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Pre- and post-catalyst Exhaust Gas Oxygen (EGO) sensors are traditionally used to monitor oxygen storage capacity for On Board Diagnostic (OBD) purposes. In this paper the same sensors are used instead to monitor catalyst-promoted hydrogen generation, exploiting the sensor's otherwise undesirable sensitivity to the hydrogen content in the exhaust. This offers a new approach to catalyst health diagnosis since hydrogen generation and HC conversion efficiency both depend on the degree of activation (or deactivation) of the catalyst surface, and are therefore strongly correlated to each other. The approach has the advantage that it is more directly related to catalyst deterioration or malfunction as defined (in terms of HC emissions levels) under current OBD legislation.

Reversible catalyst deactivation dynamics can have a significant effect on both conversion efficiency and post-catalyst EGO sensor distortion, yet are often ignored in conventional oxygen storage modeling for on-board catalyst control and OBD systems. The aim of the present paper is to include these dynamics in an extended model which exploits the otherwise unfortunate effects of sensor distortion to provide a measure of catalyst deactivation, and hence obtain more accurate predictions of conversion efficiency. Furthermore, by fitting the combined oxygen storage and reversible deactivation model to the data, unbiased estimates of the true post-catalyst AFR can be obtained which are then available for improved catalyst control and diagnostic strategies.