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While the Diesel Particulate Filter (DPF) is actually a quasi-standard equipment in the European Diesel passenger cars market, an interesting solution to fulfill NOx emission limits for the next EU 6 legislation is the application of a Selective Catalytic Reduction (SCR) system on the exhaust line, to drastically reduce NOx emissions. In this context, one of the main issues is the performance of the SCR system during cold start and warm up phases of the engine. The exhaust temperature is too low to allow thermal activation of the reactor and, consequently, to promote high conversion efficiency and significant NOx concentration reduction. This is increasingly evident the smaller the engine displacement, because of its lower exhaust system temperature (reduced gross power while producing the same net power, i.e., higher efficiency).