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Proton exchange membrane fuel cell (PEMFC) has attracted extensive attention in recent years because of its high efficiency and zero emission. Although fuel cell technology has made great progress, durability is still the bottleneck of its large-scale commercialization. In order to systematically study the degradation of fuel cell system for transportation applications, we selected the most severe operating condition - on-off cyclic condition as the research object, and focused on the influence of cell temperature and air relative humidity on the degradation rate of fuel cell by means of polarization curve, reference voltage and CV. The results show that with the same temperature, the fuel cell performance degradation rate first decreases and then increases with the decrease of humidity, which may be due to the increase of platinum ion transfer rate at high relative humidity and the dry membrane at low relative humidity.

Proton exchange membrane fuel cell (PEMFC) system is considered to be one of the ideal replacement for conventional Internal Combustion Engines (ICE) due to its zero emission, low operating temperature and high power density. The high-pressure PEMFC system has become the future development direction because the higher gas pressure can effectively improve the performance and power density of stack. However, the high gas pressure can lead to the damage of membrane electrode assembly (MEA) and even the failure of fuel cell stack. As the air supply system is a nonlinear system, the flow and pressure have a strong coupling relation. For this problem, firstly, the mathematical model of air supply system is established in MATLAB/Simulink. Then a dual-loop control strategy is used in controller.

Proton exchange membrane fuel cells (PEMFC), which convert the chemical energy into electrical energy directly through electrochemical reactions, are widely considered as one of the best power sources for new energy vehicles (NEV). Some of the major advantages of a PEMFC include high power density, high energy conversion efficiency, minimum pollution, low noise, fast startup and low operating temperature. The Membrane Electrode Assembly (MEA) is one of the core components of fuel cells, which composes catalyst layers (CL) coated proton exchange membrane (PEM) and gas diffusion layers (GDL). The performance of MEA is closely related to mass transportation and the rate of electrochemical reaction. The MEA plays a key role not only in the performance of the PEMFCs, but also for the reducing the cost of the fuel cells, as well as accelerating the commercial applications. Commercialized large-size MEA directly plays a major role in determining fuel cell stack and vehicle performance.