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Governing bodies world-wide are setting increasingly tighter emission standards to help improve air quality. US and Californian LEV/ULEV standards are pace setting, European Stage II legislation has just become effective. In Brazil, the upcoming 1997 standards are also demanding for tighter emission control. The monolithic ceramic honeycomb catalytic converter -for more than the past 20 years- has been a reliable key element in the automotive emission control systems. In order to help meet tightened emission regulation as well to satisfy even more stringent durability requirement, an advanced thinwall ceramic Celcor XT has been developed for increased geometric surface area and reduced backpressure. The product properties as well as FTP and ECE emission and durability test results are being described in this paper. Converter system durability is also determined by robust canning and mounting systems. A durable mounting concept, especially for preconverters, is being described.

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.

Catalytic converter substrates for automobile emission control have to operate under the hostile conditions of the automotive exhaust. This paper will first discuss the mechanical and physical properties to ensure durable mechanical function of the catalytic substrate and converter system. High temperature mechanical and thermal shock substrate requirements and properties will be discussed. The functionality of a catalytic converter is significantly influenced by the catalytic coating. At the same time, substrate characteristics as will be shown, also effect converter functional parameters like back pressure, light-off and conversion efficiency. The importance of the substrate parameters cell shape, cell density and substrate mass and their effect on thermohydraulic parameters like heat- and mass transfer factors for various cell structures and substrates will be presented.

Upcoming EU5 and expected emissions legislation BS5 in India in combination with efforts to optimize the overall fuel economy has created new challenges in the development of aftertreatment systems for passenger cars equipped with diesel engines. Since EU5 and BS5 emissions legislation will strongly be focused on the reduction of particulate matter it is likely that all vehicle applications will need aftertreatment systems with diesel particulate filters. High filtration efficiency combined with a high resistance to thermo-mechanical stress is a strong requirement for diesel particulate filters to meet EU5 and BS5 emission legislation. Besides those requirements the backpressure of particulate filters has to be considered since backpressure is also related to fuel economy and therefore CO₂ emissions.

High emission performance standards and precious metals costs have pushed the catalytic substrate toward high cell density and thin wall, such as the 600/4, 600/3 and 900/2 products. Due to the inherently lower mechanical strength of these products, coupled with a shift from underbody to close-coupled placement, a concern was expressed that the severe thermal and mechanical conditions may cause structural damage to the substrate, which in turn could impact the catalyst performance. One source of reduced performance during use is the loss of catalyst due to erosion. A previous study1 indicated that the existence of particulate in an air-stream could cause substrate erosion. However, it was not clear if other factors could contribute to or accelerate the erosion process. In order to address this question, experiments were performed to examine the influence of high velocity flow, temperature, impingement angle, particulate characteristics, and coating effect on erosion.

The study was aimed at assessing the impact of fuel quality on the PN10 and PN23 emissions. A total of 6 fuels having different level of ethanol, renewable components, additives, and aromatic hydrocarbons were tested on the test vehicle. In the first phase of the study, the emission tests were conducted removing the GPF present in the original aftertreatment system to measure the direct impact of different fuels on the tailpipe particle emissions. The emission results showed that heavy aromatics components lead to a significant increase in particle emissions while the fuel with renewable components and E20 emit less PN comparing to the E10 reference fuel. However, those fuel impacts became very small with a GPF present due to a high filtration efficiency independent of fuel type.

With the implementation of Emissions Stage 5 in Europe all passenger cars with diesel engines need after treatment systems with Diesel Particulate Filters (DPF). Therefore Indian post BS-IV regulations are expectedto force the introduction of DPFs for the Indian domestic market as well. In this paper a new low porosity Aluminum Titanate (AT) DPF generation is discussed and how this new product family can help address specific requirements for the Indian market. Two new technologies of the DuraTrap®AT DPFs complement the existing portfolio. One technology has an increased soot mass limit, the second new product significantly reduces the pressure drop over the filter.

