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The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

A characteristic mechanism of in-cylinder combustion is “time-domain mixing” which mixes up unburned gas, products in the different stages of combustion process, and burned gas, by “eddy”, a flow component with its scales of several to 10 mm. It seems to play a role in completing the combustion. Now that direct injection is a central engine technology, a keyword to combustion control is “freedom of mixing”, that is, no restriction on mixture formation, realized by direct injection. Various kinds of combustion control technologies utilizing it, have been presented. After combustion control for a premixed leanburn gasoline engine, and a direct injection gasoline engine, was achieved by turbulence control, and mixing control, respectively, the next target of combustion control will be ignition control. It will be possible, by controlling some boundary condition on combustion and fuel chemistry. Time-domain mixing and freedom of mixing will support it.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

A Finite Element Method (FEM) simulation was conducted to predict energy-absorbing characteristics in an impact of a head form against plastic plates. Static and dynamic material tests were conducted in order to determine material properties of the plastics. The properties were applied in an explicit FEM code. The FEM results were validated through the impact tests by the head form against the same plastic plates. It was proved that the FEM could simulate the test result well, when the precise material properties were introduced in the simulation. The method can be expected to be available to predict energy-absorbing characteristics during the impact by the head form against automobile plastic components such as shell portions of instrument panels.

The accuracy of real-time A/F measurement at engine test benches has been improved with a modified equation to calculate A/F from exhaust gas composition. In addition to CO, CO2, total hydrocarbon (THC) and O2, the proposed equation includes NO and NO2 concentration as variables. In an attempt to improve the accuracy of the assumed constants in the equation, experiments have been conducted using automotive exhaust H2O and H2 analyzers. The accuracy of the proposed equation was proven through experiments and it was also found useful for precise evaluation of three-way catalyst or oxygen sensor characteristics.

Applying micro-alloyed steel as a cost-effective method of forging engine parts eliminates quench and temper processes and saves energy. We have expanded this application to timing gears and crankshafts by changing the connecting rod material to carbon steel and vanadium, applied at the outset. Then, micro-alloyed steel treated with a soft nitriding process was used. Our recent studies have been focused on materials which exhibit both higher tensile strength and better machinability. This paper describes the results of applying different types of micro-alloyed steel to those engine parts.

Several different steel sheets were tested for energy absorption, using hat square columns and dynamic crash testing. Results indicate that steel sheets containing large volume fraction of retained austenite have relatively high energy absorption. The relationship between retained austenite and energy absorption was analyzed. These special steel sheets have already been successfully used for production body parts, such a front-side-member, without difficulties arising in volume production.

The adoption of the diesel engine EGR systems, and increased uses of alcohol in spark ignited engines require wear resistant and low maintenance valve trains. Silicon nitride ceramic inserts were pressureless-sintered and successfully die-cast in rocker arms contacting the overhead cams in the valve trains. As fired, the insert sliding surface was fine and precise, eliminating any further processing. The comosite structure was machined with the sliding surface as a reference plane. Beside inherent high wear resistance, these lighter inserts reduced inertial forces of the trains and the torque required to drive the cams. The hard, brittle ceramics and a softer, more elastic aluminum alloy made the structure more durable and reliable. The process of development includes characterization, screening, manufacturing and quality control of the materials, and determination of wear resistance and reliability for this new structure.

The authors developed, for use in diesel engines, ceramic tappets cast in aluminum alloy that drastically improved wear resistance and valve train dynamics. The ceramic tappets consist of two parts: a ceramic head, which contacts the cam and push rod, and a tappet body made of aluminum alloy. Concerning the ceramic, silicon nitride was the best material of the three ceramics evaluated in the tests and the sliding surface, in contact with the cam and push rod, was left unground. As for the aluminum alloy, hyper-eutectic aluminum-silicon alloy with a controlled pro-eutectic silicon size was selected. A reliability analysis using the finite-element method (FEM) was also made on the structure of the ceramic tappet for enhanced durability and reliability. The combination of this tappet and a cam made of hardened ductile cast iron, hardened steel, or chilled cast iron, respectively exhibits excellent wear resistance.

This paper describes a calculating method to predict the quasi-static collapsing behaviors of spot-welded closed-hat section curved beams under axial compression. The overall deformat ions and the local buckling modes of beams were calculated using a geometrical model. Force-displacement relations were predicted by a elastic-plastic structural analysis method using the ‘plastic hinge’ concept. Collapsing tests were made on beams which are differenting section size, rotation angle, and metal sheet thickness. Comparisons between the calculated and experimental results of deformed shapes of beams, the local buckling modes and the force displacement relations are discussed.

