A multiplexed transmission system utilizing newly developed optical polymer has been proposed. The system is composed of a star-shaped optical network, in which optical signals can be transmitted bi-directionally through a fiber and optical branches between the central and local controllers. The new polymer optical fiber has been developed and adopted for this system, and it was designed to be durable to the high temperature in automotive engine rooms. The high temperature resistibility of the fiber has been achieved with utilization of a thermo-setting resin for the core materials. The optical loss characteristics of the fiber is as low as 0.50 dB/m at 660 nm wavelength.