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With introductions of stringent diesel engine emission regulations, the DOC and DPF systems have become the mainstream technology to eliminate soot particles through diesel combustion under various operation conditions. Urea-based SCR has been the mainstream technical direction to reduce NOx emissions. For both technologies, low-temperature conditions or cold start conditions pose challenges to activate DOC or SCR emission-reduction performance. To address this issue, mini or full flow burner systems may be used to increase exhaust temperature to reach DOC light-off or SCR initiation temperature by combustion of diesel fuel. In essence, the burner systems incorporate a fuel injector, spray atomization, proper fuel / air mixing mechanisms, and combustion control as independent heat sources.

To meet EPA Tier IV large diesel engine emission targets, intensive development efforts are necessary to achieve NOx reduction and Particulate Matter (PM) reduction targets [1]. With respect to NOx reduction, liquid urea is typically used as the reagent to react with NOx via SCR catalyst [2]. Regarding to PM reduction, additional heat is required to raise exhaust temperature to reach DPF active / passive regeneration performance window [3]. Typically the heat can be generated by external diesel burners which allow diesel liquid droplets to react directly with oxygen in the exhaust gas [4]. Alternatively the heat can be generated by catalytic burners which enable diesel vapor to react with oxygen via DOC catalyst mostly through surface reactions [5].

The Diesel engine combustion process results in harmful exhaust emissions, mainly composed of Particulate Matter (PM), Hydro Carbon (HC), Carbon monoxide (CO) and Nitrogen Oxides (NOx). Several technologies have been developed in the past decades to control these diesel emissions. One of the promising and well matured technology of reducing NOx is to implement Selective Catalytic Reduction (SCR) using ammonia (NH3) as the reducing agent. For an effective SCR system, the aqueous urea solutions should be fully decomposed into ammonia and it should be well distributed across the SCR. In the catalyst, all the ammonia is utilized for NOx reduction process. In the design stage, it is more viable to implement Computational Fluid Dynamics (CFD) for design iterations to determine an optimized SCR system based on SCR flow distribution. And in later stage, experimental test is required to predict the after-treatment system performance based on NOx reduction.

The Diesel Particulate Filter (DPF) is used on today's diesel vehicles to reduce the amount of soot being released into the atmosphere from diesel exhaust. The DPFs are typically wall-flow filtration devices of various extruded porous ceramic materials with more than 95% efficiency. Once the filter has loaded with soot, the DPF undergoes regeneration where the exhaust temperature is raised to burn off the soot. With the DPF being relatively new aftertreatment technology, the exhaust industry must investigate the acoustic and performance effects of the DPF when added to an exhaust system. In many applications the DPF replaces the exhaust muffler because of limited packaging space. The acoustic performance of the DPF changes with increasing soot density and exhaust backpressure. The acoustic response is measured with physical testing at multiple soot load densities. This study is part of a graduation thesis project for Kettering University[1].

It is important to quantitatively characterize the automotive events in order to not only accurately interpret their past but also to reliably predict and forecast their short-term, medium-term, and even long-term future. In this paper, several automotive industry related events, i.e. vehicle safety, vehicle weight/HP ratio, the emissions of CO2, HC, CO, and NOx, are analyzed to find their general trends. Exponential and power law functions are used to empirically fit and quantitatively characterize these data with an emphasis on the two functions’ effectiveness in predictability. Finally, three empirical emission laws based on the historical HC, CO, and NOx data are proposed and the impact of these laws on emission control is discussed.

To meet the 2010 diesel engine emission regulations, an aftertreatment system was developed to reduce HC, CO, NOx and soot. In NOx reduction, a baseline SCR module was designed to include urea injector, mixing decomposition tube and SCR catalysts. However, it was found that the baseline decomposition tube had unacceptable urea mixing performance and severe deposit issues largely because of poor hardware design. The purpose of this article is to describe necessary development work to improve the baseline system to achieve desired mixing targets. To this end, an emissions Flow Lab and computational fluid dynamics were used as the main tools to evaluate urea mixing solutions. Given the complicated urea spray transport and limited packaging space, intensive efforts were taken to develop pre-injector pipe geometry, post-injector cone geometry, single mixer design modifications, and dual mixer design options.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

A series of novel metal-oxide (TiO2, TiO2-SiO2)-supported Mn, Fe, Co, V, Cu and Ce catalysts were prepared by incipient wetness technique and investigated for the low-temperature selective catalytic reduction (SCR) of NOx with ammonia at industrial relevantly conditions. Among all the prepared catalysts, Cu/TiO2 showed superior de-NOx performance in the temperature range of 150-200 °C followed by Mn/TiO2 in the temperature range of 200-250 °C. The Ce/TiO2 catalyst exhibited a broad temperature window with notable de-NOx performance in the temperature regime of 250-350 °C. The phyico-chemical characterization results revealed that the activity enhancement was correlated with the properties of the support material. All the anatasetitania-supported catalysts (M/TiO2 (Hombikat)) demonstrated significantly high de-NOx performance above 150 °C.

