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Conventional methods to measure gas concentrations and, in particular, NO are typically based on sampling by valve, sample treatment and subsequent analysis. These methods suffer low spatial and temporal resolution. The introduction of high energy lasers in combination with fast detection systems allowed to detect the NO distribution inside optically accessible Diesel engines. In this paper, a high spatial and temporal resolution in-situ technique based on ultraviolet - visible absorption spectroscopy is proposed. The characterization of the combustion process by the detection of gaseous compounds from the start of combustion until the exhaust phase was performed. In particular, this technique allows the simultaneous detection of NO and OH absolute concentrations inside an optically accessible Diesel combustion chamber.

Non-intrusive diagnostic techniques based on broadband (190-550 nm) extinction and scattering spectroscopy were applied at undiluted exhaust Common- Rail (CR) diesel engine in real time. The influence of load and Exhaust Gas Recirculation (EGR) on soot mass concentration, size distribution of emitted particles and NO concentration was analyzed. NO concentration was evaluated by ""in-situ"" ultraviolet-visible absorption measurements and compared with those obtained by conventional analyzer. The extinction and scattering spectra were compared with those evaluated by the Lorenz-Mie model for spherical particles in order to retrieve the size, the number concentration of the emitted particles and particulate mass. The optical measurements showed that new generation diesel engines, in spite of a drastic reduction of the exhaust mass concentration, caused the emission in the atmosphere of high number concentration of carbonaceous nanoparticles.

Two different optical techniques for detection, sizing and counting nanoparticles were applied to undiluted exhaust from 16 v–1900 cc Common Rail diesel engine upstream and downstream a Catalyzed Diesel Particulate Filter (CDPF): Broadband Ultraviolet–Visible Extinction and Scattering Spectroscopy (BUVESS) and Laser Induced Incandescence (LII). They are powerful “in situ” and non-intrusive techniques; they are able to measure mass concentration and size of particles, considering their chemical properties. BUVESS overcomes the intrinsic limitations of single wavelength techniques because it takes advantage of data at several wavelengths to retrieve primary particle size distribution. LII measures mean size of primary particles with a large dynamic range, not limited by aggregate size and by complex retrieving procedure.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

A 0.5 liter optical HCCI engine firing a mixture of n-heptane (50%) and iso-octane (50%) with air/fuel ratio of 3 is studied using large eddy simulation (LES) and laser diagnostics. Formaldehyde and OH LIF and in-cylinder pressure were measured in the experiments to characterize the ignition process. The LES made use of a detailed chemical kinetic mechanism that consists of 233 species and 2019 reactions. The auto-ignition simulation is coupled with LES by the use of a renormalized reaction progress variable. Systematic LES study on the effect of initial temperature inhomogeneity and turbulence intensity has been carried out to delineate their effect on the ignition process. It was shown that the charge under the present experimental condition would not be ignited without initial temperature inhomogeneity. Increasing temperature inhomogeneity leads to earlier ignition whereas increasing turbulence intensity would retard the ignition.

In this work, a boosted single-cylinder spark ignition port-fuel injection optical engine was used for the experimental activity. Firstly, it was equipped with a four-valve head of a commercial turbocharged multi-cylinder engine. Then a prototype engine head with flush installed intake valves was tested. The effect of the different head geometry was evaluated in closed intake valves fuel injection condition. High spatial resolution cycle-resolved digital imaging was used to characterise the flame propagation. Moreover, the presence of diffusion-controlled flames near the valves and on the cylinder walls was investigated. These flames induced the formation of unburned hydrocarbons and soot particles. The spatial distribution and temporal evolution of soot were evaluated by the two colour pyrometry. The prototype configuration showed higher combustion process efficiency than the standard one inducing a little increase in performance and a slight reduction in carbon oxides emissions.

The growing demands on fuel economy and always stricter limitations on pollutant emissions has increased the interest in the ignition phenomena to guarantee successful flame development for all the spark ignition (SI) engine operating conditions. The initial size and the growth of the flame have a strong influence on the further development of the combustion process. In particular, for the new FIAT generation of turbocharged SI engines, the first times of spark ignition combustion are not yet fully understood. This is mainly due to the missing knowledge concerning the detailed physical and chemical processes taking place during the all set of the flame propagation. These processes often occur simultaneously, making difficult the interpretation of measurements. In the present paper, flame dynamic was followed by UV-visible emission imaging in an optical SI engine.

