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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The strain-induced diffusionless shear transformation of retained austenite to martensite during straining of transformation induced plasticity (TRIP) assisted steels increases strain hardening and delays necking and fracture leading to exceptional ductility and strength, which are attractive for automotive applications. A novel technique that provides the retained austenite volume fraction variation with strain with improved precision is presented. Digital images of the gauge section of tensile specimens were first recorded up to selected plastic strains with a stereo digital image correlation (DIC) system. The austenite volume fraction was measured by synchrotron X-ray diffraction from small squares cut from the gage section. Strain fields in the squares were then computed by localizing the strain measurement to the corresponding region of a given square during DIC post-processing of the images recorded during tensile testing.

This paper is the second in the series of documents designed to record the progress of a series of SAE documents - SAE J2836™, J2847, J2931, & J2953 - within the Plug-In Electric Vehicle (PEV) Communication Task Force. This follows the initial paper number 2010-01-0837, and continues with the test and modeling of the various PLC types for utility programs described in J2836/1™ & J2847/1. This also extends the communication to an off-board charger, described in J2836/2™ & J2847/2 and includes reverse energy flow described in J2836/3™ and J2847/3. The initial versions of J2836/1™ and J2847/1 were published early 2010. J2847/1 has now been re-opened to include updates from comments from the National Institute of Standards Technology (NIST) Smart Grid Interoperability Panel (SGIP), Smart Grid Architectural Committee (SGAC) and Cyber Security Working Group committee (SCWG).

A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

This paper presents two methods of characterizing and describing the formability of tailor welded blanks (TWB). The first method involves using miniature tensile specimens, extracted from TWB weld material, to quantify mechanical properties and material imperfection within TWB welds. This technique combines statistical methods of describing material imperfection together with conventional M-K method modeling techniques to determine safe forming limit diagrams for weld material. The second method involves the use of an extended M-K method modeling technique, which places multiple material thickness and material imperfections inside one overall model of TWB performance. These methods of describing TWB formability and their application to specific aluminum TWB populations are described.

Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.

An axisymmetric finite element model is generated to simulate the windshield glass damage propagation subjected to impact loading of a flying object. The windshield glass consists of two glass outer layers laminated by a thin poly-vinyl butyral (PVB) layer. The constitutive behavior of the glass layers is simulated using brittle damage mechanics model with linear damage evolution. The PVB layer is modeled with linear viscoelastic solid. The model is used to predict and examine through-thickness damage evolution patterns on different glass surfaces and cracking patterns for different windshield designs such as variations in thickness and curvatures.

This paper examines the effects of failure modes on the static strength and total energy absorption of aluminum spot-welded samples using experimental, statistical, and analytical approaches. The main failure modes for aluminum spot welds are nugget pullout and interfacial fracture. Two populations of aluminum spot welds were studied. Within each population, coupon configurations of lap shear, cross tension and coach peel were considered. Thirty replicate static strength tests were performed for each coupon configuration. The resulted peak load and energy absorption level associated with each failure mode was studied using statistical models. Next, an analytical model was developed to determine the failure mode of an aluminum resistance spot weld based on stress analysis. It is found that weld size, sheet thickness, and level of weld porosity and defects are the main factors determining the cross tension failure mode for an aluminum spot weld.

In this paper, results of finite element crash simulation are presented for a TRIP steel side rail with and without considering the phase transformation during forming operations. A homogeneous phase transformation model is adapted to model the mechanical behavior of the austenite-to-martensite phase. The forming process of TRIP steels is simulated with the implementation of the material model. The distribution and volume fraction of the martensite in TRIP steels may be greatly influenced by various factors during forming process and subsequently contribute to the behavior of the formed TRIP steels during the crushing process. The results indicate that, with the forming induced phase transformation, higher energy absorption of the side rail can be achieved. The phase transformation enhances the strength of the side rail.

This paper examines some key aspects of the manufacturing process that “ Transformation Induced Plasticity” (TRIP) steels would be exposed to, and systematically evaluate how the forming and thermal histories affect final strength and ductility of the material. We evaluate the effects of in-service temperature variations, such as under hood and hot/cold cyclic conditions, to determine whether these conditions influence final strength, ductility and energy absorption characteristics of several available TRIP steel grades. As part of the manufacturing thermal environment evaluations, stamping process thermal histories are included in the studies. As part of the in-service conditions, different pre-straining levels are included. Materials from four steel suppliers are examined. The thermal/straining history versus material property relationship is established over a full range of expected thermal histories and selected loading modes.

This paper presents the coupon performance data of friction stir welded tailor welded blanks (TWBs) joined to a monolithic aluminum sheet by self-piercing rivets (SPRs). Uniaxial tensile tests were performed to characterize the joint strength and the total energy absorption capability of the TWB/monolithic sheet joint assemblies. Cyclic fatigue tests were also conducted to characterize the fatigue behavior and failure mechanisms of the jointed assemblies. This study provides data for the automotive designer to determine whether friction stir welded aluminum TWB/monolithic sheet joints are within the target joint strengths for a particular application if it should be pierced during the assembly process.

Two analytical tools for failure predictions in free-expansion tube hydroforming, namely “Process Window Diagram” (PWD) and forming limit curve (FLC), are discussed in this paper. The PWD represents the incipient failure conditions of buckling, wrinkling and bursting of free-expansion tube hydroforming processes in the plane of process parameters, e.g. internal pressure versus axial compression. The PWD is a useful tool for design engineers to quickly assess part producibility and process design for tube hydroforming. An attempt is also made to draw the differences between FLCs for sheet and tube so that the appropriate FLC could be used to estimate the bursting or fracture limits in free-expansion tube hydroforming processes.

