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Technical Paper

A Study on Effect of Heterogeneity of Oxygen Concentration of Mixture in a Combustion Chamber on Combustion and Emissions of Diesel Engine

2007-07-23
2007-01-1845
In this study, the combustion characteristics of diesel flame achieved in a rapid compression and expansion machine (RCEM) at various patterns of oxygen distribution in the chamber are investigated in order to clarify the effect of heterogeneity of oxygen distribution in diesel engines induced by EGR on the soot and NOx emissions. To make the heterogeneous distribution of oxygen in a combustion chamber, the mixtures with different oxygen concentrations are injected through the each different port located on the cylinder wall. Results indicate that the amount of oxygen entrained into the spray upstream the luminous flame region affects the NO emission from diesel flame strongly.
Journal Article

Aromatic Additive Effect on Soot Formation and Oxidation in Fischer-Tropsch Diesel (FTD) Spray Flame -Morphology and Nanostructure Analysis of In-Flame Soot Particles via HRTEM-

2013-10-14
2013-01-2681
In order to examine the effect of aromatic addition to Fischer-Tropsch Diesel (FTD) fuel on formation and oxidation processes of soot particles in diesel spray flame, small amount of naphthalene (0 to 65,000 ppm) was added to the FTD fuel and variation of soot morphology and nanostructure of primary soot particles directly sampled in a diesel spray flame were investigated via High-Resolution Transmission Electron Microscopy (HRTEM). A single-shot diesel spray flame was achieved in a constant volume combustion chamber under a diesel-like condition (Ta=1000K, Pa=2.7MPa) and a grid for HRTEM observation was directly exposed to the spray flame to thermophoretically sample soot particles onto the grid surface. The primary particle diameter, aggregate gyration radius, lattice fringe length, lattice fringe tortuosity and lattice fringe separation of soot particles sampled at different locations (from 60 to 90mm from nozzle tip) in the spray flame were analyzed.
Journal Article

Automated Detection of Primary Particles from Transmission Electron Microscope (TEM) Images of Soot Aggregates in Diesel Engine Environments

2015-09-01
2015-01-1991
The major challenge of the post-processing of soot aggregates in transmission electron microscope (TEM) images is the detection of soot primary particles that have no clear boundaries, vary in size within the fractal aggregates, and often overlap with each other. In this study, we propose an automated detection code for primary particles implementing the Canny Edge Detection (CED) and Circular Hough Transform (CHT) on pre-processed TEM images for particle edge enhancement using unsharp filtering as well as image inversion and self-subtraction. The particle detection code is tested for soot TEM images obtained at various ambient and injection conditions, and from five different combustion facilities including three constant-volume combustion chambers and two diesel engines.
Journal Article

Direct Sampling, TEM Analysis and Optical Measurement of Soot Particles at Different Axial Locations in a Transient Spray Flame

2011-08-30
2011-01-2051
In order for better understanding of soot formation and oxidation processes in diesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a transient spray flame were analyzed via high-resolution transmission electron microscopy (HRTEM). The soot distribution in the spray flame was simultaneously observed by high-speed shadowgraphy. The transient spray combustion was achieved in a constant volume combustion chamber under a high pressure and high temperature condition (940 K, 2.5 MPa). The soot samples were taken at different axial locations in the spray flame, 40 - 90 mm from the injector nozzle, using an intrusive soot sampler. Pressure histories, heat release rates and laser shadowgraphs of spray combustion were compared between the cases with and without the soot sampler in order to check the intrusion effect of soot sampler on combustion.
Technical Paper

Effect of Fuel Aromatics on In-Flame Diesel Soot Nanostructure via HRTEM

2015-09-01
2015-01-1829
In order to examine the effect of fuel aromatics on soot processes in diesel flame, nanostructure and morphology of soot particles directly sampled in a diesel flame were investigated via High-Resolution Transmission Electron Microscopy (HRTEM). Three test fuels with different aromatic contents, aromatic-free Fischer-Tropsch Diesel (FTD), naphthalene-added (65,000ppm) FTD and conventional JIS#2 diesel fuels were used. TEM grids were directly exposed to single-shot diesel flames in a constant volume combustion chamber under a diesel-like condition with EGR (1000K, 2.7MPa, 15%O2) to thermophoretically sample soot particles at different axial locations from 40 to 120mm from nozzle. The soot nanostructure such as length, tortuosity and separation of lattice fringes in primary particles and morphology such as primary particle diameter and aggregate gyration radius were analyzed and compared among different fuels and in-flame locations.
Technical Paper

High-Resolution Transmission Electron Microscopy of Soot Directly Sampled at Different Axial Locations in Diesel Spray Flame

2011-09-11
2011-24-0068
For better understanding of soot formation and oxidation processes in a diesel spray flame, morphology, microstructure and size of soot particles directly sampled at different locations in the spray flame (40mm to 90mm from injector nozzle tip) were investigated using a high-resolution transmission electron microscope (HRTEM). The diesel spray flame was achieved in a constant volume combustion chamber under diesel-like conditions (2.5MPa and 940K). The concentration, diameter of primary particles and the radius of gyration of soot aggregates increased in the upstream region (40 to 50mm), exhibited a peak around the mid-stream region (60 to 70mm), and then decreased in the downstream region (80 to 90mm) from the injector nozzle tip, which corresponds to formation, peak concentration and oxidation of soot particles in the spray flame, respectively.
Technical Paper

