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Journal Article

A Chemical and Morphological Study of Diesel Injector Nozzle Deposits - Insights into their Formation and Growth Mechanisms

2017-03-28
2017-01-0798
Modern diesel passenger car technology continues to develop rapidly in response to demanding emissions, performance, refinement, cost and fuel efficiency requirements. This has included the implementation of high pressure common rail fuel systems employing high precision injectors with complex injection strategies, higher hydraulic efficiency injector nozzles and in some cases <100µm nozzle hole diameters. With the trend towards lower diameter diesel injector nozzle holes and reduced cleaning through cavitation with higher hydraulic efficiency nozzles, it is increasingly important to focus on understanding the mechanism of diesel injector nozzle deposit formation and growth. In this study such deposits were analysed by cross-sectioning the diesel injector along the length of the nozzle hole enabling in-depth analysis of deposit morphology and composition change from the inlet to the outlet, using state-of-the-art electron microscopy techniques.
Technical Paper

A Critical Road Test Evaluation of a High-Performance Gasoline Additive Package in a Fleet of Modern European and Asian Vehicles

2004-06-08
2004-01-2027
A road test has been conducted to quantify the benefits provided by a high-performance gasoline additive package in a fleet of cars representative of Europe, SE Asia, and South America. The emissions, fuel consumption, and engine cleanliness benefits of additised versus untreated gasoline were compared in 15 pairs of cars. A further 6 cars were operated on a mixture of fuels to show the benefits of additised fuel versus mixed fuelling. The design of the experiment was based on a similar road test conducted in 1991. Through careful test design and execution, it has been possible to assess the performance of the package at a high statistical confidence level. The package provides a high level of inlet system cleanliness, a significant reduction in fuel consumption and reduced HC emissions.
Technical Paper

A Mathematical Model for the Vapour Composition and Flammability of Gasoline - Diesel Mixtures in a Fuel Tank

2017-10-08
2017-01-2407
Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this, but a practical concern is the flammability of the headspace vapours in the vehicle fuel tank. Gasoline is much more volatile than diesel so, at most ambient temperatures, the headspace vapours in the tank are too rich to burn. A gasoline/diesel mixture in a fuel tank therefore can result in a flammable headspace, particularly at cold ambient temperatures. A mathematical model is presented that predicts the flammability of the headspace vapours in a tank containing mixtures of gasoline and diesel fuel. Fourteen hydrocarbons and ethanol represent the volatile components. Heavier components are treated as non-volatile diluents in the liquid phase.
Technical Paper

A New Protocol for the Road Test Evaluation of Gasoline Additive Packages

2006-10-16
2006-01-3408
The accurate confirmation of fuel economy benefits arising from the use of a gasoline additive package is a difficult exercise. In order to fully understand, and accurately quantify, the interaction between the treated fuel and the engine it is necessary to carry out a fleet test which allows the benefit to be measured precisely yet under realistic conditions. A series of road tests, based on a ‘paired fleet’ design, has been carried out over the last two decades. Careful analysis of the results of these tests has led to the design of a new fleet testing protocol based around ‘quads’ rather than pairs of vehicles. This new test protocol also incorporates advances in vehicle selection and preparation procedures and has resulted in a test that is both more robust and flexible, and that achieves even better resolution than before.
Technical Paper

An Efficient, High-Precision Vehicle Testing Procedure to Evaluate the Efficacy of Fuel-Borne Friction Modifier Additives

2019-12-19
2019-01-2353
Improved fuel economy is increasingly a key measure of performance in the automotive industry driven by market demands and tighter emissions regulations. Within this environment, one way to improve fuel economy is via fuel additives that deliver friction- reducing components to the piston-cylinder wall interface. Whilst the use of friction modifiers (FMs) in fuel or lubricant additives to achieve fuel economy improvements is not new, demonstrating the efficacy of these FMs in vehicles is challenging and requires statistical design together with carefully controlled test conditions. This paper describes a bespoke, efficient, high-precision vehicle testing procedure designed to evaluate the fuel economy credentials of fuel-borne FMs. By their nature, FMs persist on engine surfaces and so their effects are not immediately reversible upon changing to a non FM-containing fuel (“carryover” effect), therefore requiring careful design of the test programme.
Journal Article

