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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors on Powertrain Intake Valve Deposits

2013-04-08
2013-01-0893
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.
Technical Paper

Cellulosic Ethanol Fuel Quality Evaluation and its Effects on PFI Intake Valve Deposits and GDI Fuel Injector Plugging Performance

2013-04-08
2013-01-0885
The U.S. Renewable Fuel Standard 2 (RFS2) mandates the use of advanced renewable fuels such as cellulosic ethanol to be blended into gasoline in the near future. As such, determining the impact of these new fuel blends on vehicle performance is important. Therefore, General Motors conducted engine dynamometer evaluations on the impact of cellulosic ethanol blends on port fuel injected (PFI) intake valve deposits and gasoline direct injected (GDI) fuel injector plugging. Chemical analysis of the test fuels was also conducted and presented to support the interpretation of the engine results. The chemical analyses included an evaluation of the specified fuel parameters listed in ASTM International's D4806 denatured fuel ethanol specification as well as GC/MS hydrocarbon speciations to help identify any trace level contaminant species from the new ethanol production processes.
Journal Article

Hybrid Automata Modeling of SI Gasoline Engines towards State Estimation for Fault Diagnosis

2011-12-15
2011-01-2434
Mean Value Engine Models, commonly used for model based fault diagnosis of SI engines, fail to capture the within-cycle dynamics of engines, often resulting in reduced fault sensitivity. This paper presents a new Hybrid Automata based modeling approach for characterizing the within-cycle dynamics of the thermo-fluidic processes in a Spark Ignition Gasoline Engine, targeted for use in model based fault diagnosis. Further, using a hybrid version of the Extended Kalman Filter (EKF), the states from the nonlinear hybrid automata based dynamic model are estimated and their results validated w.r.t standard industrial simulation software, AMESim. It is observed that due to the switching of within cycle engine dynamics, causing mode change, there is a corresponding change in model's structure which in turn can cause change in system's observability.
Journal Article

Numerical Investigation of Buoyancy-Driven Flow in a Simplified Underhood with Open Enclosure

2013-04-08
2013-01-0842
Numerical results are presented for simulating buoyancy driven flow in a simplified full-scale underhood with open enclosure in automobile. The flow condition is set up in such a way that it mimics the underhood soak condition, when the vehicle is parked in a windbreak with power shut-down after enduring high thermal loads due to performing a sequence of operating conditions, such as highway driving and trailer-grade loads in a hot ambient environment. The experimental underhood geometry, although simplified, consists of the essential components in a typical automobile underhood undergoing the buoyancy-driven flow condition. It includes an open enclosure which has openings to the surrounding environment from the ground and through the top hood gap, an engine block and two exhaust cylinders mounted along the sides of the engine block. The calculated temperature and velocity were compared with the measured data at different locations near and away from the hot exhaust plumes.
Journal Article

Detailed Simulations of Stratified Ignition and Combustion Processes in a Spray-Guided Gasoline Engine using the SparkCIMM/G-Equation Modeling Framework

2012-04-16
2012-01-0132
Recently, high-speed optical imaging data for a single operating point of a spray-guided gasoline engine has, along with the flamelet model and the G-equation theory, enabled the development of the new spark-ignition model SparkCIMM. Within its framework, detailed chemistry flamelet models capture the experimental feature of multiple localized ignition events along the excessively stretched and restriking spark channel, as well as the observations of non-spherical highly corrugated early turbulent flame fronts. The developed flamelet models account for the substantial turbulent fluctuations in equivalence ratio and enthalpy present under spray-guided conditions. A non-unity Lewis number formulation captures the deficient species diffusion into the highly curved flame reaction zone.
Technical Paper

Experimental Investigation of Light-Medium Load Operating Sensitivity in a Gasoline Compression Ignition (GCI) Light-Duty Diesel Engine

2013-04-08
2013-01-0896
The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.
Technical Paper

Correlating Measured Combustion Performance with CFD Predicted In-Cylinder Flows for a Spark-Ignition Direct-Injection (SIDI) Engine with Enhanced Charge Motion

2013-04-08
2013-01-1090
A numerical and corresponding experimental study was undertaken to identify the ability to accurately predict combustion performance using our 3-D numerical tools for a direct-injection homogeneous-charge engine. To achieve a significant range of combustion rates, the evaluation was conducted for the engine operating with and without enhanced charge motion. Five charge motion configurations were examined, each having different levels of swirl and tumble flow leading to different turbulence generation and decay characteristics. A detailed CFD analysis provides insight into the in-cylinder flow requirements as well as the accuracy of the submodels. The in-cylinder air-fuel distribution, the mass-averaged swirl and tumble levels along with mean flow and turbulent kinetic energies are calculated throughout the induction and compression processes.
Technical Paper

