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Biofuels, such as ethanol and butanol, have been the subject of significant political and scientific attention, owing to concerns about climate change, global energy security, and the decline of world oil resources that is aggravated by the continuous increase in the demand for fossil fuels. This study evaluated the potential emissions impacts of different alcohol blends on a fleet of modern gasoline vehicles. Testing was conducted on a fleet of nine vehicles with different combinations of ten fuel blends over the Federal Test Procedure and Unified Cycle. The vehicles ranged in model year from 2007-2014 and included four vehicles with port fuel injection (PFI) fueling and five vehicles with direct injection (DI) fueling. The ten fuel blends included ethanol blends at concentrations of 10%, 15%, 20%, 51%, and 83% by volume and iso-butanol blends at concentrations of 16%, 24%, 32%, and 55% by volume, and an alcohol mixture giving 10% ethanol and 8% iso-butanol in the final blend.

For automotive applications, it is necessary to maximize the fuel conversion efficiency of a PEM direct-methanol fuel cell (DMFC) over the broadest possible dynamic range of power. The research reported here critically examines the efficiency of the DMFC stack when operated over a broad power range. This research establishes a basis for a control strategy that simultaneously: optimizes DMFC fuel conversion efficiency versus power level, leads into a system level optimization of efficiency vs. power, and provides an operational strategy for controlling a direct-methanol fuel cell for maximum fuel efficiency from minimum to maximum power demand. First, there is an explanation of the experimental conditions used to obtain the DMFC experimental data that is reported and analyzed. Next the DMFC methanol crossover phenomenon is discussed and characterized. Then the conceptual framework for the optimization of fuel conversion efficiency is presented.

The paper is based on the premise that the sole purpose of combustion in piston engines is to generate pressure for pushing the expansion process away from the compression process (both expressed in terms of appropriate polytropes) to create a work producing cycle. This essential process, referred to as the dynamic stage of combustion, is carved out of the cycle and its salient properties deduced from the measured pressure profile, as a solution of an inverse problem: deduction of information on an action from its outcome. An analytical technique, construed for this purpose, is first presented and, then, applied to a direct injection, spark-ignition, methanol fueled four-stroke engine.

Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquified petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide. nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs.

We assessed the engine-out emissions of an ultra-low sulfur diesel (ULSD) and a neat hydrogenated vegetable oil (HVO) from a light-duty diesel truck equipped with common rail direct injection. The vehicle was tested at least twice on each fuel using the LA-92 drive cycle and at steady-state conditions at 30 mph and 50 mph at different loads. Results showed reductions in the engine-out total hydrocarbon (THC), carbon monoxide (CO), nitrogen oxide (NOx), and particulate emissions with HVO. The reductions in soot mass, solid particle number, and particulate matter (PM) mass emissions with HVO were due to the absence of aromatic and polyaromatic hydrocarbon compounds, as well as sulfur species, which are known precursors of soot formation. Volumetric fuel economy, calculated based on the carbon balance method, did not show statistically significant differences between the fuels.

The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.

Steady-state, transient and dithering characteristics of emission conversion efficiencies of three-way catalysts on natural gas IC engine were investigated experimentally on a single-cylinder CFR engine test bench. Steady-state runs were conducted as references for specific engine emission levels and corresponding catalyst capacities. The steady-state data showed that conversion of HC will be the major problem since conversion of HC was effective only for a very narrow range of exhaust mixture. Unsteady exploration runs with both lean-to-rich and rich-to-lean transitions were conducted. These results were interpreted with a time scale analysis, according to which a qualitative oxygen storage model was proposed featuring the difference between oxygen absorption and desorption rates on the palladium catalysts.

Significant improvement of engine performance can be achieved by ushering in a micro-electronic system to control the execution of combustion - an exothermic process whose sole purpose is to generate pressure. Hence, the primary feedback for the controller is provided by a pressure transducer. The activators are piezo-electrically activated pintle valves of MEMS type. The task of the micro-electronic processor is to provide an accurate feed-forward signal for the actuators on the basis of the information obtained from the feedback signal, within a time interval between consecutive cycles. Furnished here for this purpose is an algorithm for an interface module between the pressure sensor and the governor. Concomitantly, the gains thus attainable in the reduction of fuel consumption and curtailment of pollutant formation are thereby assessed. The implementation of this method of approach is illustrated by application to a HCCI engine.

