Impact of Hydrothermal Aging on the Formation and Decomposition of Ammonium Nitrate on a Cu/zeolite SCR Catalyst 2017-01-0946

Low-temperature (T ≤ 200°C) NO_x conversion is receiving increasing research attention due to continued potential reductions in regulated NO_x emissions from diesel engines. At these temperatures, ammonium salts (e.g., ammonium nitrate, ammonium (bi)sulfate, etc.) can form as a result of interactions between NH₃ and NO_x or SO_x, respectively. The formation of these salts can reduce the availability of NH₃ for NO_x conversion, block active catalyst sites, and result in the formation of N₂O, a regulated Greenhouse Gas (GHG). In this study, we investigate the effect of hydrothermal aging on the formation and decomposition of ammonium nitrate on a state-of-the-art Cu/zeolite selective catalytic reduction (SCR) catalyst. Reactor-based constant-temperature ammonium nitrate formation, temperature programmed oxidation (TPO), and NO titration experiments are used to characterize the effect of hydrothermal aging from 600 to 950°C. N₂ adsorption (BET) surface area and diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS) experiments are also conducted in order to correlate the morphological effects of hydrothermal aging with concomitant changes in ammonium nitrate chemistry. The insights provided herein support the diesel aftertreatment communities’ ongoing efforts to understand low-temperature chemical processes such as ammonium salt formation and their impact on emissions.