Analysis of a Diesel Passenger Car Behavior On-Road and over Certification Duty Cycles

2016-10-17
2016-01-2328
Precise, repeatable and representative testing is a key tool for developing and demonstrating automotive fuel and lubricant products. This paper reports on the first findings of a project that aims to determine the requirements for highly repeatable test methods to measure very small differences in fuel economy and powertrain performance. This will be underpinned by identifying and quantifying the variations inherent to this specific test vehicle, both on-road and on Chassis Dynamometer (CD), that create a barrier to improved testing methods. In this initial work, a comparison was made between on-road driving, the New European Drive Cycle (NEDC) and World harmonized Light-duty Test Cycle (WLTC) cycles to understand the behavior of various vehicle systems along with the discrepancies that can arise owing to the particular conditions of the standard test cycles.
Journal Article

Application of a Split Lubrication Gasoline Engine to the Screening and Understanding of Friction Modifier Behaviour

2011-08-30
2011-01-2134
A series of viscous and surface friction modifier additives has been studied in a modified SI engine with separable valve train lubrication. From the results, it has been possible to classify the hydrodynamic or boundary lubrication nature of the observed effects for a series of lubricant additives. It is shown that the frictional benefit of a given additive depends not only on the engine operating condition but also on the engine components on which it is acting. For some additives a fuel economy benefit can switch to a disbenefit as operating regime changes and a different aspect of the additive properties becomes important. Such observations are rationalised in the context of conventional lubrication theory.
Journal Article

Assessing the Impact of Lubricant and Fuel Composition on LSPI and Emissions in a Turbocharged Gasoline Direct Injection Engine

2020-04-14
2020-01-0610
Downsized turbocharged gasoline direct injection (TGDI) engines with high specific power and torque can enable reduced fuel consumption in passenger vehicles while maintaining or even improving on the performance of larger naturally aspirated engines. However, high specific torque levels, especially at low speeds, can lead to abnormal combustion phenomena such as knock or Low-Speed Pre-Ignition (LSPI). LSPI, in particular, can limit further downsizing due to resulting and potentially damaging mega-knock events. Herein, we characterize the impacts of lubricant and fuel composition on LSPI frequency in a TGDI engine while specifically exploring the correlation between fuel composition, particulate emissions, and LSPI events. Our research shows that: (1) oil composition has a strong impact on LSPI frequency and that LSPI frequency can be reduced through a carefully focused approach to lubricant formulation.
Technical Paper

Control of Diesel Engine Exhaust Gas Recirculation System Deposits with Fuel Additives

2022-08-30
2022-01-1072
Exhaust Gas Recirculation (EGR) is employed in diesel engines to reduce engine-out NOx emissions. Despite the concerted design efforts of manufacturers, high-pressure Exhaust Gas Recirculation (HP-EGR) systems can be susceptible to fouling as the particulate matter, hydrocarbons and other entrained species deposit from the exhaust gas flow as it cools on its passage through the EGR system. Such deposits can lead to a number of problems including deterioration of emissions, fuel efficiency, performance and drivability, as well as breakdowns. The development of an engine test method to enable the study of the impact of fuel on deposits in the HP-EGR system was reported in 2020. In the test, a 4-cylinder light-duty diesel engine of 1.6L displacement runs at conditions conducive to EGR deposit formation over 24 hours and the impact of fuels on deposit formation is determined through weighing of the EGR system components before and after the test.
Journal Article

Dedicated GTL Vehicle: A Calibration Optimization Study

2010-04-12
2010-01-0737
GTL (Gas-To-Liquid) fuel is well known to improve tailpipe emissions when fuelling a conventional diesel vehicle, that is, one optimized to conventional fuel. This investigation assesses the additional potential for GTL fuel in a GTL-dedicated vehicle. This potential for GTL fuel was quantified in an EU 4 6-cylinder serial production engine. In the first stage, a comparison of engine performance was made of GTL fuel against conventional diesel, using identical engine calibrations. Next, adaptations enabled the full potential of GTL fuel within a dedicated calibration to be assessed. For this stage, two optimization goals were investigated: - Minimization of NOx emissions and - Minimization of fuel consumption. For each optimization the boundary condition was that emissions should be within the EU5 level. An additional constraint on the latter strategy required noise levels to remain within the baseline reference.
Technical Paper