The transportation industry is finding an ever-increasing number of applications for products manufactured using the tubular hydroforming process. Most of the current hydroforming applications use steel tubes. However, with the mounting regulatory pressure to reduce vehicle emissions, aluminum alloys appear attractive as an alternative material to reduce vehicle weight. The introduction of aluminum alloys to tubular hydroforming requires knowledge of their forming limits. The current work investigates the forming limits of AA6061 in both the T4 and T6 tempers under laboratory conditions. These experimental results are compared to theoretical forming limit diagrams calculated via the M-K method. Free hydroforming results and forming limit diagrams are also compared to components produced under commercial hydroforming conditions.

Tailor welded blanks are finding increasing application in automotive structures as a powerful method to reduce weight through material minimization. As consumer demand and regulatory pressure direct the automotive industry toward improved fuel efficiency and reduced emissions, aluminum alloys are also becoming an attractive automotive structural material with their potential ability to reduce vehicle weight. The combination of aluminum and tailor welded blanks thus appears attractive as a method to further minimize vehicle weight. Two major concerns regarding the application of aluminum tailor welded blanks are the formability and durability of the weld materials. The current work experimentally and numerically investigates aluminum tailor welded blanks ductility, and experimentally investigates their fatigue resistance.

Due to mismatch of the coefficients of thermal expansion (CTE) of various layers in the PEN (positive/electrolyte/ negative) structures of solid oxide fuel cells (SOFC), thermal stresses and warpage on the PEN are unavoidable due to the temperature changes from the stress-free sintering temperature to room temperature during the PEN manufacturing process. In the meantime, additional mechanical stresses will also be created by mechanical flattening during the stack assembly process. In order to ensure the structural integrity of the cell and stack of SOFC, it is necessary to develop failure criteria for SOFC PEN structures based on the initial flaws occurred during cell sintering and stack assembly.

This paper presents development of a multi-scale material model for a 980 MPa grade transformation induced plasticity (TRIP) steel, subject to a two-step quenching and partitioning heat treatment (QP980), based on integrated computational materials engineering principles (ICME Model). The model combines micro-scale material properties defined by the crystal plasticity theory with the macro-scale mechanical properties, such as flow curves under different loading paths. For an initial microstructure the flow curves of each of the constituent phases (ferrite, austenite, martensite) are computed based on the crystal plasticity theory and the crystal orientation distribution function. Phase properties are then used as an input to a state variable model that computes macro-scale flow curves while accounting for hardening caused by austenite transformation into martensite under different straining paths.

In this paper, the microstructure-based finite element modeling method is used in investigating the loading path dependence of formability of transformation induced plasticity (TRIP) steels. For this purpose, the effects of different loading path on the forming limit diagrams (FLD) of TRIP steels are qualitatively examined using the representative volume element (RVE) of a commercial TRIP800 steel. First, the modeling method was introduced, where a combined isotropic/kinematic hardening rule is adopted for the constituent phases in order to correctly describe the cyclic deformation behaviors of TRIP steels during the forming process with combined loading paths which may include the unloading between the two consecutive loadings. Material parameters for the constituent phases remained the same as those in the authors' previous study [ 1 ] except for some adjustments for the martensite phase due to the introduction of the new combined hardening rule.

Limited room temperature formability hinders the wide-spread use of high strength aluminum alloys in body parts. Forming at warm temperatures or from softer tempers are the current solutions. In this work, our approach is to start with age-hardened sheets from 7xxx and 6xxx family of alloys and improve their formability using local thermomechanical processing only in the regions demanding highest ductility in the forming processes. We achieved local formability improvements with friction stir processing and introduce another process named roller bending-unbending as a concept and showed its feasibility through finite element simulations. Initial results from FSP indicated significant deformation in the processed zones with minimal sheet distortion. FSP also resulted in dynamically recrystallized, fine grained (d < 5 μm) microstructures in the processed regions with textures significantly different from the base material.

Macroscopic constitutive behaviors of aluminum 5052-H38 honeycombs under dynamic inclined loads with respect to the out-of-plane direction are investigated by experiments. The results of the dynamic crush tests indicate that as the impact velocity increases, the normal crush strength increases and the shear strength remains nearly the same for a fixed ratio of the normal to shear displacement rate. The experimental results suggest that the macroscopic yield surface of the honeycomb specimens as a function of the impact velocity under the given dynamic inclined loads is not governed by the isotropic hardening rule of the classical plasticity theory. As the impact velocity increases, the shape of the macroscopic yield surface changes, or more specifically, the curvature of the yield surface increases near the pure compression state.

This paper presents the strength data for conventional automotive windshields in both the new and used conditions. More specifically, the biaxial strength of outer surface of curved and symmetrically laminated windshield, measured in biaxial flexure, is reported. The relative contributions of inplane membrane stress, which can be significant for new windshields, and bending stress are quantified with the aid of strain gauge rosettes mounted on both the outer and inner surfaces of windshield. The strength distribution for new and used windshields, based on Weibull distribution function, is found to be multimodal indicating more than one family of surface flaws. Depending on handling damage during manufacturing, assembly and installation processes, the low strength region of new windshields can approach that of used windshields with 50,000+ road miles!