Diesel Oxidation Catalysts for Light Duty Vehicles. 2000-01-1422
The low exhaust gas temperatures experienced on light duty Diesel vehicles present a very challenging environment for the successful operation of catalytic aftertreatment. To meet the future more severe legislation, Diesel engines are being developed with greater combustion efficiencies and advanced fueling control. These engine developments may produce lower particulate matter (PM) and nitrogen oxides (NOx) emissions, but increased hydrocarbon (HC) and carbon monoxide (CO) emissions may occur. As a result of these engine changes exhaust gas temperatures may reduce still further. These factors demand catalysts with high oxidation activity at low temperatures.
This paper reviews oxidation catalyst technology developed for light duty Diesel vehicles and the factors affecting their performance. Results obtained on synthetic gas rigs, bench engines and vehicles are presented. A discussion oh the effect of the level of sulfur (S) present in Diesel fuel on aftertreatment is given. A Stage III TDI passenger vehicle equipped with advanced catalyst technology passed the European Stage III legislation after 80,000 km vehicle aging.