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The characteristics of three-way-catalyst during engine start process were investigated based on a simulated start/stop test system for HEV application. Although the catalyst has already reached its light-off temperature, the conversion efficiency is poor during engine start process due to the deviation of lambda from stoichiometric. The high concentration hydrocarbon emission spike can be stored by catalyst substrate temporarily, then it is released. This dynamic process decreases the conversion efficiency for the following exhaust hydrocarbon emission. When the initial temperature of catalyst substrate before engine start increased from 150°C to 400°C, the conversion efficiency for both the hydrocarbon and NO are increased.

In this paper an estimation method on location of peak pressure (LPP) employing flame ionization measurement, with the spark plug as a sensor, was discussed to achieve combustion parameters estimation at quick start of HEV engines. Through the cycle-based ion signal analysis, the location of peak pressure can be extracted in individual cylinder for the optimization of engine quick start control of HEV engine. A series of quick start processes with different cranking speed and engine coolant temperature are tested for establishing the relationship between the ion signals and the combustion parameters. An Artificial Neural Network (ANN) algorithm is used in this study for estimating these two combustion parameters. The experiment results show that the location of peak pressure can be well established by this method.