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The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

The increasingly stringent regulations for fuel economy and emissions require better optimization and control of oil consumption. One of the primary mechanisms of oil consumption is vaporization from the liner; we consider this as the “minimum oil consumption (MOC).” This paper presents a physical-mathematical cycle model for predicting the MOC. The numerical simulations suggest that the MOC is markedly sensitive to oil volatility, liner temperature, engine load and speed but less sensitive to oil film thickness. A one-line correlation is proposed for quick MOC estimations. It is shown to have <15% error compared to the cycle MOC computation. In the “dry region” (between top ring and OCR at the TDC), oil is depleted due to high heat and continual exposure to the combustion chamber.

This paper describes the use of a modified quasi-dimensional spark-ignition engine simulation code to predict the extent of cycle-to-cycle variations in combustion. The modifications primarily relate to the combustion model and include the following: 1. A flame kernel model was developed and implemented to avoid choosing the initial flame size and temperature arbitrarily. 2. Instead of the usual assumption of the flame being spherical, ellipsoidal flame shapes are permitted in the model when the gas velocity in the vicinity of the spark plug during kernel development is high. Changes in flame shape influence the flame front area and the interaction of the enflamed volume with the combustion chamber walls. 3. The flame center shifts due to convection by the gas flow in the cylinder. This influences the flame front area through the interaction between the enflamed volume and the combustion chamber walls. 4. Turbulence intensity is not uniform in cylinder, and varies cycle-to-cycle.

The direct injection spark-ignition engine is the only internal combustion engine with the potential to equal the efficiency of the diesel and to tolerate a wide range of fuel types and fuel qualities without deterioration of performance. However, this engine has low combustion efficiency and excessive hydrocarbon emissions when operating at light load. In this paper, potential sources of hydrocarbon emissions during light load operation are postulated and analyzed. The placement of fuel away from the primary combustion process in conjunction with a lack of secondary burnup are isolated as important hydrocarbon emissions mechanisms. Analyses show that increasing cylinder gas temperatures can improve secondary burnup of fuel which would reduce hydrocarbon emissions. Practical means to achieve this include higher compression ratio and use of ceramic parts in the combustion chamber.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

The engine-out (EO) total and speciated hydrocarbon emissions data from the Auto-Oil Program Phase II Heavy Hydrocarbon Study had been analyzed. The methodology was to first investigate the stabilized EO emissions (Bag 2) of a specific vehicle (Vehicle 04B, a 1989 Model Year Ford Taurus); then the vehicle-to-vehicle differences in Bag2 emissions were considered. Finally, the differences in the Bag2 and the starting/warm-up EO emissions (Bag1) were examined. The speciated emissions may be interpreted as a “feed-through” part due to the unreacted fuel species, and an “offset” part due to the decomposition products. The significant non-fuel emitted species were methane and the olefins. The HC emissions for vehicles with different total emissions were similar in species composition. For both the total and speciated emissions, there was no substantial difference between the Bag1 and Bag2 values for Vehicle 04B.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

A dynamometer-mounted four-cylinder Saturn engine was used to accumulate combustion chamber deposits (CCD), using an additized fuel. During each deposit accumulation test, the HC emissions were continuously measured. The deposit thickness at the center of the piston was measured at the beginning of each day. After the 50 and 35-hour tests, HC emissions were measured with isooctane, benzene, toluene, and xylene, with the deposited engine, and again after the deposits had been cleaned from the engine. The HC emissions showed a rapid rise in the first 10 to 15 hours and stabilization after about 25 hours of deposit accumulation. The HC increase due to CCD accumulation accounted for 10 to 20% of the total engine-out HC emissions from the deposit build-up fuel and 10 to 30% from benzene, isooctane, toluene, and xylene, making CCDs a significant HC emissions source from this engine. The HC emissions stabilized long before the deposit thickness.

Understanding oil transport mechanisms is critical to developing better tools for oil consumption and piston skirt lubrication [1]. Our existing Two-Dimensional Laser Induced Fluorescence (2DLIF) system with an acquisition rate of 1 frame every one or two cycles was proven to be effective to display oil accumulation patterns and their evolution over many cycles in the piston ring pack system [2,3,4]. Yet, the existing system is unable to resolve instantaneous oil flow patterns in the piston-liner interface. In this work, a high-speed LIF system was developed. After a number of iterations the finalized high speed LIF system includes a 23 W, 100 kHz, 532 nm laser and a high speed camera capable of 100,000 FPS at 384 × 264 pixel resolution. After each component was selected, optimization of the quality of images taken from the system began.

Inorganic engine lubricant additives, which have various specific, necessary functions such as anti-wear, leave the combustion chamber bound to soot particles (approximately ≤1% by mass) as ash [13], and accumulate in aftertreatment components. The diesel particulate filter (DPF) is especially susceptible to ash-related issues due to its wall-flow architecture which physically traps most of the soot and ash emissions. Accumulated lubricant-derived ash results in numerous problems including increased filter pressure drop and decreased catalytic functionality. While much progress has been made to understand the macroscopic details and effects of ash accumulation on DPF performance, this study explores the nano- and micron-scale forces which impact particle adhesion and mobility within the particulate filter.

