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Nissan Motor Company has recently released the �Nissan Green Program 2016� which is a six-year action plan embodying the company�s environmental philosophy: Symbiosis of People, Vehicles and Nature. One of the key activities of this Program is the successful penetration of Zero-Emission Vehicles into the market which includes electric vehicle (EV) cumulative sales of 1.5M units with our Alliance partner Renault, introduction of a fuel cell electric vehicle (FCEV) into the market, taking a global leadership in supplying batteries for electric drive and creating zero-emission societies. This presentation will highlight some of these key activities. Presenter Kev Adjemian, Nissan Technical Center NA

A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

The application of accelerated catalyst aging procedures on an engine dynamometer test bed for the purpose of demonstrating catalyst durability is examined. A proof-of-principle approach is followed using catalysts from vehicles certified to U.S. Tier 2 Bin 4 and California SULEV 2 levels. Accelerated durability demonstration methods based upon conventional fuel cut cycles were employed to age catalysts to levels predicted by quantification of thermal catalyst bed severity on the Standard Road Cycle (SRC) relative to the fuel cut aging cycle using the Bench Aging Time (BAT) equation. Emissions deterioration on the accelerated aging cycle is compared to the automobile manufacturers' certification values and to whole vehicle emissions performance results from several different in-use vehicle fleets. The influence of technology on whole vehicle emissions levels and deterioration characteristics is also evaluated.

In recognizing the potential for large, damaging impacts from climate change, California enacted Executive Order S-03-05, requiring a reduction in statewide greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050. Given that the transportation light-duty vehicle (LDV) segment accounts for 28% of the state's GHG emissions today, it will be difficult to meet the 2050 goal unless a portfolio of near-zero carbon transportation solutions is pursued. Because it takes decades for a new propulsion system to capture a large fraction of the passenger vehicle market due to vehicle fleet turn-over rates, it is important to accelerate the introduction of these alternatives to ensure markets enter into early commercial volumes (10,000s) between 2015 and 2020. This report summarizes the results and conclusions of a modeling exercise that simulated GHG emissions from the LDV sector to 2050 in California.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.

Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

Research has been conducted on Controlled Auto-Ignition (CAI) engine with natural gas. CAI engine has the potential to be highly efficient and to produce low emissions. CAI engine is potentially applicable to automobile engine. However due to narrow operating range, CAI engine for automobile engine which require various speed and load in real world operation is still remaining at research level. In comparison some natural gas engines for electricity generation only require continuous operation at constant load. There is possibility of efficiency enhancement by CAI combustion which is running same speed at constant load. Since natural gas is primary consisting of methane (CH4), high auto-ignition temperature is required to occur stable auto-ignition. Usually additional intake heat required to keep stable auto-ignition. To keep high compression temperature, single cylinder natural gas engine with high compression ratio (CR=26) was constructed.

The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III and Tier 3 emission standards which will require significant reductions in hydrocarbon (HC) and oxides of nitrogen (NOx) emissions. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines, so the time required to achieve effective emissions control after a cold-start with typical aftertreatment devices is considerably longer. To address this challenge, a novel diesel cold-start emission control strategy was investigated on a 2L class diesel engine. This strategy combines several technologies to reduce tailpipe HC and NOx emissions before the start of the second hill of the FTP75. The technologies include both engine tuning and aftertreatment changes.

Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed.

A fuel design concept for an HCCI engine based on chemical kinetics to optimize the heat release profile and achieve robust ignition was proposed, and applied to the design of the optimal methane-based blend. Ignition process chemistry of each single-component of natural gas, methane, ethane, propane, n-butane and isobutane, was analyzed using detailed chemical kinetic computations. Ethane exhibits low ignitability, close to that of methane, when the initial temperature is below 800 K, but higher ignitability, close to those of propane, n-butane and isobutane, when the initial temperature is above 1100 K. Furthermore, ethane shows a higher heat release rate during the late stage of the ignition process. If the early stage of an ignition process takes place during the compression stroke, this kind of heat release profile is desirable in an HCCI engine to reduce cycle-to-cycle variation during the expansion stroke.

