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In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

The use of lean or ultra-lean ratios is an efficient and proven strategy to reduce fuel consumption and pollutant emissions. However, the lower fuel concentration in the cylinder hinders the mixture ignition, requiring greater energy to start the combustion. The prechamber is an efficient method to provide high energy favoring the ignition process. It presents the potential to reduce the emission levels and the fuel consumption, operating with lean burn mixtures and expressive combustion stability. In this paper the analysis of the combustion process of SI engines equipped with an innovative architecture and operating in different injection modes was described. In particular, the effect of the prechamber ignition on the engine stability and the efficiency was investigated in stoichiometric and lean-burn operation conditions. The activity was carried out in two parts.

Homogeneous Charge Compression Ignition (HCCI) combustion was applied to a transparent diesel engine equipped with high pressure Common Rail (CR) injection system. By means of CR system the quantity of fuel was split into five injections per cycle. Combined measurements, based on digital imaging and spectroscopic techniques, were applied to follow the evolution of HCCI combustion process with high temporal and spatial resolution. Digital imaging allowed to analyse injection and combustion phases. Broadband ultraviolet - visible extinction spectroscopy (BUVES) and flame emission measurements were carried out to evaluate the presence of radicals and species such as HCO, OH, CH, and CO. In particular, BUVES measurements were performed to follow fuel oxidation, and pollutant formation and oxidation. During injection and cool combustion, bands of aromatic compounds and alkyl peroxides, indicating fuel decomposition, and hydrogen peroxides were detected.

Nowadays HCCI combustion process is revealing the most useful technique for reducing pollutant emission from internal combustion engines. In the present paper, HCCI combustion was realized by means of single late injection at high pressure and heavy EGR, up to 50%. A transparent Direct Injection (DI) diesel engine equipped with high pressure Common Rail (CR) injection system was used. The engine was fed with commercial diesel fuel and ran in continuous mode. Digital imaging and spectroscopic techniques, with high temporal and spatial resolution, were applied to study the low temperature combustion process. Injection and combustion phases were analysed by digital imaging. Mixing process, autoignition and pollutants formation were investigated by Broadband Ultraviolet - Visible Extinction Spectroscopy (BUVES) and flame emission measurements. Radicals and species such as OH, CH and CO were detected in the combustion chamber.

Ignition delay in diesel engine combustion comprehends both a chemical and a physical amount, the first depending on fuel composition and charge temperature and pressure, the last resulting of time needed for the fuel to atomize, vaporize and mix with air. Control of this parameter, which is mandatory to weight the relative amount of premixed to diffusive stage of the hydrocarbon combustion, is here considered. Experimental measurements of flame intensity spectra obtained by in situ measurements on an optically accessible test device show the presence of peaks corresponding to radicals as OH and CH appearing at the pressure start of combustion. Since OH radicals result from chain branching reactions, a numerical simulation is performed based on a reduced kinetic scheme which allows to measure the branching agent concentration, and whose approximate nature is adequate to the proportion chemical aspects contribute to the overall delay.

Diesel combustion process was studied and characterized by digital imaging and ultraviolet-visible flame emission, extinction and scattering spectroscopy. Optical measurements were applied to a transparent diesel engine, realized by modifying a single cylinder, air-cooled, 4-stroke diesel engine by means of an external combustion chamber on the top of the engine, connected to the main chamber by a tangential passage. Diesel engine was equipped with a fully flexible electronic controlled ‘Common Rail’ injection system. Measurements were performed at 1000 rpm engine speed for two typical injection strategies. The first one consisted of a main injection in order to compare the results with those ones obtained by conventional injection system operating at low pressure. The other one was based on a pilot and main injection that is typical of current direct injection diesel engines.