Diesel burners recently have been used in Diesel Particulate Filter (DPF) regeneration process, in which the exhaust gas temperature is raised through the combustion process to burn off the soot particles. The feasibility of such process using the burner in large diesel applications is investigated along with a mixer and DPF. For such applications, only partial flow of the exhaust stream is fed into the burner and the resulting hot flow from combustion process is then mixed with the rest of the main stream. The amount of flow into the burner plays a vital role in overall system performance as it determines the amount of hot gas needed for Diesel Oxidation Catalyst (DOC) light-off (to facilitate DPF regeneration) and also oxygen amount needed for secondary combustion. A passive valve plate design is proposed for such flow split applications for the burner.

With increasing applications of urea SCR for NOx emission reduction, improving the system performance and durability has become a high priority. A typical urea SCR system includes a urea injector, injector housing, mixer, and appropriate pipe configurations to allow continuous urea injection into the exhaust stream and evaporation of urea solution into gaseous products. Continuous operation at various conditions with high NOx reduction is possible, but one problem that threatens the life and performance of these systems is urea deposit. When urea or its byproducts become deposited on the inner surfaces of the system including walls, mixers, injector housings and substrates it can create concerns of backpressure and material deteriorations. In addition, deposits as a waste of reagents can negatively affect engine operation, emissions performance and DEF economy. Urea deposit behavior is explored in terms of heat transfer, pipe geometry, injector layout and mixing mechanisms.

The main objective of this work is to develop a low-temperature SCR catalyst for the reduction of nitrogen oxides at cold start, low-idle and low-load conditions. A series of metal oxide- incorporated beta zeolite catalysts were prepared by adopting incipient wetness technique, cation-exchange, deposition-precipitation and other synthesis techniques. The resulting catalysts were characterized and tested for reduction of NOx in a fixed bed continuous flow quartz micro-reactor using ammonia as the reductant gas. Initial catalyst formulations have been exhibited good NOx reduction activity at low-temperatures. These catalyst formulations showed a maximum NOx conversion in the temperature range of 100 - 350°C. Besides, more experiments were performed with the aim of optimizing these formulations with respect to the metal atomic ratio, preparation method, active components and supported metal type.

The commercial vehicle industry continues to move in the direction of improving brake thermal efficiency while meeting more stringent diesel engine emission requirements. This study focused on demonstrating future emissions by using an exhaust burner upstream of a conventional aftertreatment system. This work highlights system results over the low load cycle (LLC) and many other pertinent cycles (Beverage Cycle, and Stay Hot Cycle, New York Bus Cycle). These efforts complement previous works showing system performance over the Heavy-Duty FTP and World Harmonized Transient Cycle (WHTC). The exhaust burner is used to raise and maintain the Selective Catalytic Reduction (SCR) catalyst at its optimal temperature over these cycles for efficient NOX reduction. This work showed that tailpipe NOX is significantly improved over these cycles with the exhaust burner.

The low-NOx standard for heavy duty trucks proposed by the California Air Resources Board represents a significant challenge to the engine and aftertreatment system. In this study, exhaust thermal management requirements were quantified using a combination of engine and aftertreatment modeling. First, a 1-D engine model was used to develop a control strategy capable of increasing the exhaust enthalpy and decreasing the engine-out NOx over the initial portion of the cold FTP cycle. The outputs from this model were then used as inputs to a 1-D model of a representative HD aftertreatment system. Several different passive exhaust thermal management technologies were evaluated with this aftertreatment system model, including insulating the downpipe, close-coupling the aftertreatment system, and reducing the thermal inertia of the DOC and DPF; the last option provides the most benefit to early NOx conversion.

