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One promising alternative for meeting stringent NOx limits while attaining high engine efficiency in lean-burn operation are NOx storage catalysts (NSC), an established technology in passenger car aftertreatment systems. For this reason, a NSC system for a stationary single-cylinder CHP gas engine with a rated electric power of 5.5 kW comprising series automotive parts was developed. Main aim of the work presented in this paper was maximising NOx conversion performance and determining the overall potential of NSC aftertreatment with regard to min-NOx operation. The experiments showed that both NOx storage and reduction are highly sensitive to exhaust gas temperature and purge time. While NOx adsorption rate peaks at a NSC inlet temperature of around 290 °C, higher temperatures are beneficial for a fast desorption during the regeneration phase. Combining a relatively large catalyst (1.9 l) with a small exhaust gas mass flow leads to a low space velocity inside the NSC.