Technical Paper
Development of a High Performance Catalyzed Hydrocarbon Trap Using Ag-Zeolite
2004-03-08
2004-01-1275
A high performance catalyzed hydrocarbon (HC) trap, consisting of a Ag-impregnated zeolite and a three-way catalyst (TWC), was developed to achieve the stringent exhaust regulations such as SULEV. To improve the HC retention ability and durability of Ag-zeolite, the effects of wash-coat loading, HCs species, space velocities (SV) etc. on HC desorption profiles upon heating-up were examined in detail. In the present study, a simulated durability test using a cyclic lean-stoichiometric aging, was developed and applied for durability evaluation. An ultraviolet visible near-infrared spectrophotometer (UV-Vis) showed that specific chemical species of Ag were responsible for the delay of HC desorption. After the cyclic aging, the retention effect of Ag was only seen with aromatic compounds. It was revealed that the HC retention effect on aromatic compounds was maintained at high SV values, which was confirmed by actual vehicle tests.