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Many papers have been written for SAE on electrochemical metallizing, a modern term for “selective” or “brush” plating. These papers have dealt primarily with the aerospace industry, including the use of non-embrittling cadmium LHE® coatings for corrosion protection on aircraft. Shadowed by 30 years of successes in the aerospace industry, electrochemical metallizing corrosion protection in the automotive industry is often overlooked. Specifically, the use of selectively applied zinc coatings for corrosion protection on wheel hubs during manufacture has proven integral at several European automotive manufacturers. In the past, environmental conditions have corroded both the hubs and wheels of automobiles. Quite often the corrosion is in the microscopic gap between the hub and the wheel, which over time causes the wheel to seize and prevents removal. This has been frustrating to both stranded motorists and shop mechanics.

The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.

The critical component for maintaining uniform zinc phosphate coatings on aluminum is fluoride. The control of free fluoride is critical to the operation of the process, because aluminum is dissolved in a zinc phosphate bath as a step in the coating reaction. If the dissolved aluminum is not removed from the bath, it will inhibit the formation of coatings on all metals being treated. This paper presents the characteristics and composition of zinc phosphate coatings on aluminum and steel, and lists some practical considerations of the transition from steel to aluminum components. Some possible problem areas discussed are: galvanic corrosion, underpaint quality, surface finish, electro-painting, and new paint surfaces.

This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

This specification covers the requirements for producing a zinc phosphate coating on ferrous alloys and the properties of the coating.

Copper and brass radiators have served the automobile industry for many years using traditional fabrication processes. Demand for newer and stronger radiators with lighter weight for the modern vehicles prompted investigation of alternate materials. Properties of zinc alloys and their compatibility with brass suggested these could be used for radiator manufacture. Many zinc alloy compositions were investigated in the initial studies, because a solder alloy has to have many positive attributes. The first screening studies evaluated the ability of the solder to spread over copper and brass surfaces, representing tube, fin, and header materials. The second most important feature was the melting range of the developed alloy. In order to retain the anneal resistance of the fin and temper in the tube it was desirable to have a zinc solder with a melting temperature at 800°F or less.

For over a decade, industry prognosticators have been predicting that the use of plastics by automakers would soon surpass the deployment of metals in automobiles, While there is no denying that plastics have made inroads, it recently has become apparent that metal will retain its position as the prime car material for the foreseeable future. One reason for the revised forecast is the development of improved zinc coatings for the automotive industry. Such material as electrogalvanized and Galfan™ are shaping up as steel's saviors when it comes to ensuring that metal will continue to play the major role on car assembly lines. Meanwhile on the other side of the equation, developments in zinc die casting technology have taken the edge off plastics' forward thrust into both functional and decorative car part applications.

A presentation on zinc demonstrating its versatile applications to the auto industry. A review of metal balances, domestic, world and major producing countries. The energy required to mine, smelt and refine zinc is compared to other metals. The value of recycling zinc is also considered. This paper concludes with a statement, supported with evidence, that today's automobile is a better buy than twenty years ago.

This paper describes a design for an electric vehicle (EV) battery system using a secondary (rechargeable) lead-acid section for power and a recyclable (mechanically replaced) primary zinc-air section for range. This approach optimizes the performance of each battery, resulting in a system with driving performance (acceleration, range, and refueling time) equal to that for internal combustion vehicles (ICVs). The physical characteristics of the system's components are highly compatible with their ICV counterparts, resulting in a substantial reduction in the cost of building prototype vehicles. The overall cost of the rechargeable/recyclable approach is estimated to be equal to that for the traditional single rechargeable battery approach.

Dreisbach ElectroMotive, Inc. (DEMI) is developing and testing a maintenance-free wall-plug rechargeable Zinc-Air Battery to power Electric Vehicles. This new battery technology offers over 200 mile vehicle range capability from very low cost, commonly available raw materials. This paper will focus on the preliminary systems integration needed by an electric Vehicle to operate these air breathing batteries in various common environments. Air cooling and reaction air requirements will be covered as well as the actual systems used to implement these requirements in a Chrysler minivan* which is sponsored by Southern California Edison (SCE). In addition, the projected system implementations of Zinc-Air batteries in automobiles and multi-use vans will be presented.

Energy Development Associates, a division of Gulf+Western Industries, Inc., has undertaken the design and fabrication of a four-passenger electric car incorporating state-of-the art zinc-chloride battery technology. The purpose of the project is to demonstrate the viability of the zinc-chloride energy storage system as a practical alternative to cars powered by internal combustion engines. Significant among the project goals to be achieved is the attainment of a vehicle range three to four times that of current lead-acid battery-powered vehicles on a single battery charge. Progress to date on the project is discussed. It includes the design, specification, and fabrication of the battery, vehicle and its components, motor control system, and battery control microprocessor.

