gasoline Organic & Metal Particulates) metal-nanoparticles (including sub 20nm) from gasoline cars are investigated for different engine technologies. In the present paper some results of investigations of nanoparticles from four gasoline cars - an older one with MPI and three newer with DI - are represented.