Designing Fuels Compatible with Reformers and Internal Combustion Engines

2004-06-08
2004-01-1926
Because reformer technology can be used in conjunction with advanced internal combustion engine technology, it is important to be able to formulate fuels that are compatible with both reformers and ICEs It has been found that most hydrocarbon species typically present in gasoline can be reformed with relative ease. The exception is that olefinic species of carbon number 6 and above are relatively much harder to reform. It is shown how a reformer compatible gasoline fuel with high octane can be blended. For Diesel fuels, synthetic ‘Gas to Liquid’ fuels are generally less susceptible to coking and hence superior to petroleum-derived fuels, for use with an onboard reformer.
Technical Paper

Developing a Precision and Severity Monitoring System for CEC Performance Tests

2004-06-08
2004-01-1892
The Coordinating European Council, CEC, develops performance tests for the motor, oil, petroleum, additive and allied industries. In recent years, CEC has moved away from using round robin programmes (RRP's) for monitoring the precision and severity of test methods in favour of regular referencing within a test monitoring system (TMS). In a TMS, a reference sample of known performance, determined by cross-laboratory testing, is tested at regular intervals at each laboratory. The results are plotted on control charts and determine whether the installation is and continues to be fit to evaluate products. Results from all laboratories are collated and combined to monitor the general health of the test. The TMS approach offers considerable benefits in terms of detecting test problems and improving test quality. However, the effort required in collating data for statistical analysis is much greater, and there are technical difficulties in determining precision from TMS data.
Journal Article

Development and Application of an Engine Test Method to Rate the Internal Injector Deposit Formation of Diesel Fuels and Additives

2022-08-30
2022-01-1070
Design efforts to improve the hydraulic efficiency of high-pressure diesel fuel systems and thus further improve overall engine efficiency have resulted in the utilisation of low-spill control valves and reduced injector component clearances to reduce general leakage losses. Overall, these advances have contributed significantly to the high efficiency diesel engines of today. However, the combination of very high fuel pressures, cavitation and low fuel leakage volumes increases the heating of the remaining fuel, increasing temperature and, in turn, the propensity for deposits to form inside the injector. This deposit phenomenon is commonly known as Internal Diesel Injector Deposits (IDID) and can cause rough engine running and failed engine starts requiring injector cleaning or replacement. Methods studying this phenomenon are under development in the industry.
Technical Paper

Development and Assessment of Traction Fluids for Use in Toroidal (IVT) Transmissions

2002-03-04
2002-01-0588
The attributes of a traction fluid are fundamental to the successful operation of a traction drive transmission. The fluid must lubricate and protect the components against wear and corrosion, whilst simultaneously providing high traction to transmit power efficiently. A selection of commercial and candidate fluids have been assessed with both a bench-test and a novel traction rig. The principal objective has been to achieve a balance between the conflicting requirements of low temperature viscometrics and high temperature traction. Fluid performance is found to vary according to the rig employed underlining the need to test under prevailing conditions. Data from the traction rig is validated against a variator module.
Journal Article

Development of an Engine Test to Rate the EGR Deposit Formation Propensity of Fuels in Light-Duty Diesel Engines

2020-09-15
2020-01-2096
Exhaust Gas Recirculation (EGR) is employed in diesel engines to reduce engine-out NOx. Carbon-containing deposits form in the EGR systems of modern diesel engines as the particulate matter, hydrocarbons and other entrained species deposit from the exhaust gas flow as it cools. Much work has been done by Original Equipment Manufacturers (OEMs) to reduce deposits and mitigate their effects by optimized dimensioning of EGR coolers and valves, introduction of EGR cooler bypass for use in the most sensitive cold conditions and experimenting with oxidation catalysts upstream of the EGR system. Nevertheless, deposits forming in the high-pressure Exhaust Gas Recirculation (HP-EGR) systems of modern diesel engines can sometimes lead to a number of problems including emissions and fuel consumption deterioration, poor performance and drivability, as well as breakdowns. An engine test method has been developed to enable the impact of fuel on deposits in the HP-EGR system to be studied.
Technical Paper

Effect of Oil Viscosity and Driving Mode on Oil Dilution and Transient Emissions Including Particle Number in Plug-In Hybrid Electric Vehicle

