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The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

A gasoline Road Octane study was conducted by the Coordinating Research Council (CRC) to evaluate the effects of heavy aromatics (C9 and heavier) and ethanol content on Road Octane performance independent of Research Octane Number (RON) and Motor Octane Number (MON). Maximum-throttle and part-throttle Road ON’s were found to be well predicted by equations containing only RON and MON terms. Heavier aromatics were found to have a small adverse effect on both maximum-throttle and part-throttle Road ON independent of its direct effects on RON and MON. The all-car data did not show a significant ethanol-content effect, but eight of the thirty-seven cars did show significant effects for ethanol content.

A program of emission testing and carburetor adjustment to reduce the levels of hydrocarbons and carbon monoxide in the exhaust gases and to demonstrate fuel economy improvements was held in Charlottetown during the week of July 14 to 19, 1980. The program was a co-operative effort of the Centre of Energy Studies of the Technical University of Nova Scotia, the Mobile Sources Division of the Air Pollution Control Directorate, Environment Canada and the Prince Edward Island Energy Corporation. Five hundred and twenty vehicles were tested during the period. The program was well received by the public and indicated that only 32% of the vehicle fleet were within specification when initially tested. A large percentage of these vehicles were satisfactorily adjusted. Mailback record cards were used to obtain an indication of the improved fuel economy. The data suggests that a substantial saving in fuel can be attained through carburetor tuning for low exhaust emissions.

Controlled Auto Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), is one of the most promising combustion technologies to reduce the fuel consumption and NOx emissions. Currently, CAI combustion is constrained at part load operation conditions because of misfire at low load and knocking combustion at high load, and the lack of effective means to control the combustion process. Extending its operating range including high load boundary towards full load and low load boundary towards idle in order to allow the CAI engine to meet the demand of whole vehicle driving cycles, has become one of the key issues facing the industrialisation of CAI/HCCI technology. Furthermore, this combustion mode should be compatible with different fuels, and can switch back to conventional spark ignition operation when necessary. In this paper, the CAI operation is demonstrated on a 2-stroke gasoline direct injection (GDI) engine equipped with a poppet valve train.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.

Today turbo-diesel powertrains offering low fuel consumption and good low-end torque comprise a significant fraction of the light-duty vehicle market in Europe. Global CO₂ regulation and customer fuel prices are expected to continue providing pressure for powertrain fuel efficiency. However, regulated emissions for NO and particulate matter have the potential to further expand the incremental cost of diesel powertrain applications. Vehicle segments with the most cost sensitivity like compacts under 1400 kg weight look for alternatives to meet the CO₂ challenge but maintain an attractive customer offering. In this paper the concepts of downsizing and downspeeding gasoline engines are explored while meeting performance needs through increased BMEP to maintain good driveability and vehicle launch dynamics. A critical enabler for the solution is adoption of gasoline direct injection (GDi) fuel systems.

Until recently, the application of the detailed chemistry approach as a predictive tool for engine modeling has been sort of a “taboo” for different reasons, mainly because of an exaggerated rigor to the chemistry/turbulence interaction modeling. In terms of this ideology, if the interaction cannot be simulated properly, the detailed chemistry approach makes no sense. The novelty of the proposed methodology is the coupling of a generalized partially stirred reactor, PaSR, model with the high efficiency numerics to treat detailed oxidation kinetics of hydrocarbon fuels. In terms of this approach, chemical processes are assumed to proceed in two successive steps: the reaction follows after the micro-mixing is completed on a sub-grid scale.

The fuel injection in internal combustion engines plays a crucial role in the mixture formation, combustion process and pollutants' emission. Its correct modeling is fundamental to the prediction of an engine performance through a computational fluid dynamics simulation. In the first part of this work a tridimensional numerical simulation of a multi-hole’s injector, using ethanol as fuel, is presented. The numerical simulation results were compared to experimental data from a fuel spray injection bench test in a quiescent vessel. The break up model applied to the simulation was the combined Kelvin-Helmholtz Rayleigh-Taylor, and a sensitivity analysis of the liquid fuel penetration curve, as well on the overall spray shape was performed according to the model constants. Experimental spray images were used to aid the model tuning. The final configuration of the KH-RT model constants that showed best agreement with the measured spray was C3 equal to 0.5, B1, 7 and Cb, 0.

