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A fuel design concept for an HCCI engine based on chemical kinetics to optimize the heat release profile and achieve robust ignition was proposed, and applied to the design of the optimal methane-based blend. Ignition process chemistry of each single-component of natural gas, methane, ethane, propane, n-butane and isobutane, was analyzed using detailed chemical kinetic computations. Ethane exhibits low ignitability, close to that of methane, when the initial temperature is below 800 K, but higher ignitability, close to those of propane, n-butane and isobutane, when the initial temperature is above 1100 K. Furthermore, ethane shows a higher heat release rate during the late stage of the ignition process. If the early stage of an ignition process takes place during the compression stroke, this kind of heat release profile is desirable in an HCCI engine to reduce cycle-to-cycle variation during the expansion stroke.

This study tried to find a potential of dedicated EGR (d-EGR) system added to the four-cylinder spark ignition (SI) engine to decrease heat loss (Qheatloss) and improve thermal efficiency (ηth). Test fuels were chosen by methane and propane. PREMIX code in CHEMKIN-PRO was employed to calculate laminar burning velocity (SL) and flame temperature (Tf). Wiebe function and Wocshni's heat transfer coefficient were considered to calculate ηth. The results show that the d-EGR system increased ηth and it was higher than that of stoichiometric combustion of conventional SI engines due to the low Tf and fast SL.