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The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

Today's biofuels require large amounts of energy in the production process for the conversion from biomass into fuels with conventional properties. To reduce the amounts of energy needed, future fuels derived from biomass will have a molecular structure which is more similar to the respective feedstock. Butyl levulinate can be gained easily from levulinic acid which is produced by acid hydrolysis of cellulose. Thus, the Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of this biofuel compound, as a candidate for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. Previous investigations identified most desirable fuel properties like a reduced cetane number, an increased amount of oxygen content and a low boiling temperature for compression ignition engine conditions.

Partly competing objectives, as low fuel consumption, low friction, long oil maintenance rate, and at the same time lowest exhaust emissions have to be fulfilled. Diminishing resources, continuously reduced development periods, and shortened product cycles yield detailed knowledge about oil consumption mechanisms in combustion engines to be essential. There are different ways for the lubricating oil to enter the combustion chamber: for example as blow-by gas, leakage past valve stem seals, piston rings (reverse blow-by) and evaporation from the cylinder liner wall and the combustion chamber. For a further reduction of oil consumption the investigation of these mechanisms has become more and more important. In this paper the influence of the mixture formation and the resulting fuel content in the cylinder liner wall film on the lubricant oil emission was examined.

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.

With Post Euro 6 emission standards in discussion, stricter particulate number (PN) targets as well as a decreased PN cut-off size from 23 to 10 nm are expected. Sub-23 nm particulates are considered particularly harmful to human health, but are not yet taken into account in the current vehicle certification process. Not considering sub-23 nm particulates during the development process could lead to significant additional efforts for Original Equipment Manufacturers (OEM) to comply with future Post Euro 6 PN emission limits. It is therefore essential to increase knowledge about the formation and filtration of particulates below 23 nm. In the present study, a holistic Gasoline Particulate Filter (GPF) characterization has been carried out on an engine test bench under varying boundary conditions and on a burner bench with a novel ash loading methodology.

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.

The influence of two oxygenated tailor-made fuels on soot formation and oxidation in an optical single cylinder research diesel engine has been studied. For the investigation a planar laser-induced incandescence (PLII) measurement technique was applied to the engine in order to detect and evaluate the planar soot distribution for the two bio fuels within a laser light sheet. Furthermore the OH* chemiluminescence and broad band soot luminosity was visualized by high speed imaging to compare the ignition and combustion behavior of tested fuels: Two C8 oxygenates, di-n-butylether (DNBE) and 1-octanol. Both fuels have the same molecular formula but differ in their molecular structure. DNBE ignites fast and burns mostly diffusive while 1-octanol has a low cetane number and therefore it has a longer ignition delay but a more homogeneous mixture at time of ignition. The two bio fuels were finally compared to conventional diesel fuel.

Due to increasing environmental awareness, standards for pollutant and CO2 emissions are getting stricter in most markets around the world. In important markets such as Europe, also the emissions during real road driving, so called “Real Driving Emissions” (RDE), are now part of the type approval process for passenger cars. In addition to the proceeding hybridization and electrification of vehicles, the complexity and degrees of freedom of conventional powertrains with internal combustion engines (ICE) are also continuing to increase in order to comply with stricter exhaust emission standards. Besides the different requirements placed on vehicle emissions, the drivability capabilities of passenger vehicles desired by customers, are essentially important and vary between markets.

Regulated emissions, CO2-values, comfort, good driveability, high reliability and costs, this is the main frame for all future powertrain developments. In this frame, the diesel powertrain, not only for passenger cars, but also for commercial vehicle applications, faces some challenges in order to fulfil the future European and current US emission legislations while keeping the fuel consumption benefit, good driveability and an acceptable cost frame. One of these challenges is the varying fuel qualities of diesel fuel in different countries including different cetane number, volatility, sulphur content and different molecular composition. In addition to that in the future, more and more alternative fuels with various fuel qualities and properties will be launched into the market for economical and environmental reasons. At present, the control algorithms of the injection system applied in most diesel engines is open loop control.

It is the objective of this work to characterize mixture formation in the sprays emanating from Multi-Layer (ML) nozzles under approximately engine-like conditions by quantitative, spatially, and temporally resolved fuel-air ratio and temperature measurements. ML nozzles are cluster nozzles which have more than one circle of orifices. They were introduced previously, in order to overcome the limitations of conventional nozzles. In particular, the ML design yields the potential of variable spray interaction, so that mixture formation could be controlled according to the operating condition. In general, it was also a primary aim of the cluster-nozzle concepts to combine the enhanced atomization and pre-mixing of small nozzle holes with the longer spray penetration lengths of large holes. The applied diagnostic, which is based on 1d spontaneous Raman scattering, yields the quantitative stoichiometric ratio and the temperature in the vapor phase.

Sustainable and energy-efficient consumption is a main concern in contemporary society. Driven by more stringent international requirements, automobile manufacturers have shifted the focus of development into new technologies such as Hybrid Electric Vehicles (HEVs). These powertrains offer significant improvements in the efficiency of the propulsion system compared to conventional vehicles, but they also lead to higher complexities in the design process and in the control strategy. In order to obtain an optimum powertrain configuration, each component has to be laid out considering the best powertrain efficiency. With such a perspective, a simulation study was performed for the purpose of minimizing well-to-wheel CO2 emissions of a city car through electrification. Three different innovative systems, a Series Hybrid Electric Vehicle (SHEV), a Mixed Hybrid Electric Vehicle (MHEV) and a Battery Electric Vehicle (BEV) were compared to a conventional one.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

The optimization study presented herein is aimed to minimize the fuel consumption and engine-out emissions using commercially available EN15940 compatible HVO (Hydrogenated Vegetable Oil) fuel. The investigations were carried out on FEV’s 3rd generation HECS (High Efficiency Combustion System) multi-cylinder engine (1.6L, 4 Cylinder, Euro 6). Using a global DOE approach, the effects of calibration parameters on efficiency and emissions were obtained and analyzed. This was followed by a global optimization procedure to obtain a dedicated calibration for HVO. The study was aiming for efficiency improvement and it was found that at lower loads, higher fractions of low pressure EGR in combination with lower fuel injection pressures were favorable. At higher loads, a combustion center advancement, increase of injection pressure and reduced pilot injection quantities were possible without exceeding the noise and NOx levels of the baseline Diesel.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.

The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

The influence of oil related emissions became more important in the past due to reduced engine-out emissions of combustion engines. Additionally the efficiency of exhaust gas after treatment components is influenced by oil derived components. A balancing of relevant engine oil components (Ca, Mg, Zn, P, S, Mo, B, Fe, Al, Cu) is presented in this paper. The oil components deposited in the combustion chamber, in the exhaust system as well as in the aftertreatment devices were determined and quantified. Therefore a completely cleaned DI Diesel engine with oxidation catalyst, Diesel particulate filter (DPF) and NOx adsorber catalyst (LNT) was operated in different operating conditions for 500 h in a development test cell. The operation included lean/rich cycling for NOx trap regeneration. After finishing the 500 h test procedure the engine was completely disassembled and all deposits were analyzed.