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The Spacesuit Water Membrane Evaporator (SWME) is the baseline heat rejection technology selected for development for the Constellation lunar suit. The first SWME prototype, designed, built, and tested at Johnson Space Center in 1999 used a Teflon hydrophobic porous membrane sheet shaped into an annulus to provide cooling to the coolant loop through water evaporation to the vacuum of space. This present study describes the test methodology and planning to compare the test performance of three commercially available hollow fiber materials as alternatives to the sheet membrane prototype for SWME, in particular, a porous hydrophobic polypropylene, and two variants that employ ion exchange through non-porous hydrophilic modified Nafion. Contamination tests will be performed to probe for sensitivities of the candidate SWME elements to ordinary constituents that are expected to be found in the potable water provided by the vehicle, the target feedwater source.

A Total Organic Carbon (TOC) Analyzer has been developed for a Life Sciences Risk Mitigation Flight Experiment to be conducted on Spacehab and the Russian space station, Mir. Initial launch is scheduled for December 1996 (flight STS-81). The analyzer will be tested on the Orbiter in the Spacehab module, including when the Orbiter is docked at the Mir space station. The analyzer is scheduled to be launched again in May 1997 (STS-84) when it will be transferred to Mir. During both flights the analyzer will measure the quality of recycled and ground-supplied potable water on the space station. Samples will be archived for later return to the ground, where they will be analyzed for comparison to in-flight results. Water test samples of known composition, brought up with the analyzer, also will be used to test its performance in microgravity. Ground-based analyses of duplicates of those test samples will be conducted concurrently with the in-flight analyses.

Reduction of metabolic carbon dioxide is one of the essential steps in physiochemical air revitalization for long-duration manned space missions. Under contract with NASA Johnson Space Center, Hamilton Standard is developing an Advanced Carbon Reactor Subsystem (ACRS) to produce water and dense solid carbon from carbon dioxide and hydrogen. The ACRS essentially consists of a Sabatier Methanation Reactor (SMR) to reduce carbon dioxide with hydrogen to methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolyze methane to carbon and hydrogen. The hydrogen is recycled to the SMR, while the produce carbon is periodically removed from the CFR. The SMR is well-developed, while the CFR is under development. In this paper, the fundamentals of the SMR and CFR processes are presented and results of Breadboard CFR testing are reported.

Two simulated spacecraft water systems are being used to evaluate the effectiveness of iodine for controlling microbial contamination within such systems. An iodine concentration of about 2.0 mg/L is maintained in one system by passing ultrapure water through an iodinated ion exchange resin. Stainless steel coupons with electropolished and mechanically-polished sides are being used to monitor biofilm formation. Results after three years of operation show a single episode of significant bacterial growth in the iodinated system when the iodine level dropped to 1.9 mg/L. This growth was apparently controlled by replacing the iodinated ion exchange resin, thereby increasing the iodine level. The second batch of resin has remained effective in controlling microbial growth down to an iodine level of 1.0 mg/L. Scanning electron microscopy indicates that the iodine has impeded but may have not completely eliminated the formation of biofilm.

Recovery of potable water from wastewater is essential for the success of long-term manned missions to the moon and Mars. Honeywell International and the team consisting of Thermodistillation Company (Kyiv, Ukraine) and NASA Johnson Space Center (JSC) Crew and Thermal Systems Division are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The Wastewater Processing Cascade Distillation Subsystem (CDS) utilizes an innovative and efficient multi-stage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage prototype of the subsystem was built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for development testing.

The Shuttle Orbiter humidity control and carbon dioxide removal system for extended duration missions presently uses a solid amine called HS-C. This August, on board STS-62, a new solid amine called HS-C+ will be used. HS-C+ uses the same amine and the substrate material, but a different preparation process. Forty-seven breakthrough tests have been conducted to characterize the performance of HS-C+. CO2 partial pressure, bed temperature, and H2O partial pressure were varied. Eleven HS-C breakthrough tests were also run to provide a direct comparison. Under all conditions tested, HS-C+ outperformed HS-C. Both materials adsorb all CO2 and H2O available at the start of a test when the beds are fully desorbed. As the bed becomes partially loaded, the CO2 and H2O adsorption rates decrease rapidly. HS-C+ continues adsorbing all CO2 and H2O available for a longer time. Greater surface area on HS-C+ may cause the improved performance.

