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In-cylinder optical diagnostic was applied to study butanol-gasoline blend combustion in a SI engine. Spark timing and fuel injection mode were changed to work in normal and knocking conditions. The experiments were realized in a single-cylinder ported fuel injection SI engine with an external boosting device. The engine worked like-stoichiometric mixture at 2000 rpm, medium boosting and wide open throttle. UV-visible natural emission spectroscopy allowed to follow the formation and the evolution of the main compounds and radical species that characterize the combustion process from the spark ignition until the exhaust. Particular interest was devoted to OH and CO₂* evolution, and to the spectral evidence of soot precursors due to fuel deposits burning. OH resulted the best marker for combustion both in normal and abnormal conditions.

Multi-wavelength ultraviolet-visible extinction spectroscopy was applied to follow the evolution of fuel vapor injected by post-injection along the exhaust line of a common-rail turbocharged direct-injection diesel engine at moderate speed and load. The exhaust line was specifically designed and customized to allow the insertion of the optical access upstream of the Diesel Oxidation Catalyst. During the experimental campaign, the engine was fuelled with commercial B5 fuel and a B30 v/v blend of RME and ultra low sulfur diesel, monitoring emissions upstream of the catalyst and exhaust gas temperature across the catalyst. Tests were performed at different engine operating conditions with particular attention to moderate speed and load.