Analysis of Formaldehyde Scavenger and Its Reaction Products in POM Using Mass Spectrometry 2021-01-0360

To meet the indoor air quality guideline of newly manufactured vehicles in Korea, China, and other countries, low formaldehyde grade POM (Polyoxymethylene) is used for interior parts essentially. In this paper, formaldehyde scavengers from of 2 commercial low formaldehyde grade POM pellets were identified by LC-MS (Liquid chromatograph-Mass spectrometer) as sebacic dihydrazide and dodecanedioic dihydrazide respectively. The reaction products between formaldehyde and formaldehyde scavengers were also detected, which were converted from hydrazide to hydrazone. So, this kind of additive would be gradually consumed by repetitive molding process or exposure to heat according to formaldehyde emission increase. We are expecting to apply this analytical method and result for quality control and benchmark of low formaldehyde grade POM.