Starting with the laboratory study, the amount of exhaust emission compound dissolved in water was measured, and the divergence of exhaust emission compounds was reviewed. Measurements were taken for hydrocarbon (HC), especially benzene, toluene, m-Xylene, p-Xylene, and o-Xylene. It was verified that the amount of exhaust emission compounds dissolved in water has positive correlation with the volume of exhaust gas introduced into the water. The dissolved amount was smaller with the low emission engine model. Volatile Organic Compound (VOC) decreased sharply at the beginning, but the decrement got smaller after a certain period of time. Next research was performed on the actual river where PWC are being used. We looked into the possible correlation between the VOC's concentration in water and the distance to the water where a lot of PWC's are running. In addition the MTBE (Methyl Tertiary-Butyl Ether) concentration was measured.

The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).

A 500 hours endurance test was performed with a heavy-duty engine (Euro IV); MAN type D 0836 LFL 51 equipped with a PM-Kat®. As fuel 100% biodiesel was used that met the European specification EN 14214. The 500 hours endurance test included both the European stationary and transient cycle (ESC and ETC) as well as longer stationary phases. During the test, regulated emissions (carbon monoxide, nitrogen oxides, hydrocarbons and particulate matter), the particle number distribution and the aldehydes emission were continuously measured. For comparison, tests with fossil diesel fuel were performed before and after the endurance test. During the endurance test, the engine was failure-free for 500 hours with the biogenic fuel. There were almost no differences in specific fuel consumption during the test, but the average exhaust gas temperature increased by about 15°C over the time. Emissions changed only slightly during the test.

The quality of mixture formation and the combustion process is of significant importance for reducing the hydrocarbon emissions of small two stroke engines. The scope of this work was to investigate the mixture conditions after the exhaust closes and after the end of combustion depending on various engine operating points. For this experimental investigation a Gas Sampling Valve (GSV) was combined with a flame ionisation detector (FID) and a CO2-analyser. Using this technique, it was possible to measure the hydrocarbon concentration after end of combustion. Furthermore the local residual gas concentration after exhaust closes was determined. To allow for a comparison of the experimental results with calculations with CFD codes, in cylinder pressure measurement and exhaust gas measurements are done additionally.

Characteristics of mass emission of unburned Oil-Particulate Matter and polycyclic aromatic hydrocarbons from two-stroke scooter were investigated. The tests were carried out under with and without oxidation catalyst and various air-fuel ratio ranging from 12 to 16 at 50:1 of fuel-oil mixing ratio for easy sampling. Unburned Oil-Particulate Matter and 4- to 7-rings polycyclic aromatic hydrocarbons were trapped on filter. These compounds were analyzed by high performance liquid chromatography with fluorescence detector. Mass emission of polycyclic aromatic hydrocarbons and unburned Oil-Particulate Matter tends to decrease as air-fuel ratio which increased up to stoichiometric ratio. The highest conversion ratio of unburned Oil-Particulate Matter on the oxidation catalyst was 64%. Conversion ratio of polycyclic aromatic hydrocarbons increased as rings are smaller.

In July 1997, the Pacific Northwest and Alaska Regional Bioenergy Program, in cooperation with several industrial and institutional partners initiated a long-haul 322,000 km (200,000 mile) operational demonstration using a biodiesel and diesel fuel blend in a 324 kW (435 HP), Caterpillar 3406E Engine, and a Kenworth Class 8 heavy duty truck. This project was designed to: develop definitive biodiesel performance information, collect emissions data for both regulated and non-regulated compounds including mutagenic activity, and collect heavy-duty operational engine performance and durability information. To assess long-term engine durability and wear; including injector, valve and port deposit formations; the engine was dismantled for inspection and evaluation at the conclusion of the demonstration. The fuel used was a 50% blend of biodiesel produced from used cooking oil (hydrogenated soy ethyl ester) and 50% 2-D petroleum diesel.

