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The optimization of the vaporization and mixture formation process is of great importance for the development of modern gasoline direct injection (GDI) engines, because it influences the subsequent processes of the ignition, combustion and pollutant formation significantly. In consequence, the subject of this work was the development of a measurement technique based on the laser induced exciplex fluorescence (LIF), which allows the two dimensional visualization and quantification of the in-cylinder air/fuel ratio. A tracer concept consisting of benzene and triethylamine dissolved in a non-fluorescent base fuel has been used. The calibration of the equivalence ratio proportional LIF-signal was performed directly inside the engine, at a well known mixture composition, immediately before the direct injection measurements were started.

The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

Fast and exact measurement of engine oil consumption is a very difficult task. Our aim is to achieve this measurement at a common test bed without engine modifications. We resolved this problem with a new technique using Laser Mass Spectrometry to detect appropriate tracers in the raw engine exhaust. The tracers are added to the engine oil. to the engine oil. For detection of these tracers we use a Laser Mass Spectrometer (LAMS). This is a combination of resonant laser ionization (with an all-solid-state laser) and Time-of-Flight Mass Spectrometry. Currently this is the only way to detect oil originated molecules (like our tracers) in the raw exhaust very fast (50 Hz) and sensitive (ppb-region). Thus, engine mapping of oil consumption over load and speed can be performed in 1-2 days with about 90 measurements. Even measurement during dynamic engine operation is possible, but not quantitative (due to the lack of information about dynamic exhaust gas mass flow).

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

In order to optimise the vibro-acoustic behaviour of panel-like structures in a more systematic way, accurate structural models are needed. However, at the frequencies of relevance to the vibro-acoustic problem, the mode shapes are very complex, requiring a high spatial resolution in the measurement procedure. The large number of required transducers and their mass loading effects limit the applicability of accelerometer testing. In recent years, optical measuring methods have been proposed. Direct electronic (ESPI) imaging, using strobed continuous laser illumination, or more recently, pulsed laser illumination, have lately created the possibility to bring the holographic testing approach to the level of industrial applicability for modal analysis procedures. The present paper discusses the various critical elements of a holographic ESPI modal testing system.