An investigation of anti-corrosion steel sheets (non-galvanized) which contain copper for automobile body parts has been conducted. Copper additives accelerate the formation of amorphous substrates. These substrates decrease the rate of corrosion. In order to retain the steel's formability and weldability, the contents of the alloying elements have been optimized. As a result, this newly developed steel sheet can be used for many different applications such as door sashes and door panels of mass produced cars. This paper describes the key properties of the newly developed steel sheet and additionally the mechanism of corrosion prevention, weldability, formability, and so on.

Austempered ductile iron (ADI) is a material having excellent mechanical properties and damping capacity. However practical mass production of ADI gears has not been possible due to ADI's poor machinability and distortion during the austempering heat treatment. With a new process method of carrying out hobbing before austempering when the material is in its soft condition, then austempering it and lastly, conducting the shave finishing process, we have diminished the above defects and developed practical ADI gears. These new gears generate less noise than ordinary nitrocarburized steel gears and are superior in pitting resistance.

When replacing a metal engine part with plastic, it is necessary to regard vibration damping as one of the important factors in terms of noise reduction as well as strength and heat resistance as being characteristics of the material. Plastics are far better for vibration damping than steel or aluminum, but this property is reduced by the addition of glassfiber-reinforced or high heat-resisting resins. We have taken notice of SMC (Sheet Molding Compound) which has the excellent strength and heat resistance properties and studied it in order to increase its vibration damping property. Since organic polymers show the peak value for vibration damping performance in the vicinity of the glass transition temperature (Tg), we studied a method to shift the Tg near the operating temperature region in order to improve the vibration damping property.

A particulate trap oxidizer system to reduce diesel particulate emissions has been developed. This system consists of a ceramic foam filter with an optimum volume, shape, and mesh number in terms of collection efficiency, pressure loss and particulate blow-off; a catalyst with a low activated-temperature for particulate incineration and with no sulfate formation during highway driving; and a regeneration system which prevents particulate overcollection during long-term continuous low-load/low-speed driving where it is difficult to achieve self-burning of particulates with a catalytic reaction. This paper describes the development of the particulate trap oxidizer system with these technologies and presents the results of practicability evaluations and 50,000-mile vehicle durability tests.

We have developed a tappet with a cam lobe contacting tip made of a hard sintered material whose base material is cobalt, which adheres less to the steel of camshafts, and which also contains fine particles of tungsten carbide and chrome carbide. We have established a new evaluation method to access wear resistance performance of the tappet. It enables us to measure directly the friction force generated between the cam lobe and tappet and to evaluate anti-scuffing performance with high accuracy because we can clarify the time, load and cam angle at which scuffing occures.

In this study, the oxidation stability, soot dispersancy, antiwear performance, and friction-reducing capability of friction modifiers (FMs) were evaluated, and an SAE 5W-30 fully synthetic oil with MoDTC type FMs was developed for heavy-duty diesel engines. In several engine tests, it was confirmed that the developed oil can double the oil drain interval in comparison with API CD SAE 30, even when EGR is applied, and improves the fuel efficiency.

Beta Ti alloy valve spring retainers are newly developed for use in mass produced automobiles for the first time. Ti alloy valve spring retainers vith a weight saving of 42%, compared to steel retainers, have reduced the inertial weight of the valve train components by 6%. And this weight reduction has the benefit of increasing the upper limit of the engine speed, which improves the engine performance. Ti alloy valve spring retainers are cold forged by the conventional fabrication facilities for steel retainers, using Ti-22V-4Al (the beta Ti alloy) which possesses excellent cold workability in a solution treated condition. Oxygen surface hardening is applied to protect Ti alloy valve spring retainers from wear damage. In addition, aging treatment and shot blasting are performed to improve strength and stiffness of valve retainers.

It is well-known that double-mass torsional rubber dampers which have two masses and springs in parallel are effective for controlling torsional vibration characteristics over a wide range of engine speed. On the occasion of reliability estimation of the rubber dampers, it is important to consider generation of heat in the rubber due to torsional vibration. By predicting generation of heat at the designing stage, optimum design of the torsional rubber dampers can be achieved. By development and application of this prediction method, a new type double-mass damper was developed. It provided higher vibration control characteristics and reliability than conventional viscous dampers, and also it provided advantages in terms of noise, productivity and weight.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

At Mitsubishi Motors, a thin-walled exhaust manifold, made of stainless cast-steel, has been developed with the aim of achieving higher heat-resisting reliability as well as weight reduction. The new exhaust manifold is made of ferritic stainless cast-steel, employing an advanced vacuum casting (CLAS). Its geometry was designed using finite element analysis and its durability was confirmed by testing both on various test devices and on a vehicle. The exhaust manifolds has been adopted on a production engine model and has proven the following advantages over a conventional cast-iron ones; excellent heat resistance. weight reduction of over 20%. possible exhaust emission reduction as a result of lower heat-capacity of the exhaust manifold.