2020-04-14
2020-01-0362
Plug-in electric vehicle (PHEV) has a promising prospect to reduce greenhouse gas (GHG) emission and optimize engine operating in high-efficiency region. According to the maximum electric power and all-electric range, PHEVs are divided into two categories, including “all-electric PHEV” and “blended PHEV” and the latter provides a potential for more rational energy distribution because engine participates in vehicle driving during aggressive acceleration not just by motor. However, the frequent use of engine may result in severe emissions especially in low state of charge (SOC) and ahead of catalyst light-off. This study quantitatively investigates the impact of oil viscosity and driving mode (hybrid/conventional) on oil dilution and emissions including particle number (PN).
Technical Paper

Effect of Sulphur and Silicon in Fuels on an Automotive Reforming Catalyst

2005-05-11
2005-01-2163
The effect of sulphur on a rhodium reformer catalyst was determined in the partial oxidation of n-heptane. The yield loss of the catalyst upon sulphur addition appeared to almost instantaneous and not progressive in time (i.e. it reaches a plateau). Up to ppm levels, the direct yield loss appeared to be linearly related to the sulphur level in the fuel and is of the order of around 3% per ppm of sulphur in the fuel. Sulphur adsorption on rhodium catalyst sites was found to be reversible. The original activity of the catalyst was quickly restored when changing to a sulphur free fuel. The effect of sulphur on the rhodium catalyst does not depend on the structure of the sulphur species. Based on this work, a 10 ppm sulphur maximum seems to be a sufficiently tight specification with respect to the stability of an appropriate reformer catalyst. By contrast, the presence of other species in fuels can cause irreversible and progressive catalyst deterioration.
Technical Paper

Effects of GTL Fuel Properties on DI Diesel Combustion

2005-10-24
2005-01-3763
Reduction of vehicle exhaust emissions is an important contributor to improved air quality. At the same time demand is growing for new transportation fuels that can enhance security and diversity of energy supply. Gas to Liquids (GTL) Fuel has generated much interest from governments and automotive manufacturers. It is a liquid fuel derived from natural gas, and its properties - sulphur free, low polyaromatics and high cetane number - make it desirable for future clean light-duty diesel engines. In this paper, the effects of distillation characteristics and cetane number of experimental GTL test fuels on direct injection (DI) diesel combustion and exhaust emissions were investigated, together with their spray behaviour and mixing characteristics. The test results show that the lower distillation test fuels produce the largest reductions in smoke and PM emissions even at high cetane numbers. This is linked to the enhanced air/fuel mixing of the lighter fuel in a shorter time.
Technical Paper

Explicit equations for designing surrogate gasoline formulations containing ethanol, isopentane, n-heptane, isooctane and toluene

2023-09-29
2023-32-0164
It is useful for research purposes to define simple surrogate gasoline compositions that can replicate the chemical and physical properties of more complex mixtures. Ethanol is used in commercially available gasolines around the world as part of the pathway to the decarbonization of the transportation sector. In this study equations were developed to predict the Research Octane Number (RON), Motor Octane Number (MON) and Dry Vapour Pressure Equivalent (DVPE) of gasoline surrogates containing ethanol (10-25 vol%), isopentane, n-heptane, isooctane and toluene. The non-linear blending behaviour associated with ethanol is found to necessitate coefficients in the equations developed for MON that are a function of ethanol content, whereas surprisingly the equations for RON and DVPE do not need this added level of complexity.
Technical Paper

Extending the Limits of Fuel Economy through Lubrication

2017-10-08
2017-01-2344
It is anticipated that worldwide energy demand will approximately double by 2050, whilst at the same time, CO2 emissions need to be halved. Therefore, there is increasing pressure to improve the efficiency of all machines, with great focus on improving the fuel efficiency of passenger cars. The use of downsized, boosted, gasoline engines, can lead to exceptional fuel economy, and on a well-to-wheels basis, can give similar CO2 emissions to electric vehicles (depending, of course, on how the electricity is generated). In this paper, the development of a low weight concept car is reported. The car is equipped with a three-cylinder 0.66 litre gasoline engine, and has achieved over 100 miles per imperial gallon, in real world driving conditions.
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