The combustion of gaseous fuels like methane in internal combustion engines is an interesting alternative to the conventional gasoline and diesel fuels. Reasons are the availability of the resource and the significant advantage in terms of CO2 emissions due to the beneficial C/H ratio. One difficulty of gaseous fuels is the preparation of the gas/air mixtures for all operation points, since the volumetric energy density of the fuel is lower compared to conventional liquid fuels. Low-pressure port-injected systems suffer from substantially reduced volumetric efficiencies. Direct injection systems avoid such losses; in order to deliver enough fuel into the cylinder, high pressures are however needed for the gas injection which forces the fuel to enter the cylinder at supersonic speed followed by a Mach disk. The detailed modeling of these physical effects is very challenging, since the fluid velocities and pressure and velocity gradients at the Mach disc are very high.

A pre-treatment technique for improving coating adhesion on stainless steel has been developed. This method dramatically enhances the adhesion between the stainless steel and the coating by pre-treating the stainless steel with a known nickel strike plating for a short period of time. Furthermore, when this process was applied to stainless fuel filler pipes to improve corrosion resistance, layout restrictions and chipping covers became unnecessary, costs were reduced, and vehicle weight was lowered.

Strict regulations on air pollution motivates clean combustion research for fossil fuels. To numerically mimic real gasoline fuel reactivity, surrogates are proposed to facilitate advanced engine design and predict emissions by chemical kinetic modelling. However, chemical kinetic models could not accurately predict non-regular emissions, e.g. aldehydes, ketones and unsaturated hydrocarbons, which are important air pollutants. In this work, we propose to use machine-learning algorithms to achieve better predictions. Combustion chemistry of fuels constituting of 10 neat fuels, 6 primary reference fuels (PRF) and 6 FGX surrogates were tested in a jet stirred reactor. Experimental data were collected in the same setup to maintain data uniformity and consistency under following conditions: residence time at 1.0 second, fuel concentration at 0.25%, equivalence ratio at 1.0, and temperature range from 750 to 1100K.

This paper covers the mathematical modeling of governing equations for the coupled heat and mass transfer phenomena during adsorption and desorption. Also the main focus is given on the methodology for numerical simulation for solving these partial differential equations for carbon canister. A comprehensive literature review is presented to summarize the target requirements of allowed evaporative emission level of gasoline vapour in grams per day based on global standards like, EU6, EPA stage II enhanced, CARB LEVII, PZEV and SULEV. In order to meet these stringent emission norms, presence of carbon canister is mandatory. The simulation results are compared for the gasoline vehicle application at various climatic temperature conditions in India, in which the canister sizing vs allowable emission targets are summarized.

Chassis dynamometer tests were conducted on three Class III on-highway motorcycles produced for the North American market and equipped with advanced emission control technologies in order to inform emissions inventories and compare the impacts of existing Tier 2 (E0) fuel with more market representative Tier 3 and LEV III certification fuels with 10% ethanol. For this study, the motorcycles were tested over the US Federal Test Procedure (FTP) and the World Motorcycle Test Cycle (WMTC) certification test cycles as well as a sample of real-world motorcycle driving informally referred to as the Real World Driving Cycle (RWDC). The primary interest was to understand the emissions changes of the selected motorcycles with the use of certification fuels containing 10% ethanol compared to 0% ethanol over the three test cycles.

Among the others, natural gas (NG) is regarded as a potential solution to enhance the environmental performance of internal combustion engines. Low carbon-to-hydrogen ratio, worldwide relatively homogeneous distribution and reduced price are the reason as, lately, many researchers efforts have been put in this area. In particular, this work focuses on the characterization of the injection process inside a constant volume chamber (CVC), which could provide a contribution to the development of direct injection technologies for a gaseous fuel. Direct injection of a gaseous fuel involves the presence of under-expanded jets whose knowledge is fundamental to achieve the proper mixture formation prior to the combustion ignition. For this reason, a density based solver was developed within the OpenFOAM library in order to simulate the jet issued from an injector suitable for direct injection of methane.

Homogeneous lean spark-ignited combustion is known for its thermodynamic advantages over conventional stoichiometric combustion but remains a challenge due to combustion instability, engine knock and NOx emissions especially at higher engine loads above the naturally aspirated limit. Investigations have shown that lean combustion can partly suppress knock, which is why the concept may be particularly advantageous in high load, boosted operation in downsized engines with high compression ratios. However, the authors have previously shown that this is not true for all cases due to the appearance of a lean load limit, which is defined by the convergence of the knock limit and combustion stability limit. Therefore, further research has been conducted with the alternative and potentially renewable fuel methane which has higher resistance to autoignition compared to gasoline.

Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.