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The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

A sensitive laser mass spectrometer is being developed for fast multicomponent engine exhaust analyses. The features of the system meet the requirements of the analysis problems at dynamic motor test stands: detection of all organic and inorganic exhaust constituents of concentrations higher than 1 ppm simultaneous detection of up to 12 selectable exhaust compounds with 100 Hz repetition rate 2 millisecond time precision relative to the motor phase. precise sampling location everywhere in the exhaust pipe system, e.g. single valve or cylinder exhaust gas analysis ruggedness for operation at engine test facilities The time and space resolution allows the tracking of the different exhaust components during one and more motor cycle in static and transient engine operations. This information is essential for an understanding of the combustion processes, which is necessary for the development of the engine and engine control and other efforts to reduce emission of pollutants.

Time-resolved concentrations of formaldehyde and acetaldehyde in the exhaust gas have been investigated during transient motor operation, such as sudden change of speed and load, misfiring and switching off the fuel mixture control. To this purpose, a new laser mass spectrometer has been applied which is capable of measuring the concentrations of individual exhaust compounds with 1 ppm sensitivity at a sampling rate of 50 Hz corresponding to a sampling period of 20 ms. At sudden speed changes, high concentrations of aldehydes are observed, in particular during the phase of decreasing speed, i.e. after closing the throttle valve.

A new multicomponent exhaust gas analyzer has been applied to investigate the time-resolved concentrations of the aromatic hydrocarbon exhaust components benzene, toluene, xylene, trimethyl benzene under dynamic engine operation, such as sudden change of speed and load, misfiring and switching off the fuel mixture control. The analyzer consisting of a compact laser mass spectrometer is capable of measuring the concentrations of the individual aromatic hydrocarbon compounds simultaneously with 1 ppm sensitivity at a sampling rate of 50 Hz corresponding to a sampling period of 20 ms. High concentration peaks are observed for these substances at instationary motor operation. However, whereas the real-time concentrations of toluene, xylene, and trimethyl benzene show equal dependence on motor speed and load a different behavior has been observed for benzene even during the emission phase of single combustion cycles.