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A summary is presented of experimental results obtained from a Cummins B5.9 175 hp, direct-injected diesel engine fueled with oxygenated diesel blends. The oxygenates tested were dimethoxy methane (DMM), diethyl ether, a blend of monoglyme and diglyme, and ethanol. The experimental results show that particulate matter (PM) reduction is controlled largely by the oxygen content of the blend fuel. For the fuels tested, the effect of chemical structure was observed to be small. Isotopic tracer tests with ethanol blends reveal that carbon from ethanol does contribute to soot formation, but is about 50% less likely to form soot when compared to carbon from the diesel portion of the fuel. Numerical modeling was carried out to investigate the effect of oxygenate addition on soot formation. This effort was conducted using a chemical kinetic mechanism incorporating n-heptane, DMM and ethanol chemistry, along with reactions describing soot formation.

This is a continuation of the presentation of thermodynamic properties of selected fuel-air mixtures in chart form, suitable for utilization in engine performance calculations. Methane and propane, representative of natural gas and LPG are the two fuels considered. Using these charts, comparisons are made between the performance to be expected with these gaseous fuels compared to octane, as representative of gasoline. Reduced engine power is predicted and this is confirmed by experience of other investigators.