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The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

Predictive simulation models are needed in order to exploit the full benefits of 1-D engine simulation. Simulation model alterations such as cam phasing affect the gas composition and gas state in the cylinders and have an effect on the combustion. Modelling of these effects is particularly important when the engine is knock limited. A knock model, able to phase the combustion towards the knock limit, was previously developed by the authors. A major challenge in such knock models is to predict the pressure and temperature evolution in the end-gas accurately through an adequate combustion model. The Wiebe function is often used to model the combustion in SI engine simulations, owing to its ease of use and computational efficiency. The Wiebe function simply imposes a curve shape for the fuel burn rate and the parameters are easily determined from calculated heat release.

In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).

More stringent emissions standards along with higher fuel economy demands have obliged auto makers to develop technical solutions that exploit synergistic features from gasoline and diesel engines. To minimize NOx and soot trade-off, diesel powertrain has been developed to adopt increasingly complex and expensive technology such as extremely high pressure fuel injection systems, low pressure EGR, and variable valve timing. These attempts are associated with promoting Partially Premixed Charge Compression Ignition (PPC-CI) combustion via increasing mixing time and ignition delay. Alternatively, PPC-CI combustion can be achieved easier by using fuels with higher resistance to auto-ignition than conventional diesel fuel. Previous work has demonstrated the possibility of reducing the cost of future diesel after-treatment systems by using gasoline-like fuels.

Recent research [21] has shown that the compression ignition concept where very low cetane fuels (RON between 70 and 85) are run in compression ignition (CI) mode has several advantages. The engine will be at least as efficient and clean as the current diesel engines but will have a less complicated after-treatment system. The optimum fuel will be less processed and therefore simpler to make compared to current gasoline or diesel fuels. Naphtha, which is a product of the initial distillation of petroleum, is one such fuel. It provides a path to mitigate the global demand imbalance between heavier and lighter fuels that is otherwise projected. Since naphtha requires much less processing in the refinery than either gasoline or diesel [23], there is an additional benefit in terms of well-to-wheel CO2 emissions and overall energy consumed. Partially premixed charge compression ignition combustion with such a low cetane fuel has usually been investigated with a diesel engine base.

Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.

Conventional fossil fuels will constitute the majority of automotive fuels for the foreseeable future but will have to adapt to changes in engine technology. Unconventional transport fuels such as biofuels, gas-to-liquid fuels, compressed natural gas, and liquid petroleum gas will also play a role. Hydrogen might be a viable transport fuel if it overcomes barriers in production, transport, storage, and safety and/or if fuel cells become viable. This book opens by considering these issues and then introduces practical transport fuels. A chapter on engine deposits follows, which is an important practical topic about how fuels affect engines that is not usually considered in other books. The next three chapters discuss auto-ignition phenomena in engines. The auto-ignition resistance of fuels is the most important fuel property since it limits the efficiency of spark ignition engines and determines the performance of compression ignition engines.

This paper is the second of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This second study focuses on drive cycle simulations and Life Cycle Assessment (LCA) for vehicles equipped with Octane-on-Demand combustion. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. The experimental engine calibration maps developed in the previous study are first provided as inputs to a drive cycle simulation tool. This is used to quantify the total fuel consumption, octane requirement and tank-to-wheel CO2 emissions for a light-duty vehicle equipped with two alternative powertrain configurations. The properties of the lower octane fuel are shown to affect the vehicle fuel consumption and CO2 emissions significantly.

This paper is the first of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This first study focuses on the application of so-called Octane-on-Demand combustion, whereby the fuel anti-knock quality is customized to match the real-time requirements of an otherwise conventional spark-ignition engine. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. Experimental engine calibration maps are first developed to quantify the minimum amount of methanol that must be added to each lower octane fuel in order to reproduce the baseline engine performance attained on a market gasoline (RON 95). The properties of the lower octane fuel are shown to affect the engine performance significantly.

The objective of this paper is to present a simulation model for controlling combustion phasing in order to avoid knock in turbocharged SI engines. An empirically based knock model was integrated in a one-dimensional simulation tool. The empirical knock model was optimized and validated against engine tests for a variety of speeds and λ. This model can be used to optimize control strategies as well as design of new engine concepts. The model is able to predict knock onset with an accuracy of a few crank angle degrees. The phasing of the combustion provides information about optimal engine operating conditions.

Knock in spark ignition engines is stochastic in nature. It is caused by autoignition in hot spots in the unburned end-gas ahead of the expanding flame front. Knock onset in an engine cycle can be predicted using the Livengood-Wu integral if the variation of ignition delay with pressure and temperature as well as the pressure and temperature variation with crank angle are known. However, knock intensity (KI) is determined by the evolution of the pressure wave following knock onset. In an earlier paper (SAE 2017-01-0689) we showed that KI can be approximated by KI = Z (∂T/∂x)-2 at a fixed operating condition, where Z is a function of Pko, the pressure, and (∂T/∂x) is the temperature gradient in the hot spot at knock onset. Then, from experimental measurements of KI and Pko, using five different fuels, with the engine operating at boosted conditions, a probability density function for (∂T/∂x) was established.

In previous studies it has been shown that the auto-ignition quality of a fuel at a given engine condition can be described by an octane index defined as, OI=(1-K) RON + K MON, where RON and MON characterize the fuel and the K-value depends only on the engine design and operating conditions. It has been shown that the K-value is highly dependent on the pressure and temperature history. Another important parameter is OI0, the OI of the fuel which gives heat release centred at top dead center; OI0 can be considered to be the requirement of the engine. In previous work, empirical relations for both K and OI0 in terms of in-cylinder pressure and temperature and engine speed and mixture strength were found but the influence of EGR was not considered.