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Nissan Motor Company has recently released the �Nissan Green Program 2016� which is a six-year action plan embodying the company�s environmental philosophy: Symbiosis of People, Vehicles and Nature. One of the key activities of this Program is the successful penetration of Zero-Emission Vehicles into the market which includes electric vehicle (EV) cumulative sales of 1.5M units with our Alliance partner Renault, introduction of a fuel cell electric vehicle (FCEV) into the market, taking a global leadership in supplying batteries for electric drive and creating zero-emission societies. This presentation will highlight some of these key activities. Presenter Kev Adjemian, Nissan Technical Center NA

Developing relatively cheap and widely available resources for heterogeneous solid catalyst synthesis is a promising approach for biodiesel fuel industry. Seashell which is essentially calcium carbonate can be used as a basic support for transesterification heterogeneous catalysts. In the present investigation, the alcoholysis of waste frying oil has been carried out using seashell-supported K3 PO4 as solid catalyst. Presenter Essam Oun Al-Zaini, PhD student, UNSW

OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute

A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.

The SAE 2012 World Congress theme, Get Connected, represents the new and diverse connections that will drive significant advancements in the auto industry of tomorrow. Not only does the theme symbolize literal connections, such as those between vehicles, infrastructure, the Internet, and the nation's electrical grid, but also demonstrates the most fundamental of connections; the connections and relationships between engineers who are developing the next generation vehicle technology. From OEMs to suppliers, across academia and governments, connecting to one another and using these connections to share ideas and expertise - in both healthy competition and in partnership - will be the catalyst of forthcoming innovation and the auto industry's basis to continued future success. GetConnected: SAE 2012 World Congress April 24-26, 2012 Cobo Center, Detroit, Michigan, USA Start connecting today. Vist www.sae.org/congress for more information.

A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH3 precursor to ammonia gas has been designed, applied and tested in a 3 liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea (figure 1). Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue®. Additionally a guanidine based formulation could be realized with high freezing stability down to almost ?30 °C (?

The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust.

This technical paper collection covers the complete particulate filter system. There are papers covering the DOC aging as well as the effect of high sulfur fuel on the DOC. A couple of papers study the effect of ash accumulation and two papers cover a novel new asymmetric cell design and modeling of this new design. Finally we have a paper on gasoline particulate filters.

This technical paper collection will focus on ‘Advances in NOx Reduction Technology’. The topics covered will include: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Abstract Carbon fiber reinforced plastic (CFRP) has been used in automobiles as well as airplanes. Because of its light weight and high strength, CFRP is a good choice for making vehicle bodies lighter, which would improve fuel economy. Conventional metal bodies provide a convenient body return for electric wiring and offer good shielding against electromagnetic fields. Although CFRP is a conductor, its conductivity is much lower than that of metals. Therefore, CFRP bodies are usually not useful for electric wiring. In thunderstorms, an automotive body is considered to be a Faraday cage that protects the vehicle’s occupants from the potential harms of lightning. Before CFRP becomes widely applied to automotive bodies, its electric and electromagnetic properties need to be investigated in order to determine whether it also works as a Faraday cage against lightning. In this article, CFRP and metal body vehicles were tested under artificial lightning.

Abstract A key problem of the construction of fully electric aircraft is the limited energy density of battery packs. It is generally accepted that this can only be overcome via new, denser battery chemistry together with a further increase in the efficiency of power utilization. One appealing approach for achieving the latter is using laser-assisted filler-based joining technologies, which offers unprecedented flexibility for achieving battery cell connections with the least possible electrical loss. This contribution presents our results on the effect of various experimental and process parameters on the electrical and mechanical properties of the laser-formed bond.

Abstract A methodology for the development of catalyst models is presented. Also, a methodology of the implementation of such models into a modular simulation tool, which simulates the units in succession, is presented. A case study is presented illustrating how suitable models can be found and used for simulations. Such simulations illustrate the behavior of the individual units and the overall system. It is shown how, by simulating the units in succession, the entire after treatment system can be tested and optimized, because the integration makes it possible to observe the effect of the modules on one another.

Abstract Dynamic stresses exist in parts of a catalyst muffler caused by the vibration of a moving vehicle, and it is important to clarify and predict the vibration response properties for preventing fatigue failures. Assuming a vibration isolating installation in the vehicle frame, the vibration transmissibility and local dynamic stress of the catalyst muffler were examined through a vibration machine. Based on the measured data and by systematically taking vibration theories into consideration, a new prediction method of the vibration modes and parameters was proposed that takes account of vibration isolating and damping. A lumped vibration model with the six-element and one mass point was set up, and the vibration response parameters were analyzed accurately from equations of motion. In the vibration test, resonance peaks from the hanging bracket, rubber bush, and muffler parts were confirmed in three excitation drives, and local stress peaks were coordinate with them as well.

Abstract The selective catalytic reduction (SCR) of nitrogen oxides seems to be the most promising technique to meet prospective emission regulations of diesel-driven commercial vehicles. In the case of developing cost-effective catalytic converters with comparably high activity, selectivity, and resistance against aging, ion-exchanged zeolites play a major role. This study presents, firstly, a brief literature review and subsequently a discussion of an extensive conversion analysis of exemplary Cu/ and Fe/zeolites, as well as a homogeneous admixture of both. The aging stages of SCR catalysts deserve particular attention in this study. In addition, the aging condition of the diesel oxidation catalyst (DOC) was analyzed, which influences the nitrogen dioxide (NO2) formation, because the NO2/nitrogen oxides (NOx) ratio upstream from the SCR converter could be identified as a key factor for low temperature NOx conversion.

Abstract Powertrain simulations and catalyst studies showed the efficiency credits and feasibility of onboard reforming as a way to recover waste heat from heavy duty vehicles (HDVs) fueled by natural gas (NG). Onboard reforming involves 1) injecting NG into the exhaust gas recycle (EGR) loop of the HDV, 2) reforming NG on a catalyst in the EGR loop to hydrogen and carbon monoxide, and 3) combusting the reformed fuel in the engine. The reformed fuel has increased heating value (4-10% higher LHV) and flame speed over NG, allowing stable flames in spark ignition (SI) engines at EGR levels up to 25-30%. A sulfur-tolerant reforming catalyst was shown to reform a significant amount of NG (15-30% conversion) using amounts of precious metal near the current practice for HDV emissions control (10 g rhodium). Engine simulations showed that the high EGR levels enabled by onboard reforming are used most effectively to control engine load instead of waste-gating or throttling.