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It has been clarified that diesel fuel properties have a great effect on the exhaust emissions and fuel consumption of a conventional diesel combustion regime. And as other diesel combustion regimes are applied in order to improve exhaust emissions and fuel consumption, it can be supposed that the fuel properties also have significant effects. The purpose of this study is to propose the optimum diesel fuel properties for a premixed compression ignition (PCI) combustion regime. In this paper, the effect of the auto-ignitability of diesel fuels on exhaust emissions and fuel consumption was evaluated using a heavy-duty single-cylinder test engine. In all experiments, fuels were injected using an electronically controlled, common-rail diesel fuel injector, and most experiments were conducted under high EGR conditions in order to reduce NOx emissions.

Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.

This work aimed to develop an LPG fueled direct injection SI engine, especially in order to improve the exhaust emission quality while maintaining high thermal efficiency comparable to a conventional engine. In-cylinder direct injection engines developed recently worldwide utilizes the stratified charge formation technique at low load, whereas at high load, a close-to-homogeneous charge is formed. Thus, compared to a conventional port injection engine, a significant improvement of fuel consumption and power can be achieved. To implement such a combustion strategy, the stratification of mixture charge is very important, and an understanding of its combustion process is also inevitably necessary. In this work, a numerical simulation was performed using a CFD code (KIVA-3), where the shape of a combustion chamber, swirl intensity, injection timing and duration, etc. were varied and their effects on the mixture formation and combustion process were investigated.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

Flame propagation characteristics, in a heavy-duty type LPG lean burn SI engine, were investigated by simulation methodology, using the global one step and the ten step chemical kinetic reaction mechanisms, respectively. The swirl ratio and equivalence ratio were varied to investigate their effects on flame front speed. The effect of increased swirl intensity on flame speed was very minor at ranges of equivalence ratio of this study. Flame front shape, however, was affected by swirl intensity. Circular flame front formed for a higher swirl ratio, which is in a qualitative accordance with that of measurements. Comparison between calculation and measurements of flame propagation characteristics shows a good agreement for both the global one step and the ten step chemical kinetic model. This work concludes that the reduced chemical kinetic reactions, consisting of ten steps, is useful for flame propagation study in an LPG SI engine.

For better understanding of the in-cylinder combustion characteristics of DME, combustion radicals of a direct injection DME-Fueled compression ignition engine were observed using a spectroscopic method. In this initial report, the emission intensity of OH, CH, CHO, C2 and NO radicals was measured using a photomultiplier. These radicals could be measured with wavelength resolution (half-width) of about 3.3 nm. OH and CHO radicals appeared first, and then CH radical emission was detected. After that, the combustion radicals were observed using a high-speed image intensified video camera. C2 and CH radicals were able to observe roughly as images. However, the emission intensity of DME combustion was not strong enough to take OH, CHO and NO radical images. CH radical combustion occurred near the chamber wall and burned like a ring, as combustion progress, indicating active heat release occurred near the chamber wall.

Development of LPG SI and CI engines for heavy duty vehicles has been carried out. In order to measure the performance and emissions of an LPG lean burn SI engine, the piston cavity, swirl ratio, and propane-butane fuel ratio were varied and tested. Compared to the bathtub and dog dish cavities, the nebula type cavity showed the best performance in terms of cyclic variation and combustion duration. High swirl improved combustion by achieving a high thermal efficiency and low NOx emissions. A feasibility study of an LPG DI diesel engine also has been carried out to study the effectiveness of the selected cetane enhancing additives:Di-tertiary-butyl peroxide (DTBP). When more than 5 wt% DTBP was added to the base fuel, stable engine operation over a wide range of engine loads was possible. The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%.

To find more effective lean mixture preparation methods for smokeless and low NOx combustion, a numerical study of the effects of in-cylinder flow field before injection on mixture formation in a premixed compression ignition engine was conducted. Premixed compression ignition combustion is a very attractive method to reduce both NOx and soot emissions, but it still has some problems, such as high HC and CO emissions. In case of early direct injection, it is important to avoid wall wetting by spray impingement, which can cause higher HC and CO emissions. Since it is not easy to examine the effects of initial flow and injection parameters on mixture formation over the wide range by practical engine tests, a computer program named “GTT (Generalized Tank and Tube)” code was used to simulate the in-cylinder phenomena before autoignition.

In this study, the main properties of two types of gas-to-liquid (GTL) fuels were investigated. Then, performance and emission characteristics of a compression ignition engine fueled with GTLs were investigated by comparison with diesel fuel. GTL1 was composed of 100% paraffin by volume, and GTL2 was composed of 99.8% paraffin and 0.2% aromatics by volume. Most GTL fuel properties were comparable to those of diesel fuel, while both fuels have a higher cetane number and lower sulphur. A diesel engine could be operated with GTL fueling without any special engine modifications. Our tests showed that with the high cetane number of GTLs, the ignition delay was shorter, and combustion started earlier than with diesel fuel. With GTL1 operation, THC and soot emissions were lower than with diesel fuel operation, and even lower with GTL2 fueling.

DME as a fuel for compression ignition (diesel) engines has been actively studied for about ten years due to its characteristically low pollution and reputation as a “smokeless fuel”. During this time, the practical application is taking shape based on necessary tasks such as analysis of injection and combustion, engine performance, and development of experimental vehicles. At this moment, standardization of DME as a fuel was started under ISO in 2007. There are concerns regarding the impurities in DME regarding the mixing during production and distribution as well as their effect on additives for lubricity and odor. In this report, the effect of DME fuel impurities on performance of a DME powered diesel engine was investigated. The platform was a DME engine with common-rail fuel injection and was evaluated under partial load stable mode and Japanese transient mode (JE05) testing parameters.

