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To meet tightening emissions standards, alternate pollution abatement technologies are necessary, such as an In-Line Adsorber (ILA) system. The ILA has a first catalyst, an adsorber, and a second catalyst. A diverter directs exhaust gas through the adsorber to capture unconverted hydrocarbons until the first catalyst reaches light-off temperature. The ILA system was designed so that the second catalyst becomes active concurrent with the adsorber hydrocarbon desorption. The system was evaluated using the FTP test with two different secondary air strategies on 3.8 liter V6 and 4.0 liter V8 vehicles. The ILA system performance consistently reduced ∼50-60% of cold start hydrocarbon emissions. This study examined a simplified ILA system designed to operate with a commercial secondary air pump powered by the engine.

There is currently a need for a practical solution for NOx abatement in automotive diesel engines. Technologies developed thus far suffer from inherent technical limitations. The selective catalytic reduction (SCR) of NOx under lean conditions has been proven to be successful for stationary applications. A new approach is described to efficiently remove NOx from the exhaust of a diesel engine powered vehicle and convert it to nitrogen and oxygen. The key to the approach is the development of an on board (in-situ) ammonia generating catalyst. The ammonia is then used as a reagent to react with exhaust NO over a secondary SCR catalyst downstream. The system can remove over 85% of the exhaust NO under achievable diesel engine operating conditions, while eliminating the potential for ammonia slip with a minimal system of sensors and feedback controls.

The present work intends to examine the selective NOx reduction efficiency of a current commercial Titanium-Vanadium washcoated catalyst and to develop a transient numerical model capable of describing the SCR process while using a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration and NO2/NO ratio. The concentrations of different components (NO, NO2, N2O, NH3, H2O and HNO3) were analyzed continuously by a FT-IR spectrometer. A temperature range from 150°C up to 650°C was examined and tests were carried out using a model exhaust gas comparable to the real diesel exhaust gas composition. There is a very good correlation between experimental and calculated results with the given chemical kinetics.

In this paper we present a comparison of two different approaches to model three-way catalyst. First, a numerical sample case simulating light-off is used to compare the 1D and the 2D models. The advantages of each code are discussed with respect to required input data, detail level of the output, comparability, and computation time. Thus, the 2D model reveals significant radial temperature gradients inside the monolith during light-off. In a second step, the 2D model is compared with experimental data. One set of data consists of an air/fuel ratio varying sweep at isothermal conditions. Another set was gained by emission measurements during a real driving MVEG tests with varying substrate cell density & inlet conditions. From these experiments the applicability of the model to numerical parameter studies is discussed.