High-Speed UV and Visible Laser Shadowgraphy of GDI In-Cylinder Pool Fire

2016-10-17
2016-01-2165
For better understanding, model development and its validation of in-cylinder soot formation processes of Gasoline Direct Injection (GDI) engines, visualization of piston surface fuel wetting, vaporization and soot formation processes of in-cylinder pool fire via high-speed UV (266nm) and visible (445nm) laser shadowgraphy was attempted in an optically accessible Rapid Compression and Expansion Machine (RCEM). A direct-injection, spark-ignition and single-shot combustion event was achieved in the RCEM under engine-equivalent, simplified and well-defined conditions operated with engine speed 600 rpm, compression ratio 9.0, equivalence ratio 0.9 and natural aspiration. The tested fuel was composed of 70% iso-octane and 30% toluene by volume and the UV absorption by toluene enabled visualization of the in-cylinder fuel distribution.
Journal Article

In-Cylinder GDI Soot via Visualization and Time-Resolved Total Cylinder Sampling

2019-01-15
2019-01-0037
For better understanding, model development and its validation of in-cylinder soot formation processes of Gasoline Direct Injection (GDI) engines, crank-angle-resolved mass and size distribution of in-cylinder soot during a GDI combustion cycle were investigated via optical measurements and total cylinder sampling technique in an optically accessible Rapid Compression and Expansion Machine (RCEM). A direct-injection, spark-ignited and single-shot combustion event was achieved in the RCEM operated with engine speed 600 rpm, compression ratio 9.0, equivalence ratio 0.9 and natural aspiration. A three-component (iso-octane 65%, n-heptane 10%, toluene 25%) gasoline surrogate fuel and a multi-hole injector shared within the Japanese SIP Innovative Combustion Technology research program were used.
Technical Paper

Infrared High-Speed Thermography of Combustion Chamber Wall Impinged by Diesel Spray Flame

2023-09-29
2023-32-0087
As a new method to examine the extremely unsteady and spatially varying wall heat transfer phenomena on diesel engine combustion chamber wall, high-speed imaging of infrared thermal radiation from the chromium coated window surface impinged by a diesel spray flame has been conducted in a constant volume combustion chamber. The infrared radiation from a back surface of the chromium layer was successfully visualized at 10kHz frame rate and 128 × 128 pixel resolution through the window. The distributions of infrared radiation, temperature and heat flux exhibited coherent and streaky structure with radial stripes extending and waving from a stagnation point likely reflecting the near-wall turbulent structure in a wall impinging diesel flame. The experiments were conducted with various parameters such as fuel injection pressure, ambient gas oxygen concentration, wall impinging distance, wall surface roughness and wall materials.
Journal Article

Laser-Induced Phosphorescence Thermography of Combustion Chamber Wall of Diesel Engine

2008-04-14
2008-01-1069
In order to investigate the mechanism of heat transfer on the chamber wall of direct-injection diesel engines, 2-D temperature imaging and heat flux measurement in the flame impinging region on the chamber wall were conducted using laser-induced phosphorescence technique. The temperature of the chamber wall surface was measured by the calibrated intensity variation of the 355nm-excited laser-induced phosphorescence from an electrophoretically deposited thin layer of La2O2S:Eu phosphor on a quartz glass plate placed in a rapid compression and expansion machine (RCEM). Instantaneous 2-D images of wall temperature at different timings after start of injection and time-resolved (10kHz) heat flux near the flame impinging region were obtained for combusting and non-combusting diesel sprays with impinging distance of 23.4mm at different injection pressures (80 and 120MPa).
Journal Article

Morphology Analysis of Wall-Deposited Diesel Soot Particles via Transmission Electron Microscope

2014-10-13
2014-01-2637
Wall-deposition of soot particles occurs due to the interaction between spray flame and cylinder liner wall/piston surface, which can potentially affect soot morphology after the in-flame formation/oxidation processes and before the exit from engine cylinder. In order to investigate these effects, flame wall impingement was simulated in a constant volume combustion vessel and thermophoretic soot sampling was conducted for Transmission Electron Microscopic analysis. A TEM grid for the sampling was exposed to a single-shot diesel spray flame multiple times and the variation of soot morphology (concentration, primary particle diameter and aggregate gyration radius) among the multiple exposures was compared. Furthermore, a newly designed impingement-type sampler vertically exposed the grid to the spray flame and sampled soot particles under different boundary condition from that of conventionally used skim-type sampler.
Journal Article

Transmission Electron Microscopy of Soot Particles Directly Sampled in Diesel Spray Flame - A Comparison between US#2 and Biodiesel Soot

2012-04-16
2012-01-0695
For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.
Technical Paper

Transmission Electron Microscopy of Soot Particles sampled directly from a Biodiesel Spray Flame

2011-08-30
2011-01-2046
For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.
Technical Paper

Uncertainty in Sampling and TEM Analysis of Soot Particles in Diesel Spray Flame

2013-04-08
2013-01-0908
For better understanding of soot formation and oxidation processes applicable to diesel engines, the size, morphology, and nanostructure of soot particles directly sampled in a diesel spray flame generated in a constant-volume combustion chamber have been investigated using Transmission Electron Microscopy (TEM). For this soot diagnostics, the effects of the sampling processes, TEM observation methodology and image processing methods on the uncertainty in the results have not been extensively discussed, mainly due to the complexity of the analysis.
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