Humidity condensate collected and processed in-flight is an important component of a space station drinking water supply. Water recovery systems in general are designed to handle finite concentrations of specific chemical components. Previous analyses of condensate derived from spacecraft and ground sources showed considerable variation in composition. Consequently, an investigation was conducted to collect condensate on the Shuttle while the vehicle was docked to Mir, and return the condensate to Earth for testing. This scenario emulates an early ISS configuration during a Shuttle docking, because the atmospheres intermix during docking and the condensate composition should reflect that. During the STS-89 and STS-91 flights, a total volume of 50 liters of condensate was collected and returned. Inorganic and organic chemical analyses were performed on aliquots of the fluid.

Twenty-nine recycled water, eight stored (ground-supplied) water, and twenty-eight humidity condensate samples were collected on board the Mir Space Station during the Phase One Program (1995-1998). These samples were analyzed to determine potability of the recycled and ground-supplied water, to support the development of water quality monitoring procedures and standards, and to assist in the development of water reclamation hardware. This paper describes and summarizes the results of these analyses and lists the lessons learned from this project. Results show that the recycled water and stored water on board Mir, in general, met NASA, Russian Space Agency (RSA), and U.S. Environmental Protection Agency (EPA) standards.

Approximately 50% of the water consumed by International Space Station crewmembers is water recovered from cabin humidity condensate. Condensing heat exchangers in the Russian Service Module (SM) and the United States On-Orbit Segment (USOS) are used to control cabin humidity levels. In the SM, humidity condensate flows directly from the heat exchanger to a water recovery system. In the USOS, a metal bellows tank located in the US Laboratory Module (LAB) collects and stores condensate, which is periodically off-loaded in about 20-liter batches to Contingency Water Containers (CWCs). The CWCs can then be transferred to the SM and connected to a Condensate Feed Unit that pumps the condensate from the CWCs into the water recovery system for processing. Samples of the condensate in the tank are collected during the off-loads and returned to Earth for analyses.

Potable- and hygiene-quality water will be supplied to crews on the International Space Station through the recovery and purification of spacecraft wastewaters, including humidity condensate, urine, and wash water. Contaminants released into the cabin air from human metabolism, hardware offgassing, flight experiments, and routine operations will be present in spacecraft humidity condensate; normal constituents of urine and bathing water will be present in urine and untreated wash water. This report describes results from detailed analyses of Mir reclaimed potable water, ground-supplied water, and humidity condensate. These results are being used to develop and test water recycling and monitoring systems for the International Space Station (ISS); to evaluate the efficiency of the Mir water processors; and to determine the potability of the recycled water on board.

A reliable nutrient delivery system is essential for long-term cultivation of plants in space. At the Kennedy Space Center, a series of ground-based tests are being conducted to compare candidate plant nutrient delivery systems for space. To date, our major focus has concentrated on the Porous Tube Plant Nutrient Delivery System, the ASTROCULTURE™ System, and a zeoponic plant growth substrate. The merits of each system are based upon the performance of wheat supported over complete growth cycles. To varying degrees, each system supported wheat biomass production and showed distinct patterns for plant nutrient uptake and water use.

This paper describes the development of a membrane-based dehumidification process for space-based applications, such as spacecraft cabins and extra-vehicular-activity (EVA) space suits. Results presented are from 1) screening tests conducted to determine the efficacy of various membranes to separate water vapor from air, and 2) parametric and long-term tests of membranes operated at conditions that simulate the range of environmental conditions (e.g., temperature and relative humidity [RH]) expected in the planned space station. Also included in this paper is a discussion of preliminary designs of membrane-based dehumidification processes for the space station and EVA space suits. These designs result in compact and energy-efficient systems that offer significant advantages over conventional dehumidification processes.

A phase change material (PCM) heat sink using super cooled ice as a non-toxic, non-flammable PCM is being developed for use in a portable life support system (PLSS). The latent heat of fusion for water is approximately 70% larger than most paraffin waxes, which can provide significant mass savings. Further mass reduction is accomplished by super cooling the ice significantly below its freezing temperature for additional sensible heat storage. Expansion and contraction of the water as it freezes and melts is accommodated with the use of flexible bag and foam materials. A demonstrator unit has been designed, built, and tested to demonstrate proof of concept. Both testing and modeling results are presented.

