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The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).

Two oxygenated fuels were evaluated on a single-cylinder diesel engine and compared to three hydrocarbon diesel fuels. The oxygenated fuels included canola biodiesel (canola methyl esters, CME) and CME blended with dibutyl succinate (DBS), both of which are or have the potential to be bio-derived. DBS was added to improve the cold flow properties, but also reduced the cetane number and net heating value of the resulting blend. A 60-40 blend of the two (60% vol CME and 40% vol DBS) provided desirable cold flow benefits while staying above the U.S. minimum cetane number requirement. Contrary to prior vehicle test results and numerous literature reports, single-cylinder engine testing of both CME and the 60-40 blend showed no statistically discernable change in NOx emissions relative to diesel fuel, but only when constant intake oxygen was maintained.

A fuel vapor system model (FVSMOD) has been developed to simulate vehicle evaporative emission control system behavior. The fuel system components incorporated into the model include the fuel tank and pump, filler cap, liquid supply and return lines, fuel rail, vent valves, vent line, carbon canister and purge line. The system is modeled as a vented system of liquid fuel and vapor in equilibrium, subject to a thermal environment characterized by underhood and underbody temperatures and heat transfer parameters assumed known or determined by calibration with experimental liquid temperature data. The vapor/liquid equilibrium is calculated by simple empirical equations which take into account the weathering of the fuel, while the canister is modeled as a 1-dimensional unsteady absorptive and diffusive bed. Both fuel and canister submodels have been described in previous publications. This paper presents the system equations along with validation against experimental data.

A method of predicting brake specific fuel consumption characteristics from limited specifications of engine design has been investigated. For spark ignition engines operating on homogeneous mixtures, indicated specific fuel consumption based on gross indicated power is related to compression ratio and spark timing relative to optimum values. The influence of burn rate is approximately accounted for by the differences in spark timings required to correctly phase combustion. Data from engines of contemporary design shows that indicated specific fuel consumption can be defined as a generic function of relative spark timing, mixture air/fuel ratio and exhaust gas recirculation rate. The additional information required to generate brake specific performance maps is cylinder volumetric efficiency, rubbing friction, auxiliary loads, and exhaust back pressure characteristics.

Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.

Instrumentation of an exhaust system to measure surface temperature at multiple locations usually involves welding independent thermocouples to the surface of the system. This report describes a new type of thermocouple fabricated to measure temperature at a point or temperature difference between points on a metallic object utilizing the metal as one component of the new thermocouple. AISI 316 stainless steel is used in the current study to represent automotive exhaust pipe. The other component of the thermocouple is Nickel-Chromium (Chromel, Chromega), one of the two metals used in type K thermocouples, which are generally used for exhaust temperature measurements during emission tests. Use of the new thermocouple is contingent upon an accurate calibration of its response to changes in temperature.

The Variable Displacement Supercharger (VDS) is a twin helical screw style compressor that has a feature to change its displacement and its compression ratio actively during vehicle operation. This device can reduce the parasitic losses associated with supercharging and improve the relative fuel economy of a supercharged engine. Supercharging is a boosting choice with several advantages over turbocharging. There is fast pressure delivery to the engine intake manifold for fast engine torque response providing the fun to drive feel. The performance delivered by a supercharger can enable engine fuel economy actions to include engine downsizing and downspeeding. The cost and difficulty of engineering hot exhaust components is eliminated when using only an air side compressor. Faster catalyst warm up can be achieved when not warming the turbine housing of a turbocharger.

The aldehyde emissions of 1.6L and 5.0L flexible fuel vehicles (FFV) have been measured, with and without a catalyst, on a range of fuels. The “zero mile” catalyzed emission levels of formaldehyde when operating on M85 (85% methanol and 15% gasoline) are in the 5-15 mg/mi range, but as mileage accumulates they tend to be in the 30-50 mg/mi range. The feedgas levels are high and appear to correlate with engine displacement. The formaldehyde and methanol emissions are higher when operating on M100, compared to M85, but the non-oxygenated hydrocarbon emissions are about the same for both fuels, which suggests that the use of M85 may actually provide more air quality benefit than M100. High mileage control of aldehydes to the level of gasoline vehicles does not appear possible with current technology.

The pre EGR valve pressure is an important measurement for the Diesel engine air handling system. It is commonly used for the EGR flow calculation during engine transient operation. Due to the erosive exhaust gas, an EGR pressure sensor will eventually have gold corrosion resulting in drive-ability issues. Therefore, a software replacement for the EGR pressure sensor is desirable. However, when the EGR valve is on the cold side of the EGR cooler, the accuracy of the EGR pressure estimation deteriorates because of the variability of the pressure drop across the EGR cooler due to EGR cooler fouling. In this paper, an adaptive scheme is developed to improve the accuracy of pre EGR valve pressure estimation in the presence of EGR cooler fouling for diesel engines. The pressure drop across the EGR cooler is shown to be proportional to the velocity pressure of the EGR flow through the cooler.

The AFR control accuracy in the cold start is crucial to lowering emissions from IC-engine vehicles. An artificial UEGO “sensor” for estimating the real-time AFR during the engine cold start has been developed on the basis of a fuel-perturbation algorithm at Ford Scientific Research Labs. The AFR values calculated by the artificial UEGO sensor have been used in the closed-loop fuel control. Considering that the engine cold start AFR is an uncertain, non-linear problem, some other techniques for optimizing the input stimulation signal and the output-filtering model are integrated together with the fuel perturbation. This artificial sensor was realized and its performance was tested on a Ford vehicle for EPA75 cold 505 test. The assessment of the artificial sensor was quite different in comparison with that of a real UEGO sensor.

