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Intensified emission regulations as well as consumption demands lead to an increasing significance of unburned hydrocarbon (UHC) emissions for diesel engines. On the one hand, the quantity of hydrocarbon (HC) raw emissions is important for emission predictions as well as for the exhaust after treatment. On the other hand, HC emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the HC molecules. Due to these reasons, a simulation model for predicting HC raw emissions was developed for diesel engines based on a phenomenological two-zone model. The HC model takes three main sources of HC emissions of diesel engines into account: Firstly, it contains a sub-model that describes the fuel dribble out of the injector after the end of injection. Secondly, HC emissions from cold peripheral zones near cylinder walls are determined in another sub-model.

In this research, simulation and experimental investigation of H2 emission formation and its influence during the post-oxidation phenomenon were conducted on a turbo-charged spark ignition engine. During the post-oxidation phenomenon phase, rich air-fuel ratio (A/F) is used inside the cylinder. This rich excursion gives rise to the production of H2 emission by various reactions inside the cylinder. It is expected that the generation of this H2 emission can play a key role in the actuation of the post-oxidation and its reaction rate if enough temperature and mixing strength are attained. It is predicted that when rich combustion inside the cylinder will take place, more carbon monoxide (CO)/ Total Hydro Carbon (THC)/ Hydrogen (H2) contents will arrive in the exhaust manifold. This H2 content facilitates in the production of OH radical which contributes to the post-oxidation reaction and in-turn can aid towards increasing the enthalpy.

The most significant operation limit prohibiting the further reduction of the CO2 emissions of gasoline engines is the occurrence of knock. Thus, being able to predict the incidence of this phenomenon is of vital importance for the engine process simulation - a tool widely used in the engine development. Common knock models in the 0D/1D simulation are based on the calculation of a pre-reaction state of the unburnt mixture (also called knock integral), which is a simplified approach for modeling the progress of the chemical reactions in the end gas where knock occurs. Simulations of thousands of knocking single working cycles with a model representing the Entrainment model’s unburnt zone were performed using a detailed chemical reaction mechanism. The investigations showed that, at specific boundary conditions, the auto-ignition of the unburnt mixture resulting in knock happens in two stages.

In the quasi-dimensional modeling of the spark-ignition combustion process, the burn rate calculation depends, among other influences, on the laminar flame speed. Commonly used models of laminar flame speeds are usually developed on the basis of measurement data limited to boundary conditions outside of the engine operation range. This limitation is caused by flame instabilities and forces flame speed models to be extrapolated for the application in combustion process simulation. However, for the investigation of, for example, lean burn engine concepts, reliable flame speed values are needed to improve the quality and predictive ability of burn rate models. For this purpose, a reference fuel for gasoline is defined to perform reaction kinetics calculations of laminar flame speeds for a wide range of boundary conditions.

Fulfilling exhaust emissions regulations and meet customer performance needs mainly drive the current engine development. Turbocharging system plays a key role for that. Currently turbocharging should provide highest engine power density at high engine speed by also allowing a very responsive performance at low end. This represents a trade-off in turbocharger development. A large scaled turbine allows having moderate exhaust gas back pressure for peak power region, but leading to loss of torque in low engine speed. In the last years of engine development scavenging helped to get away a bit from this trade-off as it increases the turbine mass flow and also reduces cylinder internal residual gas at low engine speed. The mostly in-use lean strategy runs air fuel ratios of closed to stoichiometric mixture in cylinder and global (pre catalyst) of λ = 1.05 to l = 1.3. This will be out of the narrow air fuel ratio band of λ = 1 to ensure NOx conversion in the 3-way-catalyst.

Intensified emission regulations as well as consumption demands lead to an increasing significance of carbon monoxide (CO) emissions for diesel engines. On the one hand, the quantity of CO raw emissions is important for emission predictions as well as for the exhaust gas after treatment. On the other hand, CO emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the CO molecules. Due to these reasons, a simulation model for predicting CO raw emissions was developed for diesel engines based on a phenomenological two-zone model. The CO model takes three main sources of CO emissions of diesel engines into account: Firstly, it contains a sub model that describes CO from local understoichiometric areas. Secondly, CO emissions from overmixed regions are considered.