The combustion mechanism of a fuel droplet cloud was studied by numerical simulation. We investigated how the flame front speed and combustion products changed depending on the equivalence ratio and initial temperature. Modeling was performed using the KIVA-III software package, a three dimensional analysis software used mainly for internal combustion engine applications. The computational domain was a horizontal 1x1x100 cell sector of a spherical combustion chamber and the fuel was n-decane. Results showed that when all the fuel droplets were assumed to have evaporated, the flame front speed increased from 28 cm/s to 152 cm/s as the equivalence ratio increased. The maximum flame front speed was reached at ϕ=1.1, beyond which it decreased (at richer overall equivalence ratios). With a constant equivalence ratio, the flame front speed decreased near the outside region, because the unburned gas was compressed by the expanding burned gas.

Dimethyl Ether (DME) is one of the major candidates for the next generation fuel for compression ignition (CI) engines. It has good self-ignitability and would not produce particulate, even at rich conditions. DME has proved to be able to apply to ordinary diesel engines with minimal modifications, but its combustion characteristics are not completely understood. In this study, the behavior of a DME spray and combustion process of a direct injection CI engine fueled with DME was investigated by combustion observation and in-cylinder gas sampling. To distinguish evaporated and non-evaporated zones of a spray, direct and schlieren imaging were carried out. The sampled gas from a DME spray was analyzed by gas chromatography, and the major intermediate product histories during ignition period were analyzed.

This is a preliminary work for the development of a stratified combustion engine using liquefied petroleum gas(LPG) as an alternative fuel. The main objective of this research is to find out the optimizing engine parameters from the viewpoint of mixture formation with the aid of simulation, where the KIVA_ code was used. The combustion characteristics of LPG and gasoline are different because of their different physical properties. Therefore, the numerical simulation was performed for optimizing engine parameters by changing the piston and cylinder geometry, as well as injection conditions. Result showed that geometry of combustion chamber has a great influence on mixture stratification. Also, weaker swirl seems to be better for mixture formation in the vicinity of the spark plug.

Using an extended bottom view piston having a quartz window, flame propagation observation and flame contour analysis were carried out to investigate the combustion characteristics of a heavy-duty type LPG lean burn engine. The swirl ratio and piston cavity configuration were varied to investigate their effects on combustion and engine performance. Gradual reduction of NOx but increased hydrocarbon emissions were measured for leaner mixtures compared to the stoichiometric operation. High swirl apparently accelerated the initial flame kernel development, as evidenced by a shorter crank angle interval from the spark ignition to the maximum cylinder pressure. The ‘D’ type cavity, with an increased squish area located below the intake valve, was shown to have the shortest burn duration among the piston cavities tested. The experimental flame propagation observation procedure was shown to be useful for the study of the combustion process in engines.

Performance and emissions of an LPG lean burn engine for heavy duty vehicles were measured. The piston cavity, swirl ratio, propane - butane fuel ratio, and EGR were varied to investigate their effects on combustion, and thus engine performance. Three piston cavities were tested: a circular flat-bottomed cavity with sloped walls (called the “bathtub” cavity), a round bottomed cavity (called the “dog dish” cavity), and a special high-turbulence cavity (called the “nebula” cavity). Compared to the bathtub and dog dish cavities, the nebula type cavity showed the best performance in terms of cyclic variation and combustion duration. It was capable of maintaining leaner combustion, thus resulting in the lowest NOx emissions. High swirl improved combustion by achieving a high thermal efficiency and low NOx emissions. In general, as the propane composition increased, cyclic variation fell, NOx emissions increased, and thermal efficiency was improved.

To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.

For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.

For better understanding of the in-cylinder combustion characteristics of DME, combustion radicals of a direct injection DME-Fueled compression ignition engine were observed using a spectroscopic method. In this initial report, the emission intensity of OH, CH, CHO, C2 and NO radicals was measured using a photomultiplier. These radicals could be measured with wavelength resolution (half-width) as about 3.3 nm. OH and CHO radicals appeared first, and then CH radical emission was detected. After that, the combustion radicals were observed using a high-speed image intensified video camera with band-pass filter. All of radicals were able to observe as images with half-width as 6 or about 10 nm. Rich DME leaked from nozzle was burning at the end of combustion. Therefore, the second light emission of C2 radical after the main combustion was observed.

Band spectrum images for CH, OH and CHO were taken in a heavy duty type LPG lean-burn SI engine, to investigate the combustion process as it pertains to the pollutant formation process in the post flame region. Full spectra and band spectrum flame images were observed with a bottom view single cylinder research engine and two high speed cameras. NOx emissions were also measured for excess air ratios ranging from 1.0 to 1.6. A thermodynamic model, including the detailed chemical kinetic mechanism for LPG and NOx formation reactions, was developed to predict the major reaction species in the post flame region, and NOx emissions during the combustion process. The model qualitatively described the flame images for each band spectrum and could predict the measured NOx emissions very well.

Spray characteristics of biodiesel oil was investigated as it can be applied to industrial combustion systems, including internal combustion engines. Shadowgraph methodology using Greenfield system was used to take some images of the spray and to measure droplet size. A high speed video camera was also used to take a picture of spray penetration and its angle. From the results, it shows that DME blended biodiesel oil has almost the same droplet size as conventional diesel oil, when the blended DME ratio is over 50% by weight. It is also shown that there exists optimum fuel injection pressure that has minimum droplet size when the ambient gas pressure is constant.