Three-Way Catalyst Design for Urealess Passive Ammonia SCR: Lean-Burn SIDI Aftertreatment System

2011-04-12
2011-01-0306
Lean-burn SIDI engine technology offers improved fuel economy; however, the reduction of NOx during lean-operation continues to be a major technical hurdle in the implementation of energy efficient technology. There are several aftertreatment technologies, including the lean NOx trap and active urea SCR, which have been widely considered, but they all suffer from high material cost and require customer intervention to fill the urea solution. Recently reported passive NH₃-SCR system - a simple, low-cost, and urea-free system - has the potential to enable the implementation of lean-burn gasoline engines. Key components in the passive NH₃-SCR aftertreatment system include a close-coupled TWC and underfloor SCR technology. NH₃ is formed on the TWC with short pulses of rich engine operation and the NH₃ is then stored on the underfloor SCR catalysts.
Technical Paper

The Development of Advanced 2-Way SCR/DPF Systems to Meet Future Heavy-Duty Diesel Emissions

2011-04-12
2011-01-1140
Diesel engines have the potential to significantly increase vehicle fuel economy and decrease CO₂ emissions; however, efficient removal of NOx and particulate matter from the engine exhaust is required to meet stringent emission standards. A conventional diesel aftertreatment system consists of a Diesel Oxidation Catalyst (DOC), a urea-based Selective Catalyst Reduction (SCR) catalyst and a diesel particulate filter (DPF), and is widely used to meet the most recent NOx (nitrogen oxides comprising NO and NO₂) and particulate matter (PM) emission standards for medium- and heavy-duty sport utility and truck vehicles. The increasingly stringent emission targets have recently pushed this system layout towards an increase in size of the components and consequently higher system cost. An emerging technology developed recently involves placing the SCR catalyst onto the conventional wall-flow filter.
Technical Paper

The Effect of Pt-Pd Ratio on Oxidation Catalysts Under Simulated Diesel Exhaust

2011-04-12
2011-01-1134
With a tighter regulatory environment, reduction of hydrocarbon emissions has emerged as a major concern for advanced low-temperature combustion engines. Currently precious metal-based diesel oxidation catalysts (DOC) containing platinum (Pt) and palladium (Pd) are most commonly used for diesel exhaust hydrocarbon oxidation. The efficiency of hydrocarbon oxidation is greatly enhanced by employing both Pt and Pd together compared to the case with Pt or Pd alone. However, there have been few systematic studies to investigate the effects of the ratio of platinum to palladium on catalytic oxidation over the DOC. The present study illustrates the relationship between the Pt-Pd ratio and catalyst activity and stability by evaluating a series of catalysts with various Pt to Pd ratios (1:0, 7:1, 2:1, 1:2, 1:5, 0:1). These catalysts were tested for their CO and hydrocarbon light-off temperatures under simulated conditions where both unburned and partially burned hydrocarbons were present.
Technical Paper

Effects of Fuel Ethanol Quality on Vehicle System Components

2011-04-12
2011-01-1200
Corn ethanol has been used for fuel blending as both an oxygenate and octane booster and in most U.S. states conform to the ASTM D5798 fuel ethanol quality standard. Today the fuel ethanol market is expanding the types of feedstocks used to make ethanol and changing the processing techniques. These non-corn alternative feedstocks used to produce fuel ethanol bring new chemical components into the product that are not monitored under the D5798 standard, and it is unclear if they will result in material compatibility challenges for vehicle fuel systems that could affect performance and emissions. The vehicle contains a variety of plastic, metallic, and polymeric materials in the fuel tank, fuel pump, engine, and exhaust system that are sensitive to water, ions, acids, and high molecular weight compounds.
Technical Paper

Effectiveness of Cold Soak Filtration Test to Predict Precipitate Formation in Biodiesel

2011-04-12
2011-01-1201
Biodiesel use is increasing around the world. Vehicle failures due to filter clogging issues have been reported in the field with use of biodiesel blended fuels in winter months. In certain instances, filter clogging was caused by precipitate formation above the cloud point of the fuel. Minor contaminants in biodiesel such as sterol glucosides and saturated monoglycerides are suspected to cause precipitation above the cloud point. ASTM has added a requirement to test biodiesel fuel for cold soak filtration test to prevent occurrences of this phenomenon of precipitation above the cloud point. This study focuses on understanding the correlation between cold soak filtration test results and presence of contaminants such as sterol glucosides and saturated monoglycerides in biodiesel fuels. Test samples were also subjected to thermal cycling at temperatures below the cloud point of fuel to co-correlate the cold soak filtration test results to visual observation of precipitate formation.
Journal Article

