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In this study, characteristics of the development and auto-ignition/combustion of hydrogen jets were investigated in a constant-volume vessel. The authors focused on the effects of the jet developing process and thermodynamic states of the ambient gas on auto-ignition delays of hydrogen jets. The results show that the ambient gas temperature and nozzle-hole diameter are significantly effective parameters. By contrast, it is clarified that the ambient gas oxygen concentration has a weak effect on the auto-ignition/combustion of hydrogen jets. Consequently, it is supposed that the mixture formation process is capable of improving the auto-ignition/combustion of hydrogen jets.

One of the most effective means of improving the thermal efficiency and the specific fuel consumption in spark ignition engines is the increase of the compression ratio. However, there is a limit to it because of the generation of knocking combustion due to the rise of temperature and pressure in the unburnt mixture. Also in turbo charged spark ignition engines, the ignition timing cannot be advanced until MBT in order to avoid the knocking phenomena. Generally speaking, it is very difficult to investigate the phenomena in an actual engine, because there are many restriction and the phenomena are too complex and too fast. According-ly, it is advantageous to reveal the phenomena fundamentally, including the autoignition process of the end-gas by using simplified model equipment. Therefore, a rapid compression and expansion machine (RCEM) with a pan-cake combustion chamber was designed and developed for the experiments presented here.

We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved fuel is expected to undergo flash boiling or gas separation when being injected into the combustion chamber and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Also the internal EGR effect caused by CO2 injected with the fuel is expected to NO formation. In order to assess this concept, combustion experiments were carried out using a rapid compression and expansion machine. Thus, flame characteristics and heat release rate were analyzed for the combustion process of diesel fuel and CO2 mixed fuel. And, it is revealed that the diesel fuel-liquefied CO2 mixed fuel can successfully reduce NO emission in a diesel combustion system.

There is a concept that the increase in the temperature of charge in a combustion chamber and the shield of heat transferred through a chamber wall can facilitate the oxidation of soot and reduce the discharge of soot from the engine. In the experiments presented here in, an IDI diesel engine was used to inspect the concept. The engine was installed a bigger sized cylindrical swirl chamber which was equipped with two flat quarts windows, in order to observe the combustion phenomena and to apply the optical measurement. The experiments were carried out using two types of divided chambers, that is, the swirl chamber made of ceramics and that made of steel, to examine the the effects mentioned above.

A transient gas jet seems to be a model of a diesel spray because it has no vaporization process. Recently, CNG is utilized in a diesel engine. In the case of diesel engine, sprays or jets have the free state in some cases, and they are impinging surely on the piston surface in the other cases. The 2-D image of acetylene gas with tracer particles was taken by high-speed photography. In both jets, the outer shape was measured on the images and the characteristics of the internal flow was obtained by particle image velocimetry. Then, the physical models of these jets were constructed by use of experimental results.

It is very significant to take the intermediate products in diesel combustion for understanding the generation of exhaust emissions like SOF, dry soot and so on. The products generated in a constant volume combustion chamber were sampled by pricking a sheet of polyester film installed in the chamber to freeze the chemical reaction. The gas was analyzed by a gas chromatography. The fuel used was n-heptane. It is able to explain the generation of exhaust emissions by the experimental results. The other objective is to simulate the intermediate products. It is capable of explaining the relation between the simulated and experimental results.

CNG is one of the future fuel for a CI engine. Recently, the general tendency is the use of the high pressure injection system over 100 MPa in a CI engine for the near future severe regulation. Combustion phenomenon in a CI engine with such injection system is like a transient gas diffusion flame. The flow in a gas diffusion flame was investigated by the particle image velocimetry on its 2-D images, the relative soot concentration, the temperature and the relative CO2 concentration was detected in the experiments. And the model of transient gas diffusion flame was constructed by use of experimental data.

Knocking phenomenon in a spark ignition engine breaks out due to autoignition in the unburned gas region. Investigation on the pre-autoignition reaction, that is, the reaction of cool and blue flames happening before autoignition must be carried out in detail to control knocking. The reactions appear in an extremely short time before autoignition, so, much difficulties accompany an attempt to grasp the situation. In the experiments presented hear, progress situation of pre-autoignition reaction was made clear by visualized phenomena in a rapid compression and expansion machine (R.C.E.M), which had good reproducibility. Taken by two ultra high-speed video cameras. We determined the ignition delay time was caught by analyzing the emission of light from the combustion chamber before knocking occurrence.

Diesel sprays injected into a combustion chamber of a small sized high-speed CI engine impinge surely on a piston surface and a cylinder wall. As a consequence, their vaporization, mixture formation and combustion processes are affected by impingement phenomena. And the other important factors affecting on the processes is the injection pressure. Then, the distribution of the vapor concentration in a single diesel spray impinging on a flat and hot wall was experimented by the exciplex fluorescence method, as a simple case. The injection pressure was varied in the range from 55 MPa to 120 MPa. It is found that the distribution of the vapor concentration in this case is much leaner than that in the case of the low injection pressure of 17.8MPa.

