Inevitably a fraction of the hydrocarbon fuel in spark ignition engines escapes in-cylinder combustion and flows out with the burned products. Post combustion oxidation in the cylinder and exhaust port may consume a part of this fuel and plays an important role in determining exhaust emission levels. This paper presents results from experiments designed to identify the factors that control post-combustion oxidation. Regulated exhaust components and detailed hydrocarbon species were measured using seven neat hydrocarbons and four blends as fuel. The fuels were selected to compare the relative rates of mixing and chemical kinetics. The results indicate that exhaust temperature, diffusion rates and fuel kinetics each play a complicated role in determining emission levels.