A 3 way catalytic converter (3WCC) model based on a global kinetic model was developed and validated against laboratory scale and engine test bench experiments. Various equivalence ratios and temperatures were tested. A methodology was finalized and applied to calibrate the kinetic constants. Laboratory scale experiments were first used to characterize the reaction mechanism during light-off, including the way reduction and oxidation reactions begin and compete with each other when temperature increases. The numerical results are in good agreement with the laboratory scale light-off results. Also, when adapted to simulate the engine test bench experiments, the model is able to correctly reproduce both the light-off tests and the 3WCC conversion efficiency evolution versus equivalence ratio. A calibration method in two steps was thus established and successfully used. The combination of modeling with experimental work appeared to be a powerful tool to determine the reaction mechanism.

Through an addition of a small amount of hydrogen to the main fuel, combustion process can be considerably enhanced in internal combustion engines producing significantly lower levels of exhaust emissions. This improvement in combustion can be mainly attributed to the faster and cleaner burning characteristics of hydrogen in comparison to conventional liquid and gaseous fuels. An oxygen-enrichment of a fuel-air mixture also improves thermal efficiency and reduces especially particulate, carbon monoxide and unburned hydrocarbon emissions in exhaust. This contribution describes the results of experimental investigation where a small amount of hydrogen and oxygen is produced by Hydrogen Generating System through the electrical dissociation of water and are added to the intake of a compression ignition engine operating on a commercial diesel fuel. It is shown that level of exhaust emissions including NOx can be moderately reduced using such a pre-treatment method in diesel engines.

This paper describes the performance of a single, multifunctional additive that alleviates many of the common gasoline and Diesel fuel problems. The additive has been deemed “substantially similar” by the EPA and thus may be used for bulk treatment of unleaded gasoline. Test data obtained from several independent laboratories are presented. The results show that the additive limits octane requirement increase (ORI) to an average of about 30% of that experienced when using untreated gasolines; reduces hydrocarbon emissions by the order of 10% or more; improves fuel economy approximately 1.5% - and often much more - in a variety of engines; and also reduces exhaust valve recession and combustion chamber deposits. The additive effects on Diesel engine performance and on combustion modification in both gasoline and Diesel engines will be reported later.

Life Cycle Analysis (LCA) considers the key environmental impacts for the entire life cycle of alternative products or processes in order to select the best alternative. An ideal LCA would be an expensive and time consuming process because any product or process typically involves many interacting systems and a considerable amount of data must be analysed for each system. Practical LCA methods approximate the results of an ideal analysis by setting limited analysis boundaries and by accepting some uncertainty in the data values for the systems considered. However, there is no consensus in the LCA field on the correct method of selecting boundaries or on the treatment of data set uncertainty. This paper demonstrates a new method of selecting system boundaries for LCA studies and presents a brief discussion on applying Monte Carlo Analysis to treat the uncertainty questions in LCA.

An advanced catalytic exhaust after-treatment system addresses the problem of NOX emissions from heavy-duty diesel trucks, relying on real-time catalyst modelling. The system consists of de-NOX catalysts, a device for injection of a reducing agent (diesel fuel) upstream the catalysts, and computer programmes to control the injection of the reducing agent and to model the engine and catalysts in real time. Experiments with 5 different air-assisted injectors were performed to determine the effect of injector design on the distribution of the injected diesel in the exhaust gas stream. A two-injector set-up was investigated to determine whether system efficiency could be increased without increasing the amount of catalyst or the amount of reducing agent necessary for the desired outcome. The results were verified by performing European standard transient cycle tests as well as stationary tests.

This paper reports the results of an exhaust emissions characterization from the non-catalyst control systems employed on the Mazda RX-4 rotary, the Honda CVCC, and the Chrysler electronic lean burn. Throughout the paper, exhaust emissions from these vehicles are compared to those from a Chrysler equipped with an oxidation catalyst and an air pump. The emissions characterized are carbon monoxide, hydrocarbons, nitrogen oxides, sulfur dioxide, sulfates, hydrogen sulfide, carbonyl sulfide, hydrogen cyanide, aldehydes, particulate matter, and detailed hydrocarbons. A brief description of the sampling and analysis procedures used is included within the discussion.