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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

Using a holistic 1D engine simulation approach for the modelling of full-transient engine operation, allows analyzing future engine concepts, including its exhaust gas aftertreatment technology, early in the development process. Thus, this approach enables the investigation of both important fields - the thermodynamic engine process and the aftertreatment system, together with their interaction in a single simulation environment. Regarding the aftertreatment system, the kinetic reaction behavior of state-of-the-art and advanced components, such as Diesel Oxidation Catalysts (DOC) or Selective Catalytic Reduction Soot Filters (SCRF), is being modelled. Furthermore, the authors present the use of the 1D engine and exhaust gas aftertreatment model on use cases of variable valve train (VVT) applications on passenger car (PC) diesel engines.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

Fuel cells plays significant role in the automotive sector to substitute the fossil fuels and complement to electric vehicles. In the fuel cell vehicles fuel cell stack is major component. It is important to have a robust fuel cell model that can simulate the behaviour of the fuel cell stack under various operating conditions in order to study the functioning of a fuel cell and optimize its operating parameters and achieve the best efficiency in operation. The operating voltage of the fuel cell at different current densities depends upon thermodynamic parameters like temperature and pressure of the reactants as well factors like the state of humidification of the electrolyte membrane. A 1D model is developed to capture the variation in voltage at different current densities due to internal losses and changes to operating conditions like temperature and pressure.

The introduction of more stringent standards for engine emissions requires a steady development of exhaust gas aftertreatment in addition to an optimized cylinder combustion. The reduction of the cold start phase can help significantly to lower cycle emissions. With the goal of optimizing the overall emission performance this study presents a comprehensive simulation approach. A well established 1D gas dynamics and engine simulation model is extended by three key features. These are models for combustion and pollutant production in the cylinder, models for the pollutant conversion in a catalyst, and a general species transport model. This allows to consider an arbitrary number of chemical species and reactions in the entire system.

Most of current jet aircraft circulate fuel on the airframe to match heat loads with available heat sink. The demands for thermal management in wide range of air vehicle systems are growing rapidly along with the increased mission power, vehicle survivability, flight speeds, and so on. With improved aircraft performance and growth of heat load created by Aircraft Mounted Accessory Drive (AMAD) system and hydraulic system, effectively removing the large amount of heat load on the aircraft is gaining crucial importance. Fuel is becoming heat transfer fluid of choice for aircraft thermal management since it offers improved heat transfer characteristics and offers fewer system penalties than air. In the scope of this paper, an AMESim model is built which includes airframe fuel and hydraulic systems with AMAD gearbox of a jet trainer aircraft. The integrated model will be evaluated for thermal performance.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

For the thermal management of an automobile, the induced airflow becomes necessary to enable the sufficient heat transfer with ambient. In this way, the components work within the designed temperature limit. It is the engine-cooling fan that enables the induced airflow. There are two types of engine-cooling fan, one that is driven by engine itself and the other one is electrically driven. Due to ease in handling, reduced power consumption, improved emission condition, electrically operated fan is becoming increasingly popular compared to engine driven fan. The prime mover for electric engine cooling fan is DC motor. Malfunction of DC motor due to overheating will lead to engine over heat, Poor HVAC performance, overheating of other critical components in engine bay. Based upon the real world driving condition, 1D transient thermal model of engine cooling fan motor is developed. This transient model is able to predict the temperature of rotor and casing with and without holes.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.

Motor thermal management of electric vehicles (EVs) is becoming more significant due to its close relations to vehicle aerodynamic performance and power consumption, while computer aided engineering (CAE) plays an important role in its development. A 1D-3D coupled model is established to characterize transient thermal performance of the motor in an electric vehicle on a high performance computer (HPC) platform. The 1D motor thermal management model is integrated with the 1D powertrain model, and a 3D thermal model is established for the motor, while online data exchange is realized between the 1D and 3D models. The 1D model gives boundaries such as inlet coolant temperature, mass flowrate and motor heat generation to the 3D model, while the 3D model gives back boundaries such as heat transfer to coolant simultaneously. Transient simulations are performed for the 140kph(20°C) driving cycle, and the model is calibrated with experimental data.

Thermal management in electric vehicles (EVs) has attracted more attention due to its increasing significance, and computer aided engineering (CAE) plays an important role in its development. A 1D-3D online coupling approach is proposed to completely characterize transient thermal performance of an electric vehicle on a high performance computer (HPC) platform. The 1D thermal management model, consisting of air conditioning, motor cooling and battery cooling systems, is integrated with the 1D control strategy model and powertrain model consisting of motor, battery, driver and vehicle models. The 3D model is established for the air flow around the full vehicle and through its underhood. The 3D model gives boundaries such as heat exchanger air flowrates and heat flows on some component surfaces to the 1D model, while 1D gives back boundaries such as heat exchanger heat loads, component surface temperatures and fan speed simultaneously.

An integrated engineering approach using computer modeling, laboratory and vehicle testing enabled the Ford GT engineering team to achieve supercar thermal management performance within the aggressive program timing. Theoretical and empirical test data was used during the design and development of the engine cooling system. The information was used to verify design assumptions and validate engineering efforts. This design approach allowed the team to define a system solution quickly and minimized the need for extensive vehicle level testing. The result of this approach was the development of an engine cooling system that adequately controls air, oil and coolant temperatures during all driving and environmental conditions.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.

Ever increasing specific power of diesel engines has put huge demand on effective thermal management of the pistons for the desired reliability and durability. The piston temperature control is commonly achieved by injecting cooling oil into piston galleries, but the design of the cooling system as well as the boundary conditions used in FEA simulations have so far relied mostly on empirical methods. A numerical procedure using 3D computational fluid dynamics (CFD) has therefore been developed to simulate the cooling process and to estimate the cooling efficiency of gallery. The model is able to predict the detailed oil flow and heat transfer in gallery, of different designs and engine applications, under dynamic conditions. The resulted spatially resolved heat transfer coefficient from the CFD model, with better accuracy, enables improved prediction of piston temperature in finite element analysis (FEA).

A large amount of heat is generated in electric vehicle battery packs during high rate charging, resulting in the need for effective cooling methods. In this paper, a prototype liquid cooled large format Lithium-ion battery module is modeled and tested. Experiments are conducted on the module, which includes 31Ah NMC/Graphite pouch battery cells sandwiched by a foam thermal pad and heat sinks on both sides. The module is instrumented with twenty T-type thermocouples to measure thermal characteristics including the cell and foam surface temperature, heat flux distribution, and the heat generation from batteries under up to 5C rate ultra-fast charging. Constant power loss tests are also performed in which battery loss can be directly measured.

A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.

Mild hybridisation, using a 48 V system architecture, offers fuel consumption benefits approaching those achieved using high-voltage systems at a much lower cost. To maximise the benefits from a 48 V mild-hybrid system, it is desirable to recuperate during deceleration events at as high a power level as possible, whilst at the same time having a relatively compact and low cost system. This paper examines the particular requirements of the battery pack for such a mild-hybrid application and discusses the trade-offs between battery power capabilities and possible fuel consumption benefits. The technical challenges and solutions to design a 48 V mild-hybrid battery pack are presented with special attention to cell selection and the thermal management of the whole pack. The resulting battery has been designed to achieve a continuous-power capability of more than 10 kW and a peak-power rating of up to 20 kW.