A Comparison of Spray-Guided Stratified-Charge Combustion Performance with Outwardly-Opening Piezo and Multi-Hole Solenoid Injectors

2011-04-12
2011-01-1217
This investigation was aimed at measuring the relative performance of two spray-guided, single-cylinder, spark-ignited direct-injected (SIDI) engine combustion system designs. The first utilizes an outwardly-opening poppet, piezo-actuated injector, and the second a conventional, solenoid operated, inwardly-opening multi-hole injector. The single-cylinder engine tests were limited to steady state, warmed-up conditions. The comparison showed that these two spray-guided combustion systems with two very different sprays had surprisingly close results and only differed in some details. Combustion stability and smoke emissions of the systems are comparable to each other over most of the load range. Over a simulated Federal Test Procedure (FTP) cycle, the multi-hole system had 15% lower hydrocarbon and 18% lower carbon monoxide emissions.
Journal Article

Fatigue Behavior and Life Prediction for Aluminum Castings in the Absence of Casting Flaws

2011-04-12
2011-01-0193
Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].
Technical Paper

Evaluation and Design of Injector Hole Patterns Using CFD with a Fuel Tracer Diagnostic for Gasoline Direct Injection (GDI) Engines

2011-04-12
2011-01-0840
A CFD code is enhanced with a fuel tracer diagnostic to track the liquid and vapor fuel mass separately from individual spray plumes of a multi-hole injector and the wall film. The approach works by solving a set of additional scalar transport equations for fuel vapor generated from individual nozzle hole and the wall film. The diagnostic tool is first validated against experiments from a 4-valve, wall-guided spark-ignition direct-injection (SIDI) engine. A CFD analysis is carried out to understand the experimentally observed trade-offs in combustion stability and smoke emissions between a 70degree hollow-cone swirl injector and a 40 degree, 5-hole, circular-type multi-hole injector at a lean, stratified idle operating condition. Engine tests show that the multi-hole injector results in lower COV of IMEP than the hollow-cone swirl injector at the expense of significantly higher smoke emissions.
Technical Paper

Balance of Electrical Power Requirements through Smart Electric Power Management

2011-04-12
2011-01-0042
This paper examines Smart Electric Power Management as it pertains to when the vehicle charging system is active. Over the past decade there have been several factors at play which have stressed the demands placed upon the vehicle electrical power system. Many of these factors present challenges to electrical power that are at cross-purposes with one another. For example, demands of new and existing electrical loads, customer expectations about load performance and battery life, and the push by governments' world-wide for increased fuel economy (FE) and reduced CO2 emissions all have direct impact and can be directly impacted by decisions made in electric power design. As the electrification of the vehicle has progressed we now have much more specific vehicle state data available and the means to share this information among on-board computers through serial data link connectivity.
Technical Paper

The Influence of DISI Engine Operating Parameters on Particle Number Emissions

2011-04-12
2011-01-0143
The future EURO 6 emission standard will limit the particle number and mass for gasoline engines. The proposed limit for particle mass is 4.5 mg/km. For particle number there is not yet a limit defined but a wide range of proposals are under discussion (6E11 - 8E12 Particles/km) The particle emissions on a homogeneous SIDI engine are mainly caused by insufficient mixture preparation. A combustion improvement could be achieved by a careful recalibration as well as a hardware optimization that mainly avoids wall impingement and substoichiometric zones in the combustion chamber. The analyses of current SIDI vehicles show significant PN emission peaks during cold start and transient operation on a NEDC cycle. To give a better understanding of cause and effect of the particle formation at steady state results so as transient load steps were performed at an engine dynamometer.
Technical Paper

Effects of Fuel Corrosion Inhibitors on Powertrain Intake Valve Deposits

2011-04-12
2011-01-0908
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.
Technical Paper

Experimental Study of NOx Reduction by Passive Ammonia-SCR for Stoichiometric SIDI Engines

2011-04-12
2011-01-0307
As vehicle fuel economy requirements continue to increase it is becoming more challenging and expensive to simultaneously improve fuel consumption and meet emissions regulations. The Passive Ammonia SCR System (PASS) is a novel aftertreatment concept which has the potential to address NOx emissions with application to both lean SI and stoichiometric SI engines. PASS relies on an underfloor (U/F) SCR for storage of ammonia which is generated by the close-coupled (CC) TWCs. For lean SI engines, it is required to operate with occasional rich pulses in order to generate the ammonia, while for stoichiometric application ammonia is passively generated through the toggling of air/fuel ratio. PASS serves as an efficient and cost-effective enhancement to standard aftertreatment systems. For this study, the PASS concept was demonstrated first using lab reactor results which highlight the oxygen tolerance and temperature requirements of the SCR.
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