The share of gasoline engines based on direct injection (DI) technology is rapidly growing, to a large extend driven by their improved efficiency and potential to lower CO2 emissions. One downside of these advanced engines are their significantly higher particulate emissions compared to engines based on port fuel injection technologies [1]. Gasoline particulate filters (GPF) are one potential technology path to address the EU6 particulate number regulation for vehicles powered by gasoline DI engines. For the robust design and operation of GPFs it is essential to understand the mechanisms of soot accumulation and oxidation under typical operating conditions. In this paper we will first discuss the use of detailed numerical simulation to describe the soot oxidation in particulate filters under typical gasoline engine operating conditions. Laboratory experiments are used to establish a robust set of soot oxidation kinetics.

With the introduction of EU6d and CN6 all vehicles with gasoline direct injection and many with port fuel injection engine will be equipped with a gasoline particulate filter (GPF). A range of first generation filter technologies has been introduced successfully, helping to significantly reduce the tailpipe particulate number emissions. The continued focus on particulate emissions and the increasing understanding of their impact on human health, combined with the advanced emission regulations under RDE conditions results in the desire for filters with even higher filtration efficiency, especially in the totally fresh state. At the same time, to balance with the requirements on power and CO2, limitations exist with respect to the tolerable pressure drop of filters. In this paper we will report on a new generation of gasoline particulate filters for uncatalyzed applications.

Gasoline particulate filters (GPF) have become a standard aftertreatment component in Europe, China, and since recently, India, where particulate emissions are based on a particle number (PN) standard. The anticipated evolution of regulations in these regions towards future EU7, CN7, and BS7 standards further enhances the needs with respect to the filtration capabilities of the GPFs used. Emission performance has to be met over a broader range in particle size, counting particles down to 10nm, and over a broader range of boundary conditions. The requirements with respect to pressure drop, aiming for as low as possible, and durability remain similar or are also enhanced further. To address these future needs new filter technologies have been developed. New technologies for uncatalyzed GPF applications have been introduced in our previous publications.

A novel diesel particulate filter for passenger car applications was introduced by Corning, based on a stabilized aluminum titanate composition. As part of the development and material evaluation Corning has performed extensive on-road testing of the new material. The testing included several vehicles, filters, system layouts and driving profiles. The filters were tested from 100,000 km to 240,000km. All test vehicles were equipped with instrumentation and data acquisition hardware, enabling the detailed recording of the relevant parameters such as temperature profiles inside the filter, the pressure drop as well as engine data. Throughout the field evaluations the filters were regularly checked for emissions over the NEDC on a chassis dynamometer according to the current European test protocol. In all cases excellent emission performance has been observed over the duration of the tests. The pressure drop performance has generally been good.

Catalyzed soot filters are being fitted to an increasing range of diesel-powered passenger cars in Europe. While the initial applications used silicon carbide wall-flow filters, oxide-based filters are now being successfully applied. Oxide-based filters can offer performance and system cost advantages for applications involving both a catalyzed filter with a separate oxidation catalyst, and a catalyzed filter-only that incorporates all necessary catalytic oxidation functions. Advanced diesel catalyst technologies have been developed for alternative advanced oxide filter materials, including aluminum titanate and advanced cordierite. In the development of the advanced catalyzed filters, improvements were made to the filter material microstructures that were coupled with new catalyst formulations and novel coating processes that had synergistic effects to give enhanced overall performance.

Information on transport mechanisms in a Diesel Particulate Filter (DPF) provides crucial insight into the filter performance. Extensive experimental work has been pursued to modify, customize and validate a model yielding accurate predictions of a ceramic wall-flow DPF pressure drop. The model accounts, not only for the major pressure drop components due to flow through porous walls but also, for viscous losses due to channel plugs, flow contraction and expansion due to flow entering and exiting the trap and also for flow secondary inertial effects near the porous walls. Experimental data were collected on a matrix of filters covering change in filter diameter and length, cell density and wall thickness and for a wide range of flow rates. The model yields accurate predictions of DPF pressure drop with no particulate loading and, with adequate adjustment, it is also capable of making predictions of pressure drop for filters lightly-loaded with particulates.