The characteristics of the early development of fuel sprays from pressure swirl atomizer injectors of the type used in direct injection gasoline engines is investigated. Planar laser-induced fluorescence (PLIF) was used to visualize the fuel distribution inside a firing optical engine. The early spray development of three different injectors at three different fuel pressures (3, 5, and 7 MPa) was followed as a function of time in 30 μsec intervals. Four phases could be identified: 1) A delay phase between the rising edge of the injection pulse and the first occurrence of fuel in the combustion chamber, 2) A solid jet or pre-spray phase, in which a poorly atomized stream of liquid fuel during the first 150 μsec of the injection. 3) A wide hollow cone phase, separation of the liquid jet into a hollow cone spray once sufficient tangential velocity has been established and 4) A fully developed spray, in which the spray cone angle is narrowed due to a low pressure zone at the center.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

Smoke is emitted in diesel engines because fuel injected into the combustion chamber burns with insufficient oxygen. The emission smoke from diesel engines is a very important air pollution problem. Smoke emission, which is believed to be largely related to the diffusion combustion in diesel engines, results from pyrolysis of fuel not mixed with air. Therefore, the smoke emission is dependent on diffusion combustion phenomena, which are controlled by engine parameters. This paper presents an analysis of combustion by relating the smoke emission with heat release in diesel engines. An analysis is made of the diffusion combustion quantity, the smoke emission, and the fraction of diffusion combustion as related to the engine parameters which are air-fuel ratio, injection timing, and engine speed.

Intake valve thermal behavior was observed across a wide range of operating conditions while running an engine on both propane and gasoline. Compared to the gaseous fuel, the liquid fuel operation has cooler valve temperatures (∼50-100C difference) and there is significant temperature gradient across the valve surface due to liquid fuel impinging on the front quadrant of the valve. The valve warm-up time is largely determined by the effective thermal inertia of the valve (∼valve body plus 1/3 of stem mass) and the thermal resistance to the seat. The valve is heated up by the combustion chamber; the dominant cooling paths are through the seat contact and the liquid fuel evaporation. Just after starting, very little fuel evaporates from the cold valve until there is a substantial increase in valve temperature in a period of approximately 10-20 seconds.

This paper evaluates the lag time in a turbocharged single cylinder engine in order to determine its viability in transient applications. The overall goal of this research is to increase the power output, reduce the fuel economy, and improve emissions of single cylinder engines through turbocharging. Due to the timing mismatch between the exhaust stroke, when the turbocharger is powered, and the intake stroke, when the engine intakes air, turbocharging is not conventionally used in commercial single cylinder engines. Our previous work has shown that it is possible to turbocharge a four stroke, single cylinder, internal combustion engine using an air capacitor, a large volume intake manifold in between the turbocharger compressor and engine intake. The air capacitor stores compressed air from the turbocharger during the exhaust stroke and delivers it during the intake stroke.

In internal combustion engines, a portion of liquid fuel spray may directly land on the liner and mix with oil (lubricant), forming a fuel-oil film (~10μm) that is much thicker than the original oil film (~0.1μm). When the piston retracts in the compression stroke, the fuel-oil mixture may have not been fully vaporized and can be scraped by the top ring into the 1st land crevice and eventually enter the combustion chamber in the format of droplets. Studies have shown that this mechanism is possibly a leading cause for low-speed pre-ignition (LSPI) as the droplets contain oil that has a much lower self-ignition temperature than pure fuel. In this interest, this work aims to study the oil-fuel interactions on the liner during an engine cycle, addressing molecular diffusion (in the liquid film) and vaporization (at the liquid-gas interface) to quantify the amount of fuel and oil that are subject to scraping by the top ring, thereby exploring their implications on LSPI and friction.

A technique has been developed to measure the desorption and subsequent oxidation of fuel in the oil layer by spiking the oil with liquid fuel and firing the engine on gaseous fuel or motoring with air. Experiments suggest that fuel desorption is not diffusion limited above 50 °C and indicated that approximately two to four percent of the cylinder oil layer is fresh oil from the sump. The increase in hydrocarbon emissions is of the order of 100 ppmC1 per 1% liquid fuel introduced into the fresh oil in a methane fired engine at mid-speed and light load conditions. Calculations indicate that fuel desorbing from oil is much more likely to produce hydrocarbon emissions than fuel emerging from crevices.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

In order to understand why emissions of Particulate Matter (PM) from Spark-Ignition (SI) automobiles peak during periods of transient operation such as rapid accelerations, a study of controlled, repeatable transients was performed. Time-resolved engine-out PM emissions from a modern four-cylinder engine during transient load and air/fuel ratio operation were examined, and the results could be fit in most cases to a first order time response. The time constants for the transient response are similar to those measured for changes in intake valve temperature, reflecting the strong dependence of PM emissions on the amount of liquid fuel in the combustion chamber. In only one unrepeatable case did the time response differ from a first order function: showing an overshoot in PM emissions during transition from the initial to the final steady state PM emission level.

Photographic and performance studies with a Rapid Compression Machine at the Massachusetts Institute of Technology have been used to develop insight into the role of mixing in diesel engine combustion. Combustion photographs and performance data were analyzed. The experiments simulate a single fuel spray in an open chamber diesel engine with direct injection. The effects of droplet formation and evaporation on mixing are examined. It is concluded that mixing is controlled by the rate of entrainment of air by the fuel spray rather than the dynamics of single droplets. Experimental data on the geometry of a jet in a quiescent combustion chamber were compared with a two-phase jet model; a jet model based on empirical turbulent entrainment coefficients was developed to predict the motion of a fuel jet in a combustion chamber with swirl. Good agreement between theory and experiment was obtained.