Electrically assisted turbochargers are a promising technology for improving boost response of turbocharged engines. These systems include a turbocharger shaft mounted electric motor/generator. In the assist mode, electrical energy is applied to the turbocharger shaft via the motor function, while in the regenerative mode energy can be extracted from the shaft via the generator function, hence these systems are also referred to as regenerative electrically assisted turbochargers (REAT). REAT allows simultaneous improvement of boost response and fuel economy of boosted engines. This is achieved by optimally scheduling the electrical assist and regeneration actions. REAT also allows the exhaust turbine to operate within a narrow range of optimal vane positions relative to the unassisted variable geometry turbocharger (VGT). The ability to operate within a narrow range of VGT vane positions allows an opportunity for a more optimal turbine design for a REAT system.

Thermal effectiveness of Exhaust Gas Recirculation (EGR) coolers used in diesel engines can progressively decrease and stabilize over time due to inner fouling layer of the cooler tubes. Thermophoretic force has been identified as the major cause of diesel exhaust soot fouling, and models are proposed in the literature but improvements in simulation are needed especially for the long-term trend of soot deposition. To describe the fouling stabilization behavior, a removal mechanism is required to account for stabilization of the soot layer. Observations from previous experiments on surrogate circular tubes suggest there are three primary factors to determine removal mechanisms: surface temperature, thickness, and shear velocity. Based on this hypothesis, we developed a 1D CFD fouling model for predicting the thermal effectiveness reduction of real EGR coolers. The model includes the two competing mechanisms mentioned that results in fouling balance.

Tests are conducted to improve the use of exhaust gas recirculation on a single cylinder diesel engine with EGR stream treatment techniques that include intake heating, combustible substance oxidation, catalytic fuel reforming, and partial bypass-flow control. In parallel with the empirical work, theoretical modeling analyses are performed to investigate the effectiveness of the reforming process and the combined effects on the overall system efficiency. The research is aimed at stabilizing and expanding the limits of heavy EGR during steady and transient operations so that the individual limiting conditions of EGR can be better identified. Additionally, the heavy EGR is applied to enable in-cylinder low temperature combustion. The effectiveness of EGR treatment on engine emission and operating characteristics are therefore reported.

This paper provides an overview of the effects of blending ethanol with gasoline for use in spark ignition engines. The overview is written from the perspective of considering a future ethanol-gasoline blend for use in vehicles that have been designed to accommodate such a fuel. Therefore discussion of the effects of ethanol-gasoline blends on older legacy vehicles is not included. As background, highlights of future emissions regulations are discussed. The effects on fuel properties of blending ethanol and gasoline are described. The substantial increase in knock resistance and full load performance associated with the addition of ethanol to gasoline is illustrated with example data. Aspects of fuel efficiency enabled by increased ethanol content are reviewed, including downsizing and downspeeding opportunities, increased compression ratio, fundamental effects associated with ethanol combustion, and reduced enrichment requirement at high speed/high load conditions.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

The purpose of this work was to examine gasoline particle filters (GPFs) at high mileages. Soot levels for gasoline direct injection (GDI) engines are much lower than diesel engines; however, noncombustible material (ash) can cause increased backpressure, reduced power, and lower fuel economy. In this study, a post mortem was completed of two GPFs, one at 130,000 mi and the other at 150,000 mi, from two production 3.5L turbocharged GDI vehicles. The GPFs were ceramic wall-flow filters containing three-way catalytic washcoat and located downstream of conventional three-way catalysts. The oil consumption was measured to be approaching 23,000 mpqt for one vehicle and 30,000 mpqt for the other. The ash contained Ca, P, Zn, S, Fe, and catalytic washcoat. Approximately 50 wt% of the collected ash was non-lubricant derived. The filter capture efficiency of lubricant-derived ash was about 50% and the non-lubricant metal (mostly Fe) deposition rate was 0.9 to 1.2 g per 10,000 mi.

Phosphorous poisoning on customer-aged catalysts was investigated by material analysis and performance testing. Most of the phosphorus was associated with the oxide components in the washcoat. These contaminants were roughly classified as aluminum phosphate, cerium phosphate, zinc-calcium phosphate. Deactivation of the catalyst with aluminum phosphate was strong and followed a linear correlation from oxalic acid testing. Phosphorus scavenging additives were researched to inhibit increase of aluminum phosphate. According to thermodynamic calculations, lower free energy of compounds of additive and phosphate is expected to prevent formation of aluminum phosphate.

In gasoline Powertrain systems, the evaporative emission control (EVAP) system canister purge valve (CPV) can be actuated by pulse-width modulated (PWM) signals. The CPV is an electronically actuated solenoid. The PWM controlled CPV, when actuated, creates pressure pulsations in the system. This pulsation is sent back to the rest of the EVAP system. Given the right conditions, the fill limit vent valve (FLVV) inside the fuel tank can be excited. The FLVV internal components can be excited and produce noise. This noise can be objectionable to the occupants. Additional components within the EVAP system may also be excited in a similar way. This paper presents a bench test method using parts from vehicle’s EVAP system and other key fuel system components.

In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.

This paper describes the CFD modeling work conducted for the development and research of a Vortex Induced Stratification Combustion (VISC) system that demonstrated superior fuel economy benefits. The Ford in-house CFD code and simulation methodology were employed. In the VISC concept a vortex forms on the outside of the wide cone angle spray and transports fuel vapor from the spray to the spark plug gap. A spray model for an outward-opening pintle injector used in the engine was developed, tested, and implemented in the code. Modeling proved to be effective for design optimization and analysis. The CFD simulations revealed important physical phenomena associated with the spray-guided combustion system mixing preparation.