We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved fuel is expected to undergo flash boiling or gas separation when being injected into the combustion chamber and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Also the internal EGR effect caused by CO2 injected with the fuel is expected to NO formation. In order to assess this concept, combustion experiments were carried out using a rapid compression and expansion machine. Thus, flame characteristics and heat release rate were analyzed for the combustion process of diesel fuel and CO2 mixed fuel. And, it is revealed that the diesel fuel-liquefied CO2 mixed fuel can successfully reduce NO emission in a diesel combustion system.