The low-NOx standard for heavy-duty trucks proposed by the California Air Resources Board will require rapid warm-up of the aftertreatment system (ATS). Several different aftertreatment architectures and technologies, all based on selective catalytic reduction (SCR), are being considered to meet this need. One of these architectures, the close-coupled SCR (ccSCR), was evaluated in this study using two different physics-based, 1D models; the simulations focused on the first 300 seconds of the cold-start Federal Test Procedure (FTP). The first model, describing a real, EuroVI-compliant engine equipped with series turbochargers, was used to evaluate a ccSCR located either i) immediately downstream of the low-pressure turbine, ii) in between the two turbines, or iii) in a by-pass around the high pressure turbine.

In order to satisfy tightening global emissions regulations, diesel truck manufacturers are striving to meet increasingly stringent Oxides of Nitrogen (NOx) reduction standards. The majority of heavy duty diesel trucks have integrated urea SCR NOx abatement strategies. To this end, aftertreatment systems need to be properly engineered to achieve high conversion efficiencies. A EuroV intent urea SCR system is evaluated and failed to meet NOx conversion targets with severe urea deposit formation. Systematic enhancements of the design have been performed to enable it to meet targets, including emission reduction efficiency via improved reagent mixing, evaporation, distribution, back pressure, and removing of urea deposits. Multiple urea mixers, injector mounting positions and various system layouts are developed and evaluated, including both CFD analysis and full scale laboratory tests.

Driven by diesel engine emission regulation, more emission aftertretment products have been under development by Tenneco to address the Particular Matter (PM) and NOx reduction needs. The T.R.U.E. (Thermal Regeneration Unit for Exhaust) Clean active thermal management system is one of the examples to reduce PM. The system is designed to increase exhaust temperatures for DPF (Diesel Particulate Filter) regeneration. This product is exposed to high temperature and high oxidation. Therefore, thermal fatigue, creep, oxidation and the interaction become critical mechanism to be considered for its durability. One of the key challenges to validate this product is to find a way of accelerated testing for thermal, creep, and oxidation as well as for vibration. In this paper, accelerated durability test strategy for high temperature device like T.R.U.E Clean is addressed.

NOx emissions limits for commercial trucks will be drastically reduced in the United States and Europe later in this decade. The most recent Euro VII proposal suggested that pre-heating of the aftertreatment system with a diesel burner may be needed to meet a new low-NOx limit. Pre-heating serves to prepare the SCR catalyst so that it can begin to convert NOx almost immediately after the engine is started. This is particularly important for an engine that is not equipped with exhaust gas recirculation to reduce engine-out NOx. This study considered a burner installed between a 12.4 liter engine and an appropriately-sized in-line DOC/DPF/SCR aftertreatment system. Initially, a wide range of burner and air pump operating conditions were examined to determine the maximum fueling rate and corresponding air flow rate necessary to complete combustion and to convey the resultant heat downstream to the aftertreatment components.

Diesel burners introduce combustion of diesel fuel to raise exhaust gas temperature to Diesel Oxidization Catalyst (DOC) light-off or Diesel Particulate Filter (DPF) regeneration conditions, thereby eliminating the need of engine measures such as post-injections. Such diesel combustion requirement nevertheless poses challenges to burner development especially in combustion control and risk mitigation of DPF material failure. In particular, burner design must satisfy good soot distribution and heat distribution at DPF front face after meeting minimum requirements of ignition, heat release, and backpressure. In burner development, Computational Fluid Dynamics (CFD) models have been developed based on commercial codes for burner thermal and flow management with capability of predicting comprehensive physical and chemical phenomena including turbulence induced mixing, fuel injection, fuel droplet transport, diesel combustion, radiation, conjugate heat transfer and etc.

As emissions regulations around the world become more stringent, emerging markets are seeking alternative strategies that align with local infrastructures and conditions. A Lean NOx Catalyst (LNC) is developed that achieves up to 60% NOx reduction with ULSD as its reductant and ≻95% with ethanol-based fuel reductants. Opportunities exist in countries that already have an ethanol-based fuel infrastructure, such as Brazil, improving emissions reduction penetration rates without costs and complexities of establishing urea infrastructures. The LNC performance competes with urea SCR NOx reduction, catalyst volume, reductant consumption, and cost, plus it is proven to be durable, passing stationary test cycles and adequately recovering from sulfur poisoning. Controls are developed and applied on a 7.2L engine, an inline 6-cylinder non-EGR turbo diesel.