Zinc-coatings with a substantial Magnesium content have been in use for over 30 years by now. Unlike the well-established Zn-Al-Mg coatings originating from Japan which have significant higher alloying contents applied mainly for building applications, this Zinc Magnesium Aluminum coating (ZM) is also specifically designed to meet the requirements of car manufacturers. The ZM coating introduced by voestalpine, corrender, is in the upper range of ZM-alloying compositions, which was set by VDA (German Association of the Automotive Industry) and SAE to be within 1.0 to 2.0 wt. % Mg and 1.0 to 3.0 wt. % Al. The properties of these “European” Zinc-Magnesium coatings are well comparable within this range. Compared to GI and GA ZM coatings exhibit significant advantages in the press shops with its excellent formability and reduced galling and powdering respectively which is a significant advantage for the forming of outer panels.

Zinc-manganese alloy electroplated has been developed for automotive body panel applications. The product is manufactured on a conventional electrogalvanizing line using an electrolyte containing zinc sulfate, manganese sulfate and sodium citrate. Electroplated steel with an alloy content of 30-50% manganese exhibits excellent corrosion resistance both as-produced and after painting. Zinc-manganese coatings also show good workability and voidability. Accordingly, this product is suitable for both unexposed parts and the interior surfaces of exposed parts. Finally, zinc-manganese electroplated steel displays good wet adhesion and anti-cratering characteristics so that the product can also be used for exposed applications as automotive body panels.

The process considerations, manufacturability, corrosion properties, paintability, weldability, and formability of nominal 9 to 15 percent electrodeposited zinc-nickel (Zn-Ni) alloy-coated sheet steels for automotive applications were reviewed. Zn-Ni coatings were selected for use in automobile body panels by several automakers because of their ease of manufacturing, forming, and welding. Although Zn-Ni coatings may be easily manufactured into autobody panels without a change in production procedures, these coatings exhibit poor paintability and poor corrosion resistance, and would be risky to expose in the U.S. automotive environment at the specified 20 to 40 g/m2 coating weights. Zn-Ni coatings will not provide the cosmetic corrosion protection of zinc or zinc-iron (Zn-Fe) coatings, particularly on exterior autobody panels in a fully painted condition.

Diesel engines are coming under stricter requirements to reduce emissions. particularly those of particulates and nitrogen oxides (NOx). Recently, the U. S. EPA put into place staged requirements for heavy duty diesel engines in urban bus applications which are aimed at ultimately bringing pre-1994 engines into particulate emissions compliance with 1994 heavy duty on-road truck standards (0. 1 g/bhp-hr TPM). This reflects the need to control emissions in crowded urban environments. Zirconia based ceramic combustion management coatings, although originally developed for adiabatic or low heat rejection engines to boost thermal efficiency, have also been shown to contribute to the reduction in diesel emissions. Heavy duty transient testing of rebuilt 2-stroke MUI diesel bus engines equipped with stabilized zirconia based coatings applied by thermal spray process have shown significant reduction in exhaust opacity relative to a baseline, uncoated engine.

A zirconia electroysis cell is an all-solid state (mainly ceramic) device consisting of two electrodes separated by a dense zirconia electrolyte. The cell electrochemically reduces carbon dioxide to oxygen and carbon monoxide at elevated temperatures (800 to 1000°C). The zirconia electrolysis cell provides a simple, lightweight, low-volume system for Mars In-Situ Resource Utilization (ISRU) applications. This paper describes the fabrication process and discusses the electrochemical performance and other properties of zirconia electrolysis cells made by the tape calendering method. Electrolytes produced by this method are very thin (micrometer-thick); the thin electrolyte reduces ohmic losses in the cell, permitting efficient operation at temperatures of 800°C or below.

The zirconia exhaust gas oxygen sensor is a key component in closed loop engine emissions control systems. An equivalent circuit model of the sensor is derived from fundamental electrochemical principles. In this model, sensor electrode resistance and capacitance are separated from the zirconia electrolyte resistance. An important theoretical conclusion is that the resistances (electrode kinetics) of microscopic CO and O2 voltage cells enter into the determination of sensor output voltage and its transient response. In addition, numerical examples are given to show how the equivalent circuit can be used to model both steady state and transient characteristics of sensors.

This paper will review the role of zirconium oxide in automotive systems. Zirconium oxide has been used and been considered for use in many different applications within automotive systems. Examples include ceramics for engine liners, ionic conductors for oxygen sensors, piezoelectrics for a variety of sensors and as an ingredient of autocatalysts. In the first three examples, ceramics, ionic conductors and piezoelectrics, the known properties of zirconium oxide containing systems have been applied to solve problems in the automobile. In the last the use of zirconia here has created an interest outside automotive applications. This paper will also show how a knowledge of zirconia in one field can produce benefits in another and that through this synergy improved products can be brought to the marketplace

Keeping exhaust heat only where it is wanted is a fresh challenge for the commercial vehicle and off-highway equipment industries.

In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.