Search Results

The California Air Resources Board (CARB) has proposed procedures for the analysis of non-methane organic gases (NMOG) to determine the ozone forming potential (OFP) of automotive exhaust. For realization of these methods two differently configured GC systems are necessary. In order to reduce the efforts concerning costs, maintenance and quality control of two analytical instruments, a single run method is developed for routine analysis. This method allows identification and quantification of individual hydrocarbons (IHC) in the range of carbon numbers C2 to C12. Analytical problems arising from high contents of water and carbon dioxide in exhaust samples are discussed. Water reduction is obtained by a Nafion® Dryer by means of membrane diffusion of polar compounds. Contamination as well as memory effects due to this sample work up are described. Sample pre-concentration of 50-200 mL diluted automotive exhaust is performed using a triple phase “mixed bed” adsorption tube at O°C.