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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

A direct injection system in which fuel was injected through the cylinder wall was developed and detailed investigation was made for the purpose of reducing short-circuit of fuel in 2-stroke engines. As a result of dynamo tests using 430cc single cylinder engine, it was found that the injector was best attached at a location as close to TDC as possible on the rear transfer port side, and that the entire amount of fuel should be injected towards the piston top surface. Emissions were worsened if fuel was injected towards the exhaust port or spark plug. Although the higher injection pressure resulted in large emissions reduction effects, it did not have a significant effect on fuel consumption. When a butterfly exhaust valve, known to be effective against irregular combustion in the light load range, was applied, it was found to lead to further reductions in HC emission and fuel consumption while also improving combustion stability.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

A fast time-scale 1-D dynamic diesel particulate filter model capable of resolving the pressure pulsations due to individual cylinder firing events is presented. The purpose of this model is to investigate changes in the firing frequency component of the pulsating exhaust flow at different particulate loadings. Experimental validation data and simulation results clearly show that the magnitude and phase of the firing frequency components are directly correlated to the mass of particulate stored in a diesel particulate filter. This dynamic pressure signal information may prove particularly useful for monitoring particulate load during vehicle operation.

In order to comply with the existing emission norms of BSIII in India or EURO III and beyond that also, it is not sufficient to use the catalytic converter technology alone over the wide range of engine operating maps. Different studies across the world have proved that the cost, drivability, operating range against AFR, heat dissipation rate characteristics of catalytic converter limit their use in startup and idling conditions. One common way to tackle this condition is to use the Secondary Air Injection (SAI) system. In this system, small amount of air is injected after the exhaust port to initiate the thermal oxidation of gases. The right amount of air injected at the right time and at right location will reduce the emission by 37-90%. In the following study, SI engine vehicle with single cylinder, 160 cc and having carburetor is used as a test vehicle to evaluate the performance of SAI. The SAI system is modeled in AVL BOOST software and validated against the experimental data.

It is well known that backpressure is one of the important parameters to be minimised during the exhaust system development. Unfortunately, during the first phases of an engineering process of a new engine, engine prototypes are not available yet. Due to this the exhaust system backpressure is generally evaluated using simulation software, and/or measuring the backpressure by a flow rig test at room temperature. Goal of this paper is to compare exhaust backpressure results obtained respectively: i) at the room temperature flow rig; ii) at the engine dyno bench; iii) by simulation with one of the most common 1D fluidodynamics simulation tool (Gt-Power). A correlation of the three different techniques is presented.