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The windage tray effect on aeration in the engine sump was assessed by replacing much of the windage tray materials with wire meshes of various blockages. The mesh was to prevent direct impact of the oil drops spinning off the crank shaft onto the sump oil, and simultaneously, to provide sufficient drainage so that there was no significant build up of windage tray oil film that would interact with these droplets. Aeration at the oil pump inlet was measured by X-ray absorption in a production V-6 SI engine motoring at 2000 to 6000 rpm. Within experimental uncertainty, these windage tray changes had no effect on aeration. Thus activities in the sump such as the interaction of the oil drops spun from the crank shaft with the sump oil or with the windage tray, and the agitation of the sump oil by the crank case gas, were not major contributors to aeration at the pump inlet.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

The fuel property effects on first cycle mixture preparation were assessed by measuring the in-cylinder fuel equivalence ratio (Φ) with a Fast Flame Ionization Detector (FFID) using four different fuels. The Engine Coolant Temperature (ECT) was varied between -6°C and 80°C. The Φ values increased with both ECT and amount of injected fuel mass. The delivery fraction (fraction of the injected fuel that went into the combustible charge), however, increased with ECT but decreased with increase in injected fuel. The minimum required injected mass to produce a combustible mixture increased sharply with decrease in ECT below 20°C. There was, however, no single fuel parameter that would correlate with the measurements over the entire temperature range. Instead, the minimum required injected mass correlated to different distillation points on the ASTM distillation curve; e.g. at ECT of -6°C, it correlated to T20; at 40°C, it correlated to T50.

The effects of secondary air on the exhaust oxidation of particulate matters (PM) have been assessed in a direct-injection-spark-ignition engine under fuel rich fast idle condition (1200 rpm; 2 bar NIMEP). Substantial oxidation of the unburned feed gas species (CO and HC) and significant reduction of both the particulate number (up to ∼80%) and volume (up to ∼90%) have been observed. The PM oxidation is attributed to the reactions between the PM and the radicals generated in the oxidation of the feed gas unburned species. This hypothesis is supported by the observation that the reduction in PM volume is proportional to the amount of heat release in the secondary oxidation.

The catalyst oxygen storage capacities were measured over a test matrix consisted of fuels with 7, 33, 266 and 500 ppm sulfur, and of dynamometer-aged catalysts simulating 4K, 50K and 150K vehicle miles. A methodology was developed to relate the post-catalyst λ sensor response following an engine lean-step-transient to the total oxygen storage sites available. The time resolved NOx concentration profiles (which were most sensitive to the oxygen storage) in the catalyst were measured with the engine operating at λ modulations of various amplitudes and frequencies. The oxygen storage capacity deterioration comprised two multiplicative factors - an age factor which decreased quickly initially (by a factor of 2 from 4K to 50K miles), and then more modestly (by 30% from 50 to 150K miles), and a fuel sulfur factor which decreased by 10% for every 150 ppm increase in sulfur level.

An ignition delay correlation encompassing the effects of temperature, pressure, residual gas, EGR, and lambda (on both the rich and lean sides) has been developed. The procedure uses the individual knocking cycle data from a boosted direct injection SI engine (GM LNF) operating at 1250 to 2000 rpm, 8-14 bar GIMEP, EGR of 0 to 12.5%, and lambda of 0.8 to 1.3 with a certification fuel (Haltermann 437, with RON=96.6 and MON=88.5). An algorithm has been devised to identify the knock point on individual pressure traces so that the large data set (of some thirty three thousand cycles) could be processed automatically. For lean and for rich operations, the role of the excess fuel, air, and recycled gas (which has excess air in the lean case, and hydrogen and carbon monoxide in the rich case) may be treated effectively as diluents in the ignition delay expression.

The mixture preparation and hydrocarbon (HC) emissions behaviors for a single-cylinder port-fuel-injection SI engine were examined in an engine/dynamometer set up that simulated the first cycle of cranking. The engine was motored continuously at a fixed low speed with the ignition on, and fuel was injected every 8 cycles. Unlike the real engine cranking process, the set up provided a well controlled and repeatable environment to study the cranking process. The parameters were the Engine Coolant Temperature (ECT), speed, and the fuel injection pulse width. The in-cylinder and exhaust HC were measured simultaneously with two Fast-response Flame Ionization Detectors. A large amount of injected fuel (an order of magnitude larger than the normal amount that would produce a stoichiometric mixture in a warm-up engine) was required to form a combustible mixture at low temperatures.

When gas sample is continuously drawn from the cylinder of an internal combustion engine, the sample that appears at the end of the sampling system corresponds to the in-cylinder content sometime ago because of the finite transit time which is a function of the cylinder pressure history. This variable delay causes a dispersion of the sample signal and makes the interpretation of the signal difficult An unsteady flow analysis of a typical sampling system was carried out for selected engine loads and speeds. For typical engine operation, a window in which the delay is approximately constant may be found. This window gets smaller with increase in engine speed, with decrease in load, and with the increase in exit pressure of the sampling system.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The engine and its exhaust flow behaviors are investigated in a turbo-charged gasoline direct injection engine under simulated cold-fast-idle condition. The metrics of interest are the exhaust sensible and chemical enthalpy flows, and the exhaust temperature, all of which affect catalyst light off time. The exhaust sensible enthalpy flow is mainly a function of combustion phasing; the exhaust chemical enthalpy flow is mainly a function of equivalence ratio. High sensible and chemical enthalpy flow with acceptable engine stability could be obtained with retarded combustion and enrichment. When split injection is employed with one early and one later and smaller fuel pulse, combustion retards with early secondary injection in the compression stroke but advances with late secondary injection. Comparing gasoline to E85, the latter produces a lower exhaust temperature because of charge cooling effect and because of a faster combustion.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.