A single cylinder engine has been run with direct-injection premixed charge compression ignition (PCCI) operation. The operation is fueled with primary reference fuels for a wide variety of injection timing and equivalence ratio to investigate the effect of charge stratification and octane rating on PCCI combustion. The test results showed that although the change of the injection timing can gain the high combustion efficiency for a wide range of equivalence ratio, the combustion phasing where the high combustion efficiency is accomplished is not varied only by changing the injection timings. Therefore, the only change of injection timings does not improve the thermal efficiency which is influenced by the combustion phasing. On the other hand, at the fixed compression ratio, inlet air temperature and so on, the octane rating is useful in altering the combustion phasing.

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

Soot formation process inside the combustion chamber of an DI diesel engine is focused as a phenomenological basic scheme by using several optical diagnostics technique for the improvement of diesel exhaust emission. We have conducted the series of optical measurement research for the clarification of combustion field in an DI diesel engine. Then, this paper is a kind of review by adding the fuel vapor properties and particle image velocimetry (PIV) analysis with focusing the soot formation process. The experiments were carried out in a small sized high-speed DI diesel engine installed with an optical access view. The spray characteristics and its flow field in 2-D field were measured by laser sheet scattering (LIS) method and PIV scheme.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

In this study, a rapid compression and expansion machine(RCEM) with a pancake combustion chamber was designed to investigate fundamentally on the knocking phenomena in spark ignition(S.I) engines. This RCEM is intended to simulate combustion in an actual engine. The homogeneous pre-mixture of n-pentane and air was charged into a quiescent atmosphere of the chamber. Then, the combustion field become simpler in this machine than it in a real S.I. engine. Also, the combustion phenomena, that is a cylinder pressure history, the behavior of flame propagation and so on, with high reproducibility are realized in this machine. The phenomena caught in this experiment were so-called low speed knocking. And, this knocking characteristics such as a knock intensity and a knock mass fraction were revealed by the cylinder pressure analysis varying the charge pressure and the equivalence ratio of the mixture, a compression ratio and an ignition timing.

We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by use of the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved component is expected to undergo flash boiling or gas separation when being injected into the combustion chamber, and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Further, the internal EGR effect caused by CO2 component injected with the fuel is expected for NO formation. In order to assess this concept, spray dynamics measurement was conducted in the constant volume vessel with a variation of ambient pressure and temperature. Further, combustion experiments were carried out by using a rapid compression and expansion machine. Here, characteristics of the evaporative mixed fuel spray were examined by shadowgraph photography.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.

In previous multi-dimensional modeling on spray dynamics and vapor formation, single component fuel with pure substance has been analyzed to assess the mixture formation. Then it should be expected that the evaporation process could be performed for the multicomponent fuel such as actual Gasoline and Diesel gas oil. In this study, vapor-liquid equilibrium prediction was conducted for multicomponent fuels such as 3 and 10 components mixed solution with ideal solution analysis and non-ideal solution analysis. And the computation of distillation characteristics was conducted for the steady state fuel condition fuel condition to understand the evaporation process. As a result, calculated distillation characteristics are consistent well with experiment results. And the evaporation process of a multicomponent droplet in the combustion chamber has been calculated with the variation of ambient pressure and temperature.

In the internal combustion engines, combustion characteristics relating to HC & NO emission are affected remarkably by the spatial distribution of fuel concentration, temperature and turbulence properties. Especially, No formation process inside the combustion chamber affected by the mixture concentration field should be focused relating to the flame field temperature distribution. As the first step of NO formation study in premixed combustion field, NO formation process in the chamber was examined by considering OH radical property and flame temperature in homogeneous mixture conditions. In this study, in order to clarify NO formation process inside the transient premixed combustion field, relative concentration fields of OH radical and NO and temperature fields were measured by laser induced fluorescence technique(LIF) in the constant volume vessel for methane-air homogeneous mixture with the variation of equivalent ratio of the mixture.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

Four kinds of optical measurements were performed to investigate the process of soot formation and oxidation in a direct-injection (DI) diesel engine. Measurements were carried out in an optically accessible DI diesel engine that allows planar laser sheet for combustion diagnostics to enter the combustion chamber either horizontally or along the axis of the fuel jet. The temporal and spatial distribution of soot particles has been investigated using the laser- induced incandescence (LII) and high-speed direct photography. Fuel vapor concentration, which is directly linked to the soot formation process in diesel combustion, has been deduced from the images obtained by the measurements of laser shadowgraph and elastic Mie scattering. According to the experimental results, soot formation begins to occur near the injector nozzle in which a fuel-rich mixture is distributed with a homogeneous condition. LII signal is dominated by the fuel vapor concentration in initial combustion period.