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Regarding further development of gasoline engines several new technologies are investigated in order to diminish pollutant emissions and particularly fuel consumption. The Homogeneous Charge Compression Ignition (HCCI) seems to be a promising way to reach these targets. Therefore, in the past years there had been a lot of experimental efforts in this field of combustion system engineering. Negative valve overlap with pilot injection before pumping top dead center (PTDC) and an “intermediate” compression and combustion during PTDC, followed by the main injection after PTDC, is one way to realize and to proper control a HCCI operation. For conventional CI and SI combustion the pressure trace analysis (PTA) is a powerful and widely used tool to analyse, understand and optimize the combustion process.