Hydrogen has been proposed as a possible fuel for automotive applications. This paper reports an experimental investigation of hydrogen as HCCI engine fuel. The aim of the experimental study is to investigate the possibility to run an HCCI engine on an extremely fast burning fuel such as hydrogen as well as to study the efficiency, the combustion phasing and the formation of emissions. The experiments were conducted on a single-cylinder research engine with a displacement volume of 1.6 litres and pancake combustion chamber geometry. Variation of lambda, engine speed, compression ratio and intake temperature were parts of the experimental setting. The engine was operated in Homogenous Charge Compression Ignition (HCCI) mode and as comparison also in Spark Ignition (SI) mode. Hydrogen was found to be a possible fuel for an HCCI engine. The heat release rate was extremely high and the interval of possible start of combustion crank angles was found to be narrow.

The optimization of diesel engine performance and emissions can be achieved through a better understanding of the in-cylinder combustion process. Advanced non-intrusive optical techniques are providing new tools for investigating the thermo-fluid dynamics processes as well as they are contributing to develop predictive models for DI diesel combustion. High-speed images of spray and flame evolution as well as UV-visible chemiluminescence measurements were carried out in an optical 0.5-liter, single-cylinder, four-stroke, direct- injection diesel engine equipped with a prototype four valves cylinder head and a fully flexible CR injection system. In order to evaluate the effect of different injection strategies on the combustion process, measurements were performed varying injection parameters. The ignition location and time were individuated by combustion visualization and detection of radical species, obtained by chemiluminescence measurements.

Proton Exchange Membrane (PEM) Fuel Cell (FC) presents itself as a promising technology in view of zero-tailpipe emission vehicles. In addition, the constant development of renewable energy sources will lead to an increase in green hydrogen availability, and thus completely eliminate emissions for devices that use H2 as an energy vector. However, PEM FCs are still far from being fully developed as a technology: thermal and water management are the main issues that researchers are studying through experiments and Computational Fluid Dynamics (CFD) simulations. For the numerical approach, H2O removal models often consider a simplified flat surface, but the microgeometry of the Gas Diffusion Layer (GDL) has a leading role in determining the critical dimension for droplet detachment and how much resistance the surface poses to water sliding. The aim of this paper is to investigate the influence of droplets number on a GDL.

For the simultaneous evaluation of the influence on engine knock of both chemical conditions and global operating parameters, a combined tool was developed. Thus, a two-zone kinetic model for SI engine combustion calculation (Ignition) was implemented into an engine cycle simulation commercial code. The combined model predictions are compared with experimental data from a single-cylinder test engine. This shows that the model can accurately predict the knock onset and in-cylinder pressure and temperature for different lambda conditions, with and without EGR. The influence of nitric oxide amount from residual gas in relation with knock is further investigated. The created numerical tool represents a useful support for experimental measurements, reducing the number of tests required to assess the proper engine control strategies.

Quantitative measurements of the soot volume fraction and diameter performed by spectroscopic techniques within the combustion chamber of a diesel engine are employed to aid multidimensional simulation of the soot formation and oxidation processes. By changing the start of fuel injection, two different operating conditions are considered, which are characterized by different relative importance of the premixed to the diffusive stage of the combustion process. Both the reduced models by Hiroyasu et al., and the one by Nagle and Strikland- Constable are employed within the numerical simulation. The reason of the peculiar over-prediction of soot concentration of the latter model is discussed and related to the need of furnishing coherent values of the soot particle density and mean diameter.

Multidimensional simulation of the soot formation process in a diesel engine is realised exploiting quantitative measurements of the soot volume fraction and diameter obtained by optical techniques. Broadband extinction and scattering measurements are performed on an optically accessible 4-stroke engine where a forced air motion allows a strong prevalence of the premixed stage of combustion with respect to the non-premixed one. Two semi-empirical models for soot formation are tested in the numerical simulation, which is performed using a customized version of the KIVA-3 code. The need of furnishing coherent values of the soot particles density and mean diameter to the one of the two models requiring this kind of information, is highlighted and demonstrated to be crucial in avoiding over-prediction of the soot concentration.

In the last years, there has been an increasing concern on the emission of ultrafine particles in the atmosphere. A detailed study of formation and oxidation of these particles in the environment of the diesel cylinder presents many experimental difficulties due to the high temperatures, pressures and extremely reactive intermediate species. In this paper, in order to follow the different phases of diesel combustion process, high temporal and spatial resolution optical techniques were applied in the optically accessible chamber of diesel engine, at 2000 rpm and A/F=80:1 and 60:1. Simultaneous extinction, scattering and flame chemiluminescence measurements from UV to visible were carried out, in order to study the diesel combustion process from the droplet ignition to the formation of soot, through the growth of its precursors.