The sole purpose of combustion in a piston engine is to generate pressure in order to push the piston and produce work. Pressure diagnostics provides means to deduce data on the execution of the exothermic process of combustion in an engine cylinder from a measured pressure profile. Its task is that of an inverse problem: evaluation of the mechanism of a system from its measured output. The dynamic properties of the closed system in a piston engine are expressed in terms of a dynamic stage - the transition between the processes of compression and expansion. All the phenomena taking place in its course were analyzed in the predecessor of this paper, SAE 2002-01-0998. Here, on one hand, its concept is restricted to the purely dynamic effects, while on the other, the transformation of system components, taking place in the course of the exothermic chemical reaction to raise pressure, are taken into account by the exothermic stage.

Presented here is a reportage of the panel debate on the proposition: “Is there a future for internal combustion engines beyond the technologies of Otto and Diesel?,” held at the SAE 2001 Congress. This is preceded by a recount of all the panel discussions on the future of combustion in engines, which have taken place at the SAE Congresses since 1997. In a commentary following the reportage, a prospective view of the future is provided. It puts forth the concept that the technology, inherited over a hundred years ago from Otto and Diesel, by which the exothermic process of combustion is executed in an engine cylinder, can be advanced significantly by adopting the best that modern micro-electronic and MEMS technology can offer.

The paper presents reportage of the debate on the topic expressed by its title that was held as a special session at the SAE 2003 Congress, supplemented by commentaries on its highlights. The debate brought to focus the fact that fuel cells are, indeed, superb powerplants for automobiles, while hydrogen is at the pinnacle of superiority as the most refined fuel. The problems that remained unresolved, are: (1) when fuel cells will be practically viable to replace internal combustion engines and (2) under what circumstances hydrogen, as the ultimate fuel, will be economically viable in view of its intrinsically high cost and hazards engendered by its extraordinary flammability and explosive tendency.

Engine manufacturers have explored many routes to reducing the emissions of harmful pollutants and conserving energy resources, including development of after treatment systems to reduce the concentration of pollutants in the engine exhaust, using alternative fuels, and using alternative fuels with after treatment systems. Liquefied petroleum gas (LPG) is one alternative fuel in use and this paper will discuss emission measurements for several LPG vehicles. Regulated emissions were measured for five school buses, one box truck, and two small buses over a cold start Urban Dynamometer Driving Schedule (CS_UDDS), the Urban Dynamometer Driving Schedule (UDDS), and the Central Business District (CBD) cycle. In general, there were no significant differences in the gas phase emissions between the UDDS and the CBD test cycles. For the CS-UDDS cycle the total hydrocarbons and non-methane hydrocarbon emissions are higher than they are from the UDDS cycle.

Gasoline direct injection (GDI) engines have improved thermodynamic efficiency (and thus lower fuel consumption) and power output compared with port fuel injection (PFI) and their penetration is expected to rapidly grow in the near future in the U.S. market. In addition, the use of alternative fuels is expanding, with a potential increase in ethanol content beyond the current 10%. Increased emphasis has been placed on butanol due to its more favorable fuel properties, as well as new developments in production processes. This study explores the influence of mid-level ethanol and iso-butanol blends on criteria emissions, gaseous air toxics, and particulate emissions from two wall-guided gasoline direct injection passenger cars fitted with three-way catalysts. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer.

This paper follows a cycle-simulation method for creating an engine performance map for an ethanol fueled boosted HCCI engine using a 1-dimensional engine model. Based on experimentally determined limits, the study defined operating conditions for the engine and performed a limited parameter sweep to determine the best efficiency case for each condition. The map is created using a 6-Zone HCCI combustion model coupled with a detailed chemical kinetic reaction mechanism for ethanol, and validated against engine data collected from a 1.9L 4-Cylinder VW TDI engine modified to operate in HCCI mode. The engine was mapped between engine speeds of 900 and 3000 rpm, 1 and 3 bar intake pressure, and 0.2 and 0.4 equivalence ratio, resulting in loads between idle and 14.0 bar BMEP. Analysis of a number of trends for this specific engine map are presented, such as efficiency trends, effects of combustion phasing, intake temperature, engine load, engine speed, and operating strategy.