A new technique was proposed for the simultaneous measurement of the concentration of fuel vapor and liquid in an evaporating diesel spray injected into a high temperature and high pressure environment. This technique was based on the principle of the absorption of ultraviolet laser light by fuel vapor and the scattering of visible laser light by fuel droplets in the diesel spray. For this principle, α-methylnaphthalene was used as a test fuel. Measuring the transmissivity of ultraviolet and visible laser lights absorbed and scattered by β-methylnaphthalene spray made it possible to analyze the fuel vapor concentration, droplets density and the mixture temperature in the diesel spray. A computerized tomographic transfer technique was also adopted to analyze three-dimensional fuel concentration distribution in the spray.