The aim of the paper is the characterization in terms of chemical and physical nature of particles at exhaust of spark ignition (SI) engine. Measurements were carried out at exhaust of 16v - 1.2 litre Port Fuel Injection Spark Ignition engine downstream a catalyst. The emission of nanoparticles was investigated by optical techniques and conventional methods. In particular laser induced incandescence (LII), and broadband multiwavelength extinction-scattering spectroscopy (BUVESS) were used. LII allowed the detection and sizing primary particles of carbonaceous nature. BUVESS measured particle size distribution by numerical procedure that took advantage by data at several wavelengths. The optical results were compared with those obtained by conventional methods like opacimeter for mass concentration and Electrical Low Pressure Impactor (ELPI) for sizing. Different engine operating conditions were selected in order to evaluate their influence on the particle nature and size distribution.

The match among the increasing performance demands and the stringent requirements of emissions and the fuel consumption reduction needs a strong evolution in the two-wheel vehicle technology. In particular, many steps forward should be taken for the optimization of modern small motorcycles and scooters at low engine speeds and high loads. To this aim, detailed understanding of thermo-fluid dynamic phenomena that occur in the combustion chamber is fundamental. In this work, low-cost solutions are proposed to optimize ported fuel injection spark ignition (PFI SI) engines for two-wheel vehicles. The solutions are based on the change of phasing and on the splitting of the fuel injection in the intake manifold. The experimental activities were carried out in the combustion chamber of a single-cylinder 4-stroke optical engine fuelled with European commercial gasoline. The engine was equipped with a four-valve head of a commercial scooter engine.

The flame front propagation in normal and abnormal combustion was investigated. Cycle-resolved flame emission imaging was applied in the combustion chamber of a port fuel injection boosted spark ignition engine. The engine was fuelled with a mixture of 90% iso-octane and 10% n-heptane by volume (PRF90). The effect of fuel injection phasing was studied. The combustion process was followed from the flame kernel formation until the opening of the exhaust valves. Different phenomena correlated to the abnormal combustion were analysed. Detailed information on ignition surfaces, end-gas auto-ignitions and knock were obtained. The appearance of autoignition centres in the end gas was evaluated in terms of timing, location and frequency of occurrence.

In this work, constant volume combustion is studied using a zero-dimensional FORTRAN code, which is a wide-ranging chemical kinetic simulation that allows a closed system of gases to be described on the basis of a set of initial conditions. The model provides an engine- or reactor-like environment in which the engine simulations allow for a variable system volume and heat transfer both to and from the system. The combustion chamber is divided into two zones as burned and unburned ones, which are separated by an assumed thin flame front in the combustion model used for this work. Equilibrium assumptions have been adopted for the modeling of the thermal ionization, where Saha's equation was derived for singly ionized molecules. The investigation is focused on the thermal ionization of NO as well as for other species. The outputs generated by the model are temperature profiles, species concentration profiles, ionization degree and an electron density for each zone.

Hydrogen has been proposed as a possible fuel for automotive applications. Methanol is one of the most efficient ways to store and handle hydrogen. By catalytic reformation it is possible to convert methanol into hydrogen and carbon monoxide. This paper reports an experimental investigation of Reformed Methanol Gas as Homogeneous Charge Compression Ignition (HCCI) engine fuel. The aim of the experimental study is to investigate the possibility to run an HCCI engine on a mixture of hydrogen and carbon monoxide, to study the combustion phasing, the efficiency and the formation of emissions. Reformed Methanol Gas (RMG) was found to be a possible fuel for an HCCI engine. The heat release rate was lower than with pure hydrogen but still high compared to other fuels. The interval of possible start of combustion crank angles was found to be narrow but wider than for hydrogen. The high rate of heat release limited the operating range to lean (λ>3) cases as with hydrogen.

Numerical simulations of diesel engine combustion and emission formation have been performed using a detailed soot model. Operating conditions typical for modern truck-size engines have been investigated, and calculated results show encouraging agreement with experimental data for soot in engine exhaust gas. Predictions of details in the soot formation process compare well with detailed experimental data from the literature. The modelling of the soot/flow-field interaction is based on a flamelet approach. Source terms of the soot volume fraction are taken from a flamelet library using a presumed probability density function and integrating over mixture fraction space. In order to save computer storage and CPU time, the flamelet library of sources was constructed using a multi-parameter fitting procedure resulting in simple algebraic equations and a proper set of parameters.