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Aiming at estimating the vehicle mass and the position of center of gravity, an on-line two-stage estimator, based on the recursive least square method, is proposed for buses in this paper. Accurate information of the center of gravity position is crucial to vehicle control, especially for buses whose center of gravity position can be varied substantially because of the payload onboard. Considering that the buses start and stop frequently, the first stage of the estimator determines the bus total mass during acceleration, and the second stage utilizes the recursive least-square methods to estimate the position of the center of gravity during braking. The proposed estimator can be validated by the co-simulation with MATLAB/Simulink and TruckSim software, simulation results exhibit good convergence and stability, so the center of gravity position can be estimated through the proposed method in a certain accuracy range.