The Space Shuttle humidity separator prefilter was developed to remove debris from the air/water stream that flows from the cabin condensing heat exchanger to the humidity separator. Debris in this flow stream has caused humidity separator pitot tube clogging and subsequent water carryover on several Shuttle flights. The first design concept of the prefilter was flown on STS-40 in June, 1991. The prefilter was installed on-orbit. Video footage of its operation revealed that the prefilter did not pass water at a constant rate, resulting in a tendency to slug the humidity separator. The results from this flight test have resulted in a complete redesign of the prefilter. In this paper the first prefilter design is described, the flight results from STS-40 are examined, and the on-orbit performance of the prefilter is explained. The redesigned prefilter is described with emphasis on the features that should allow successful reduced gravity operation.

Supply of oxygen (O2) and hydrogen (H2) by electrolyzing water in space will play an important role in meeting the National Aeronautics and Space Administration's (NASA's) needs and goals for future space missions. Both O2 and H2 are envisioned to be used in a variety of processes including crew life support, spacecraft propulsion, extravehicular activity, electrical power generation/storage as well as in scientific experiment and manufacturing processes. Life Systems, Inc., in conjunction with NASA, has been developing an alkaline-based Static Feed Electrolyzer (SFE). During the development of the water electrolysis technology over the past 23 years, an extensive engineering and scientific data base has been assembled.

The removal of dissolved ions from waste water is essential for water repurification on long-term human space missions. Lynntech, Inc., has demonstrated a novel electrochemically driven purification method using tubulated bipolar ion exchange membranes for the separation of dissolved inorganic impurities as well as charged organic species from waste water. Generally, electrochemical separation methods have limited applications since they can only be applied to the purification of water that has a sufficiently high dissolved ion content to make the water conductive. The novel tubulated bipolar membranes composed of bilayers of oppositely charged ionically conducting polymers can be used to overcome this limitation. This paper deals with the scaling-up of such a device to increase the throughput to process about 100 liters of waste water per day. This is achieved by using stacks of tubulated bipolar membranes.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

Metabolically produced carbon dioxide (CO2) removal in spacesuit applications has traditionally been accomplished utilizing non-regenerative Lithium Hydroxide (LiOH) canisters. In recent years, regenerative Metal Oxide (MetOx) has been developed to replace the Extravehicular Mobility Unity (EMU) LiOH canister for extravehicular activity (EVA) missions in micro-gravity, however, MetOx may carry a significant weight burden for potential use in future Lunar or planetary EVA exploration missions. Additionally, both of these methods of CO2 removal have a finite capacity sized for the particular mission profile. Metabolically produced water vapor removal in spacesuits has historically been accomplished by a condensing heat exchanger within the ventilation process loop of the suit life support system.

The work presented in this paper summarizes the early results of an integrated advanced water recovery system test conducted by the Crew and Thermal Systems Division (CTSD) at NASA-Johnson Space Center (JSC). The system design and the results of the first two months of operation are presented. The overall objective of this test is to demonstrate the capability of an integrated advanced water recovery system to produce potable quality water for at least six months. Each subsystem is designed for operation in microgravity. The primary treatment system consists of a biological system for organic carbon and ammonia removal. Dissolved solids are removed by reverse osmosis and air evaporation systems. Finally, ion exchange technology in combination with photolysis or photocatalysis is used for polishing of the effluent water stream. The wastewater stream consists of urine and urine flush water, hygiene wastewater and a simulated humidity condensate.

An evaporative heat sink has been designed and built by AlliedSignal for NASA's Johnson Space Center. The unit is a demonstrator of a primary heat exchanger for NASA's prototype Crew Return Vehicle (CRV), designated the X-38. The primary heat exchanger is responsible for rejecting the heat produced by both the flight crew and the avionics. Spacecraft evaporative heat sinks utilize space vacuum as a resource to control the vapor pressure of a liquid. For the X-38, water has been chosen as the heat transport fluid. A portion of this coolant flow is bled off for use as the evaporant. At sufficiently low pressures, the water can be made to boil at temperatures approaching its freezing point. Heat transferred to liquid water in this state will cause the liquid to evaporate, thus creating a heat sink for the spacecraft's coolant loop. The CRV mission requires the heat exchanger to be compact and low in mass.