For years, diesel engines have been the focus of particulate matter emission reductions. Now, however, modern diesel engines emit less particles than a comparable gasoline engine. This transformation necessitates an introduction of particulate reduction strategies for the gasoline-powered vehicle. Many strategies can be leveraged from diesel engines, but new combustion and engine control technologies will be needed to meet the latest gasoline regulations across the globe. Particulate reduction is a critical health concern in addition to the regulatory requirements. This is a vital issue with real-world implications. Reducing Particulate Emissions in Gasoline Engines encompasses the current strategies and technologies used to reduce particulates to meet regulatory requirements and curtail health hazards - reviewing principles and applications of these techniques.

Diesel particulate filters are expected to be used on most passenger car applications designed to meet coming European emission standards, EU5 and EU6. Similar expectations hold for systems designed to meet US Tier 2 Bin 5 standards. Among the various products oxide filter materials, such as cordierite and aluminum titanate, are gaining growing interest due to their unique properties. Besides the intrinsic robustness of the filter products a well designed operating strategy is required for the successful use of filters. The operating strategy is comprised of two elements: the soot estimation and the regeneration strategy. In this paper the second element is discussed in detail by means of theoretical considerations as well as dedicated engine bench experiments. The impact the key operating variables, soot load, exhaust mass flow, oxygen content and temperature, have on the conditions inside the filter are discussed.

Driven by the worldwide automotive emission regulations, ceramic substrates were developed to serve as catalyst support. Since the introduction of Standard wall substrates in 1974, substrates with thinner walls and higher cell densities have been developed to meet the tighter emission requirements; Worldwide, the amount of Thinwall and Ultrathinwall substrates in series applications is increasing continuously. The properties of the substrates determine their performance regarding pressure drop, heat-up and conversion efficiency. These properties are analyzed, as well as the packaging process for Thinwall and Ultrathinwall substrates; A new packaging technique with lower pressure load is described.

With the start of EU6 in 2017 gasoline particulate filters (GPF) have been introduced to production vehicles. It is expected that by 2019 all gasoline direct injection engines sold in Europe will be equipped with a GPF. A similar trend is observed in China with a slight delay compared to Europe, but covering all gasoline engines, including those with port fuel injection technology. With the introduction of GPFs, new requirements are introduced to the management of gasoline engines and their aftertreatment. One requirement is to protect the aftertreatment components from excessive temperatures and damage as result of uncontrolled soot oxidations. While the general fundamentals are similar to those in diesel applications, significant differences exist in the relevant details.

With the start of Euro 6d regulations, gasoline particulate filters (GPF) have become standard equipment in European vehicles with gasoline-direct-injection engines. GPFs will also be broadly applied to meet the upcoming China 6 regulations. An existing challenge with GPFs is accurate soot load detection to manage the pressure loss across the exhaust system and to protect the GPFs from soot overload, which could potentially cause damage as result of uncontrolled soot oxidations. Systems with the GPF located in the under-floor position have a higher potential risk of soot overload due to lower temperatures, which can result in higher soot accumulation rates. The accuracy of existing soot estimation methods such as evaluation of the pressure drop of the soot-loaded GPF or model-based balancing of soot accumulation versus soot oxidation rates are sensitive to transient operating condition of a vehicle.

The ever-tightening regulation norms across the world emphasize the magnitude of the air pollution problem. The decision to leapfrog from BS4 to BS6 – with further reduction in emission limits -showed India’s commitment to clean up its atmosphere. The overall cycle emissions were reduced significantly to meet BS6 targets [1]. However, the introduction of RDE norms in BS6.2 [1] demanded further reduction in emissions under real time operating conditions – start-stop, hard acceleration, idling, cold start – which was possible only through strategies that demanded a cost effective yet robust solutions. The first few seconds of the engine operation after start contribute significantly to the cycle gaseous emissions. This is because the thermal inertia of the catalytic converter restricts the rate at which temperature of the catalyst increases and achieves the desired “light-off” temperature.