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The combustion processes of of lean mixtures of methane in air is examined by employing a detailed chemical kinetic scheme consisting of 178 elementary reaction steps with 41 species. The changes with time in the concentrations of the major relevant reactive species are determined from the preignition reactions to the time near equilibrium conditions. The results of such an approach to the combustion process are considered over a wide range of initial temperatures (1000 K - 1600 K) and equivalence ratios (0.2 - 1.2) while the pressure was kept at atmospheric. Calculated results obtained while using this model tend to be in good agreement with the corresponding experimental values of ignition delay. The ignition delay of methane-air mixture correlated by the following empirical expression in which constants A and B are function of the equivalence ratio while Ti is the initial mixture temperature in °K.

It is well known the dual fuel operation at lower loads suffers from lower thermal efficiency and higher unburned percentages of fuel. The present work includes a computational investigation to predict the effects of Exhaust gas recirculation (EGR) on the operation of an indirect-injection dual fuel (Ricardo-E6) engine by using a detailed chemical kinetic scheme and a quasi-two zone analytical model. The comprehensive chemical kinetic scheme for methane oxidation consisting of 178 elementary reaction steps with 41 species. A quasi-two zone analytical model is based on the effective energy releases of the pilot diesel fuel while using the detailed chemical reaction kinetic scheme for the oxidation of methane. Through the results, it was shown that, the active species such as H, O and OH produced in the high temperature combustion process and found in the exhaust gases are play a significant role in the preignition reactions.

A quasi-two zone predictive model developed in the present work for the prediction of the combustion processes in dual fuel engines and some of their performance features. Methane is used as the main fuel while employing a small quantity of liquid fuel (pilot) injected through the conventional diesel fuel system. This model emphasizes the effects of chemical kinetics activity of the premixed gaseous fuel on the combustion performance, while the role of the pilot fuel in the ignition and heat release processes is considered. A detailed chemical kinetic scheme consists of 178 elementary reaction steps and 41chemical species is employed to describe the oxidation of the gaseous fuel from the start of compression to the end of expansion process. Depend on the results of the sensitivity analysis, the detailed chemical kinetic scheme was simplified to another scheme consists of 41 elementary reaction steps and 17 chemical species to reduce the time of computations.